• Journal of the Korean Society of Combustion
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• v.13 no.1
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• pp.1-9
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• 2008

Emission characteristics of NOx and CO with heat loss under high efficiency combustion conditions of $CH_4$/Air prmixed flame were examined numerically using detailed-kinetic chemistry. The one-dimensional combustor length was fixed 5cm, and the equivalence ratio was varied from 0.75 to 0.95. To consider the effects of heat loss on NOx and CO formation, the radiative heat loss rate and combined heat loss rate of conductive and convective heat transfer are included. The following conclusions were drawn. In order to reduce the NOx and CO emission level simultaneously, the temperature of product gases must be reduced under 1,800K as soon as possible but kept over 1,300K during the residence time which is needed to converge CO to $CO_2$.

• Journal of the Korean Society of Combustion
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• v.13 no.1
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• pp.23-30
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• 2008

An analytical expression for the turbulent burning velocity is derived from the asymptotic zone conditional transport equation at the leading edge. It is given as a sum of laminar and turbulent contributions, the latter of which is given as a product of turbulent diffusivity in unburned gas and inverse scale of wrinkling at the leading edge. It was previously shown that the inverse scale is equal to four times the maximum flame surface density in the wrinkled flamelet regime [1]. The linear behavior between $U_T$ and u' shows deviation with the inverse scale decreasing due to the effect of a finite flamelet thickness at higher turbulent intensities. DNS results show that $U_T/S^0_{Lu}$ may be given as a function of two dimensionless parameters, $u'/S^0_{Lu}$ and $l_t/\delta_F$, which may be transformed into another relationship in terms of $u'/S^0_{Lu}$, and Ka. A larger $l_t/{\delta}_F$ or a smaller Ka leads to a smaller scale of wrinkling, hence a larger turbulent burning velocity in the limited range of $u'/S^0_{Lu}$. Good agreement is achieved between the analytical expression and the turbulent burning velocities from DNS in both wrinkled and thickened-wrinkled flame regimes.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.5
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• pp.750-756
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• 2002

The effect of equivalence ratio and velocity on the stability of flame in dump combustor was studied in an atmospheric pressure, laboratory scathe dump combustor operating natural gas. Traditionally, peak-to-peak pressure, fluctuation of the heat release rate and Rayleigh index were used to find and control the combustion instability. Cross correlation coefficients, Ci,j which is defined as the normalized value of the integration of the product of two of the mixer pressure, dump plane pressure and heat release rate, are introduced to see whether the flame is stable or not. Ci,j shows more sensitive to combustion status than Rayleigh index in steadily burning flame. Also, the result indicates that the amplitude of Ci,j between heat release and mixer pressure goes up before the flame at the rich de-stabilizing equivalence ratio near $\psi$=0.85. t means Ci:j at this case has a potential to detect the de-stablizing moment in prior to becoming unstable in dump combustor.

• Environmental Engineering Research
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• v.25 no.4
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• pp.522-528
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• 2020

To achieve the clean and efficient utilization of low-rank coal, the combustion and pollutant emission characteristics of chars from low-temperature and fast pyrolysis in a horizontal tube furnace were investigated in a TG-MS analyzer. According to the results, the combustion characteristic of chars was poorer than its parent coals. The temperature range of gaseous product release had a good agreement with that of TGA weight loss. Gaseous products of samples with high content of volatile were released earlier. The NO and NO₂ emissions of chars were lower than their parent coals. Coals of high rank (anthracite and sub-bituminous) released more NO and NO₂ than low rank coals of lignite, so were chars from coals of different ranks. SO₂ emissions of char samples were lower than parent coals and did not show obvious relationship with coal ranks.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.2
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• pp.123-128
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• 2010

Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.05a
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• pp.108-108
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• 1998

• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.74-78
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• 2002

In this study, the solution combustion method was employed to synthesize perovskite PZT ceramics. Multicomponent oxides can be prepared by the solution combustion synthesis using redox exothermic reaction of precursor solutions. The results of DTA/TG showed exothermic peaks in 214$^{\circ}C$ and 350$^{\circ}C$. Those were caused by the differences of the thermal decomposition behavior of oxidizer and fuel. The combustion reaction was completed at 370$^{\circ}C$ during heating procedure, but the product was not transformed into perovskite. The thermal decomposition behavior of both oxidizer and fuel were considered during solution combustion process at 600$^{\circ}C$, which showed tetragonal single phase PZT ceramics with 50 nm crystalline size. The lattice constant a was 3.997 ${\pm}$ 0.001 ${\AA}$ and the lattice constant c was 4.147${\pm}$0.001 ${\AA}$.

• Journal of the Korean Ceramic Society
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• v.34 no.11
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• pp.1165-1172
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• 1997

ZrB2 powders were prepared from a mixture of ZrO2, B2O3 and Mg by self-propagating high temperature synthesis method. The combustion product was successfully obtained from a mixture of ZrO2:B2O3:Mg=1:2:8.5 molar ratio. By-product, MgO was effectively removed by leaching with 1M HCl solution at 9$0^{\circ}C$ for over 5hours. After leaching, the Mg content was 0.86~1.42 wt%, and the mean particle size was 4.72${\mu}{\textrm}{m}$. The addition of 7.5 wt%(14Ni:1.0C) as a sintering aid greatly densified ZrB2 bodies compared with that of only Ni. The ZrB2 sintered bodies containing 7.5 wt%(14Ni:1.0C) was 94.3% of the theoretical density. In this case, ZrB2 existed as a major phase and had a bend strength of 300 MPa and a vickers hardness of 2000 kg/$\textrm{mm}^2$.

• Fire Science and Engineering
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• v.31 no.6
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• pp.23-32
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• 2017

Foam block, popularized as the self-interior goods, is susceptible to fire since the main material is the polyethylene flammable synthetic resin. However, it is widely used in homes, offices, and multi-use facilities. In order to understand the fire characteristics of the foam block, two kinds of foam blocks sold in the market (non-fire retardant and fire retardant) were evaluated according to standard of KS F 5660-1 (Reaction to fire test). In addition, the hazard analysis of the gas generated by the combustion of the specimen was performed using the FTIR gas analyzer. The cone calorimeter test showed that the ignition and flame combustion of both two specimens were burned as soon as the radiant heat blocking device was removed, and it was confirmed that the flame could become a rapid propagation factor during the fire. The analysis of the combustion gas through the FTIR gas analyzer showed that both the carbon dioxide and carbon monoxide classified as the common combustion gases and the acrolein, ammonia, and hydrogen cyanide causing serious damage to the human body were detected substantially. This study showed that a foam block product has high ignitionability and generates toxic gases. Hence, it is urgently required to establish the standards used for properly classifying the combustion characteristics of the material on the basis of the use conditions of a foam block product and to prepare the standards on the purpose of use.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.35-40
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• 2003

Immense quantities of coal combustion by-products are produced every year, and only a small fraction of them are currently utilized. The purpose of this study is to investigate reused techniques of coal to highly economic growth and expansion of country base industry. So, in this study, artificial aggregate was developed to recycle coal ash by non-sintering technique and crush method. And characteristic of developed artificial aggregate was examined. Also, noise barriers using developed artificial aggregate was made by link of development of ECO-construction product and is preparing sound absorption and transmission loss experiment. Result of study was showed that artificial aggregate was more proper to use a noise barriers and this is expected to satisfy sound absorption standard in this study. So, if shape and color considering surround and design technology is studied continuously, it can be expected to make ECO-precast product as well as maximize waste recycling.