• Bulletin of the Korean Chemical Society
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• v.7 no.6
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• pp.466-468
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• 1986

Reaction of $Ir(ClO_4)(CO)(PPh_3)_2$ with trans-$C_6H_5CH$ = $CHCO_2C_2H_5$ produces a new cationic iridium(I) complex, [Ir (trans-$C_6H_5CH$ = $CHCO_2C_2H_5)(CO)(PPh_3)_2]ClO_4$ where trans-$C_6H_5CH$ = $CHCO_2C_2H_5$ seems to be coordinated through the carbonyl oxygen rather than through the $\pi$-system of the olefinic group according to the spectral data. It has been found that Ir$(ClO_4)(CO)(PPh_3)_2$ catalyzes the hydrogenation of $CH_2$ = $CHCO_2C_2H_5$, trans-$CH_3CH$ = $CHCO_2C_2H_5$ and trans-$C_6H_5CH$ = $CHCO_2C_2H_5$ to $CH_3CH_2CO_2C_2H_5$, $CH_3CH_2CH_2CO_2C_2H_5$ and $C_6H_5CH_2CH_2CO_2C_2H_5$, respectively at room temperature under the atmospheric pressure of hydrogen. The relative rates of the hydrogenation of the unsaturated esters are mostly understood in terms of steric reasons.

• Journal of the Korea Safety Management & Science
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• v.24 no.1
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• pp.73-80
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• 2022

The purpose of this study is to present the direction of the plan to transform the residential complex into a space that can provide an open residential environment that can lead to social communication and exchange without being closed to the urban residential environment, especially in the apartment complex environment, which is becoming more dense. As a result of the Openness analysis of the 'Codan Shinonome Canal Court', the overall accessibility was good in terms of space utilization, and the openness was low in terms of the spatial composition, which is a physical environment due to the dense block type. When looking at the overall openness of the Codan Sinonome complex in terms of analysis by block, the corrected openness index (C.O.I) for all six blocks was 0.245, the corrected accessibility index (C.A.I) was 1.447 and the openness composite index (O.C.I) was assessed at 1.692. This was due to the formation of high-density block-type urban dwellings and the introduction of S-shaped streets and the layout of low-rise urban support facilities and commercial facilities. The Codan Sinonome Canal Court, which is considered an "open city residence," quantitatively confirmed that it embodies macro-space structure and human-scale space environment even in high-precision environments.

• Journal of the Korean Mathematical Society
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• v.40 no.3
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• pp.423-434
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• 2003

We prove an approximation result, and we get a new proof of the main result in [7]. I hope that this new proof may be a step towards a generalization of the Poletsky theory of discs to the case of almost complex manifolds.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1990.10a
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• pp.108-109
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• 1990

For the purpose of fabricating of L-B Films, (N-alkyl pyridinium)-TCNQ(1:1) complex is synthesized. This complex is verified by U.V, I.R and elemental analyzer.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.18 no.1
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• pp.99-132
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• 1992

Polypeptide has been used broadly as an active ingredient in cosmetics We thought it is very important to investigate the adsorption behavior of polypeptide in order to pre-estimate the effect of these polypeptides. For the study of polypeptide adsorption, we have investigated complex formation of basic homopolypeptides, poly(L-proline) Form I [PLP(I)], Form II [PLP(II)] and poly(4-hydroxy-L-proline) (PHLP) with acidic homopolypeptides, poly(L-glutamic acid) (PLGA), poly(D-glutamic acid) (PDGA) and poly(L-aspartic acid) (PLAA) through hydrogen bonding in a hydroalcoholic medium with viscometer, 1ight scatter, pH meter and circular dicroism (CD). The polypeptides used in this study have helical structure in some conditions. The result exhibited that al 1 the complexes were formed as the composition of basic/acidic homopolypeptide : L:2 irrespective of the complex systems used. A more favorable complex is formed in the PLP(II)-PLGA system than PHLP-PLGA because PLP(II) has a more flexible helical conformation, whereas PHLP has a more rigid helical conformation. The right-handed helix PLGA formed the complex favorably and quickly with the left-handed helix PLP(II), whereas the left-handed helix PDGA formed the complex favorably with the right-handed helix PLP(I). The effect of side chain of the acidic homopolypeptides on the complexation was also studied. The result showed that more favorable condition for the complexation was PLGA-PLP(II) system which has longer side chain at acidic homopolypeptide than PLAA - PLP(II). All the above facts were well supported by CD measurement for the complex systems. By the CD spectra for the complexes we could deduce the conformational change of each homopolypeptide in the complexes On the basis of the above results, we performed the adsorption test of PLP(I, II) and PHLP on the hair having a left-handed helix. The adsorption amount of each polypeptide was analyzed by HPLC. The result showed that PLP(I) was adsorbed more than PLP(II), PLP(II) was adsorbed more than PHLP on the hair. On adsorbing polypeptides having a helical structure on the hair through hydrogen bonding, it could be concluded that the helical polypeptides having the opposite directional structure to the hair are adsorbed more than those having the same directional structure with the hair and also the polypeptides having a flexible conformation are adsorbed more than those having a rigid conformation.

• Journal of Korean Society for Quality Management
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• v.20 no.1
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• pp.158-167
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• 1992

This paper represents the new techniques for optimal sampling plans of reliability applying the mathematical complex number(real and imaginary number) in the complex system of reliability. The research formulation represent a mathematical model Which preserves all essential aspects of the main and auxiliary factors of the research objectives. It is important to formule the problem in good agreement with the objective of the research considering the main and auxilary factors which affect the system performance. This model was repeatedly tested to determine the required statistical chatacteristics which in themselves determine the actual and standard distributions. The evaluation programs and techniques are developed for establishing criteria for sampling plans of reliability effectiveness, and the evaluation of system performance was based on the complex stochastic process(derived by the Runge-Kutta method. by kolmogorv's criterion and the transform of a solution to a Sturon-Liouville equation.) The special structure of this mathematical model is exploited to develop the optimal sampling plans of reliability in the complex system.

• Journal of the Korean Chemical Society
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• v.12 no.3
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• pp.114-120
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• 1968

Fe-EDTA complex, which is easily formed when Fe salt and EDTA.2Na are mixed in the aqueous medium, is found to be a very effective catalyst in the dehydropolycondensation of aminophenols. In the dehydropolycondensation of aminophenols, the catalyst, Fe(Ⅲ)-EDTA complex (higher oxidation state) is reduced to less stable Fe(Ⅱ)-EDTA complex (lower oxidation state), and the latter is easily oxidized by air to the original higher oxidation state complex, therefore the catalytic action of Fe-EDTA complex is found to be recycled effectively. Under the catalytic action of the above mentioned complex, p-aminophenol is polymerized in the aqueous medium to form the oligomers of p-aminophenol, which the degree of polymerization to be 5 or more. The oligomers formed contain partly quinone nucleus as well as amino and hydroxyl groups. In this study, the effects of the solvents and characteristics of the oligomers are discussed. These types of polymerizations catalyzed by the metallic chelate compounds are considered to be very closely related to the reactions in the living matters.

• Journal of the Korean Mathematical Society
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• v.47 no.5
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• pp.1001-1015
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• 2010

Let M be a $C^{\infty}$ real hypersurface in $\mathbb{C}^{n+1}$, $n\;{\geq}\;1$, locally given as the zero locus of a $C^{\infty}$ real valued function r that is defined on a neighborhood of the reference point $P\;{\in}\;M$. For each k = 1,..., n we present a necessary and sufficient condition for there to exist a complex manifold of dimension k through P that is contained in M, assuming the Levi form has rank n - k at P. The problem is to find an integral manifold of the real 1-form $i{\partial}r$ on M whose tangent bundle is invariant under the complex structure tensor J. We present generalized versions of the Frobenius theorem and make use of them to prove the existence of complex submanifolds.

• Journal of the Korean Institute of Telematics and Electronics C
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• v.34C no.2
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• pp.12-18
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• 1997

An efficient synthesis method of cellular architecture FPgA is proposed in this paper. To generate a logical representation called complex term which is to be directly mapped onto the cellular architecture FPGA, and SO or ESOP minimization tool was used in previous methods. Instead, we use a logic function transformed into BDD (binary decision diagram) in the actual generation of the complex temrs. In this process it estimates the cost(i.e. the number of complex terms) for three branches, 0-branch and 1-branches. This process is continued over the whole BDD to do such computation, and we observed that the number of complex terms has been reduced compared to the previous results.

• Bulletin of the Korean Chemical Society
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• v.21 no.7
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• pp.675-678
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• 2000

The reaction between silver (I) and thiomicher's ketone (TMK) was sensitive at pH 5 and 8 in the presence of non-ionic or anion surfactant. We studied the complex solution and determined the properties by beta-correction spectrophotometry, which included the complex ratio and the stability constant of the complex. The results showed that complex Ag(TMK)2 was formed in the presence of alkylphend ethoxylates (emulsifier OP) and Ag(TMK)2 was formed in the presence of sodium dodecyl benzene sulfonate (SDBS). Their real absorptivities are as follows: $\varepsilonAg(TMK)540$ = 5.23 ${\times}$ 10(4), $\varepsilonAg(TMK)2(555)$ = l.05 ${\times}$ 10(5) Lmol(-l)cm(-1) both at pH 5 and $\varepsilonAg(TMK)2(555)$ = 7,52 ${\times}$ 10(4)lmol(-1)cm(-1) at pH 8. The stability constant of complex Ag(TMK) was equal to 1.23 ${\times}$ 10(5) at pH 5 and that of Ag(TMK)2 8.29 ${\times}$ 10(9) at pH 5 and 1.15 ${\times}$ 10(11) at pH 8.