• Bulletin of the Korean Chemical Society
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• 제7권6호
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• pp.466-468
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• 1986

Reaction of $Ir(ClO_4)(CO)(PPh_3)_2$ with trans-$C_6H_5CH$ = $CHCO_2C_2H_5$ produces a new cationic iridium(I) complex, [Ir (trans-$C_6H_5CH$ = $CHCO_2C_2H_5)(CO)(PPh_3)_2]ClO_4$ where trans-$C_6H_5CH$ = $CHCO_2C_2H_5$ seems to be coordinated through the carbonyl oxygen rather than through the $\pi$-system of the olefinic group according to the spectral data. It has been found that Ir$(ClO_4)(CO)(PPh_3)_2$ catalyzes the hydrogenation of $CH_2$ = $CHCO_2C_2H_5$, trans-$CH_3CH$ = $CHCO_2C_2H_5$ and trans-$C_6H_5CH$ = $CHCO_2C_2H_5$ to $CH_3CH_2CO_2C_2H_5$, $CH_3CH_2CH_2CO_2C_2H_5$ and $C_6H_5CH_2CH_2CO_2C_2H_5$, respectively at room temperature under the atmospheric pressure of hydrogen. The relative rates of the hydrogenation of the unsaturated esters are mostly understood in terms of steric reasons.

• 대한안전경영과학회지
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• 제24권1호
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• pp.73-80
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• 2022

The purpose of this study is to present the direction of the plan to transform the residential complex into a space that can provide an open residential environment that can lead to social communication and exchange without being closed to the urban residential environment, especially in the apartment complex environment, which is becoming more dense. As a result of the Openness analysis of the 'Codan Shinonome Canal Court', the overall accessibility was good in terms of space utilization, and the openness was low in terms of the spatial composition, which is a physical environment due to the dense block type. When looking at the overall openness of the Codan Sinonome complex in terms of analysis by block, the corrected openness index (C.O.I) for all six blocks was 0.245, the corrected accessibility index (C.A.I) was 1.447 and the openness composite index (O.C.I) was assessed at 1.692. This was due to the formation of high-density block-type urban dwellings and the introduction of S-shaped streets and the layout of low-rise urban support facilities and commercial facilities. The Codan Sinonome Canal Court, which is considered an "open city residence," quantitatively confirmed that it embodies macro-space structure and human-scale space environment even in high-precision environments.

• 대한수학회지
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• 제40권3호
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• pp.423-434
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• 2003

We prove an approximation result, and we get a new proof of the main result in [7]. I hope that this new proof may be a step towards a generalization of the Poletsky theory of discs to the case of almost complex manifolds.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1990년도 추계학술대회 논문집
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• pp.108-109
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• 1990

For the purpose of fabricating of L-B Films, (N-alkyl pyridinium)-TCNQ(1:1) complex is synthesized. This complex is verified by U.V, I.R and elemental analyzer.

• 대한화장품학회지
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• 제18권1호
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• pp.99-132
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• 1992

물-알코올 용액에서 염기성으로 작용하는 폴리펩타이드와 산성으로 작용하는 폴리펩타이드 사이에 수소결합을 통한 복합체 형성에 관한 연구를 점도, PH, 빛산란, 원편광이색성, 광회전도 등으로 조사했다. 얻어진 결과는 여러가지 복합체 시스템 모두가 1:2 조성으로 복합체 형성을 한다는 것을 알 수 있었으며, 우선성 헬릭스를 가지는 폴리펩타이드와 좌선성 헬릭스를 가지는 폴리펩타이드, 즉 반대방향성의 헬릭스 구조를 가지는 폴리펩타이드들 사이에 강한 상호작용을 나타내고, 반면, 같은 방향성의 헬릭스 구조를 가지는 폴리펩타이드의 형태가 복합체 형성에 매우 중요한 역할을 한다는 것을 나타낸다. 즉, 입체선택적 복합체 형성을 보인다. 또한 구조적으로 유연한 구조를 가지는 폴리펩타이드가 강한 상호 작용을 나타낸다. 즉, PHPL보다 PLP(I)이, PLP(I)보다 PLP(II)가, PAA보다 PGA가 더 강한 상호작용을 나타낸다. 이런 상호 복합체 형성이 일어나면 형태전이가 일어난다는 것도 확인할 수 있었다. 위의 결과를 근거로 하여, 좌선성 헬릭스 구조의 모발의 케라틴에 PLP(I, II)와 PHLP를 흡착시킨 후, 흡착량을 HPLC로 측정한 결과, PLP(II)보다 PLP(I)이, PHLP보다 PLP(II)가 더 많이 흡착되었다. 결론적으로, 모발에 폴리펩타이드를 사용시, 좌선성헬릭스 구조의 폴리펩타이드 보다 우선성헬릭스 구조의 폴리펩타이드가 더 많이 흡착되고, rigid conformation의 폴리펩타이드보다 foexible conformation의 폴리펩타이드가 더 많이 모발에 흡착되어, 효과가 좋다는 것을 알 수 있다.

• 품질경영학회지
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• 제20권1호
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• pp.158-167
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• 1992

This paper represents the new techniques for optimal sampling plans of reliability applying the mathematical complex number(real and imaginary number) in the complex system of reliability. The research formulation represent a mathematical model Which preserves all essential aspects of the main and auxiliary factors of the research objectives. It is important to formule the problem in good agreement with the objective of the research considering the main and auxilary factors which affect the system performance. This model was repeatedly tested to determine the required statistical chatacteristics which in themselves determine the actual and standard distributions. The evaluation programs and techniques are developed for establishing criteria for sampling plans of reliability effectiveness, and the evaluation of system performance was based on the complex stochastic process(derived by the Runge-Kutta method. by kolmogorv's criterion and the transform of a solution to a Sturon-Liouville equation.) The special structure of this mathematical model is exploited to develop the optimal sampling plans of reliability in the complex system.

• 대한화학회지
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• 제12권3호
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• pp.114-120
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• 1968

Fe-EDTA complex, which is easily formed when Fe salt and EDTA.2Na are mixed in the aqueous medium, is found to be a very effective catalyst in the dehydropolycondensation of aminophenols. In the dehydropolycondensation of aminophenols, the catalyst, Fe(Ⅲ)-EDTA complex (higher oxidation state) is reduced to less stable Fe(Ⅱ)-EDTA complex (lower oxidation state), and the latter is easily oxidized by air to the original higher oxidation state complex, therefore the catalytic action of Fe-EDTA complex is found to be recycled effectively. Under the catalytic action of the above mentioned complex, p-aminophenol is polymerized in the aqueous medium to form the oligomers of p-aminophenol, which the degree of polymerization to be 5 or more. The oligomers formed contain partly quinone nucleus as well as amino and hydroxyl groups. In this study, the effects of the solvents and characteristics of the oligomers are discussed. These types of polymerizations catalyzed by the metallic chelate compounds are considered to be very closely related to the reactions in the living matters.

• 대한수학회지
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• 제47권5호
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• pp.1001-1015
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• 2010

Let M be a $C^{\infty}$ real hypersurface in $\mathbb{C}^{n+1}$, $n\;{\geq}\;1$, locally given as the zero locus of a $C^{\infty}$ real valued function r that is defined on a neighborhood of the reference point $P\;{\in}\;M$. For each k = 1,..., n we present a necessary and sufficient condition for there to exist a complex manifold of dimension k through P that is contained in M, assuming the Levi form has rank n - k at P. The problem is to find an integral manifold of the real 1-form $i{\partial}r$ on M whose tangent bundle is invariant under the complex structure tensor J. We present generalized versions of the Frobenius theorem and make use of them to prove the existence of complex submanifolds.

• 전자공학회논문지C
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• 제34C권2호
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• pp.12-18
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• 1997

An efficient synthesis method of cellular architecture FPgA is proposed in this paper. To generate a logical representation called complex term which is to be directly mapped onto the cellular architecture FPGA, and SO or ESOP minimization tool was used in previous methods. Instead, we use a logic function transformed into BDD (binary decision diagram) in the actual generation of the complex temrs. In this process it estimates the cost(i.e. the number of complex terms) for three branches, 0-branch and 1-branches. This process is continued over the whole BDD to do such computation, and we observed that the number of complex terms has been reduced compared to the previous results.

• Bulletin of the Korean Chemical Society
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• 제21권7호
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• pp.675-678
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• 2000

The reaction between silver (I) and thiomicher's ketone (TMK) was sensitive at pH 5 and 8 in the presence of non-ionic or anion surfactant. We studied the complex solution and determined the properties by beta-correction spectrophotometry, which included the complex ratio and the stability constant of the complex. The results showed that complex Ag(TMK)2 was formed in the presence of alkylphend ethoxylates (emulsifier OP) and Ag(TMK)2 was formed in the presence of sodium dodecyl benzene sulfonate (SDBS). Their real absorptivities are as follows: $\varepsilonAg(TMK)540$ = 5.23 ${\times}$ 10(4), $\varepsilonAg(TMK)2(555)$ = l.05 ${\times}$ 10(5) Lmol(-l)cm(-1) both at pH 5 and $\varepsilonAg(TMK)2(555)$ = 7,52 ${\times}$ 10(4)lmol(-1)cm(-1) at pH 8. The stability constant of complex Ag(TMK) was equal to 1.23 ${\times}$ 10(5) at pH 5 and that of Ag(TMK)2 8.29 ${\times}$ 10(9) at pH 5 and 1.15 ${\times}$ 10(11) at pH 8.