• Title/Summary/Keyword: Combustion carbon

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A Numerical Simulation of Hazardous Waste Destruction in a Dump Incinerator (덤프 소각기에서 유해폐기물 분해에 대한 수치해석)

  • 전영남;정오진;채종성
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.665-674
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    • 2000
  • A major source of the hazardous waste generated is from chemical industries producing plastics, herbicides, pesticides and chlorinated solvents. All of these processes produce a class if hazardous waste termed the chlorinated hydrocarbons(CHCs), either directly or from undesirable side reactions. In this study, we investigated the destruction characteristics of hazardous waste through incineration. A nonequilibrium combustion model was used to describe the effect of the chemical kinetics due to the flame inhibition characteristics of $CCl_4$ which was used as the surrogate of hazardous waste. A parametric screening studies was made in a dump incinerator proposed in this study. The dump incinerator showed high $CCl_4$ DRE(Destruction and Removal Efficiency) as 5 nines. $CCl_4$/CH$_4$ ratio appeared to be most important in the destruction of $CCl_4$ through incineration.

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A Study on the Fire Safety Performance of Interior Surface Materials in a Building (건축물의 실내건축 재료에 관한 화재안전성 연구)

  • Seo, Su-Eun;Shin, Seung-Woo
    • Proceedings of the Safety Management and Science Conference
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    • 2013.11a
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    • pp.275-290
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    • 2013
  • The main cause of building fire fatalities occur in the combustible material heat, smoke and toxic gases are. Building interior decoration, etc., especially as much of the harmful substances generated during combustion, and, used in domestic architecture wallpaper, ceiling, and other plastics, built-in foam insulation also analyzed recognition of fire hazards approach to test the conkalrorimiteo test, choedaeyeolbangchulryul through, chongbal heat, mass loss rate, generates carbon monoxide gas hazard ratio tests, analysis and evaluation rigid foam index testing the toxicity of hazardous material generated by performing a gas clean up and assess the material test results, the minimum order to provide data to quantify the risk of fire. Ensure fire safety of building materials, composite materials in order to test the various risk factors could be considered organic to the introduction of testing and evaluation is needed urgently.

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An Experimental Study on Emission Characteristics of a Semi-Bunsen Type Gas Burner (가스보일러용 세미 분젠형 버어너의 배기 특성 연구)

  • Jurng, J.S.;Park, E.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.3
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    • pp.353-358
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    • 1995
  • The emission characteristics of a semi-Bunsen type burner for gas boilers were studied experimentally. The experimental results reveal that nitric oxide emission increases with fuel flow rate. It is linearly proportional to total fue flow rate at a small amount of fuel up to 0.4 liters per minute. It does not change significantly within the range of fuel flow rate from 0.4 to 1.2 liters per minute per nozzle and increases at large fuel flow rate. The carbon monoxide emission reveals to be dependent upon the fuel flow rate per each nozzle and the number of fuel injection nozzles. Diameter of an injection nozzle could have an effect on the emission characteristics of this type of burners. However, there is no marked change in the nitric oxide emission if the total fuel flow rate is same with different nozzle sizes.

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A Study on Synthesis and Characterization of $Ti_xZr_{1-x}C$ Solid-Solution by Self-propagation High Temperature Synthesis Method (SHS법에 의한 $Ti_xZr_{1-x}C$ 고용체의 합성 및 특성 연구)

  • 이형복;오유근;이성민
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.731-737
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    • 1997
  • TixZr1-xC(0$0^{\circ}C$, 5.1 mm/sec respectively. The relative density, three point flexural strength, and the hardness of composites, which was sintered at 190$0^{\circ}C$ for 60 min by using hot-pressing under a pressure of 30 MPa, were 99%, 525 MPa and 24 GPa respectively.

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Technical Analysis of Thermal Decomposition Characteristics of Liquid Hydrocarbon Fuels for a Regenerative Cooling System of Hypersonic Vehicles

  • Lee, Hyung Ju
    • Journal of Aerospace System Engineering
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    • v.14 no.4
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    • pp.32-39
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    • 2020
  • A technological review and analysis were performed on thermal cracking of aviation hydrocarbon fuels that circulate as coolants in regenerative cooling systems of hypersonic flights. Liquid hydrocarbons decompose into low-carbon-number hydrocarbons when they absorb a considerable amount of energy at extremely high temperatures, and these thermal cracking behaviors are represented by heat sink capacity, conversion ratio, reaction products, and coking propensity. These parameters are closely interrelated, and thus, they must be considered for optimum performance in terms of the overall heat absorption in the regenerative cooling system and supersonic combustion in the scramjet engine.

Interrelationships of Fire and Explosion Properties for Chlorinated Hydrocarbons (염화탄화수소의 화재 및 폭발 특성치 간의 상관관계)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.126-132
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    • 2002
  • By using the reference data, the empirical equations which describe the interrelationships of explosion properties and physical properties of n-chlorinated hydrocarbons have been derived. The properties which have been correlated are the lower and upper explosive limits, the stoichiometric coefficients, the heats of combustion, the carbon numbers. Also, the new equations using the mathematical and statistical methods for predicting the temperature dependence of lower explosive limits(LEL) of chlorinated hydrocarbons on the basis of the literature data are proposed. The fire and explosion properties calculated by the proposed equations in this research were a good agrement with literature data within a few A.A.P.E.(Average Absolute Percent Error) and A.A.D.(Average Absolute Deviation.) From a given explosive properties, by using the proposed equations, it is possible to predict to the fire and explosion characteristics for the other chlorinated hydrocarbons.

Removal of carbon monoxide using a solid electrolyte cell reactor (고체전해질 전지 반응기를 이용한 일산화탄소의 제거)

  • 신석재;오인환
    • Journal of the Korean Society of Safety
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    • v.11 no.3
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    • pp.112-118
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    • 1996
  • When fossil fuels are burned they produce CO gas because of incomplete combustion. If the CO gas reacts with the hemoglobin in the red blood cells, it may result in death or sequelae. Generally, the CO gas is eliminated in the form of the $$$CO_2$ gas by the oxidation reaction over the platinum catalyst. In this study, the electrochemical CO removal was investgated by using the solid electrolyte cell reactor, the type of which was represented as reactants$/Pt/Y_2O_3-ZrO_2/Pt/Air$. If the overpotential was applied to the platinum working electrode, the conversion could be changed with the overpotential applied. It was found that the oxidation rate could be increased 2.8 times higher than that of the normal condition, i. e. under open circuit conditions when $P_{co}/P_{O_2}$ was 0.5 and overpotential was 0.9V. From these results, it is concluded that the reactor used in this study is more efficient than conventional catalytic reactors.

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Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media at High Pressure Conditions (고압 분위기에서 CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구)

  • Guahk, Young Tae;Lee, Dae Keun;Kim, Seung Gon;Ko, Chang-Bog;Park, Jong-Ho
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.73-74
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    • 2015
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4/oxygen$ mixture using insulated pressurized porous media combustor. Experimentally, two cylindrical SiC foams with the different pore density were piled up in a quartz tube and fully premixed mixture was supplied in the axial direction. After stabilizing fuel-rich flame at the interface of the two foams at several pressure conditions, mole fractions of synthesis gases were measured by gas chromatography. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. As the pressure increased, the rich flammability limit, $H_2/CO$ ratio, and module M increased.

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Effect of Methanol-Gasoline Blended Fuel on Engine Performance and Reduction of Exhaust Emissions (메탄올-가솔린 혼합연료가 엔진성능과 배출물저감에 미치는 영향)

  • 조행묵;이창식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.1
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    • pp.61-65
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    • 2004
  • This paper presents the effect of methanol blended fuel on the engine performance and the reduction of exhaust emissions. In this wort, the combustion effects of methanol blended fuel in the engine was investigated for the conditions of three kinds of mixing ratios. Based on the experimental results, the output characteristics of the engine show the improvement of output performance due to the blended fuel of methanol. Also, the unburned hydrocarbon and carbon monoxide emissions are decreased in accordance with the increase of methanol blended ratio.

Extinguishment of n-heptane Pool Fire by Water Mist Containing Alkali Metal Agent (알칼리 금속염을 함유한 미분무수의 헵탄 Pool Fire 소화)

  • Park, Jae-Man;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.105-111
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    • 2005
  • An experimental study is performed for extinguishing of n-heptane pool fire by water mist containing potassium acetate as a fire suppression additive. Water mist was generated by a single pressure nozzle in a small-scale chamber. The drop size distribution of water mist was measured using laser diffraction(Malvern particle sizer). The flame temperature, oxygen concentration and carbon monoxide concentration were measured. In case of using additives, the fire extinguishing time was shorter than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing additives was increased. And also dissociated metal atoms, potassium, were reacted as a scavenger of the major radical species OH, H which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.