• 제목/요약/키워드: Combustion Radical

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메탄-공기/합성가스-공기 예혼합화염의 후류 상호 작용에 대한 연구 (A Study on Downstream Interaction between Methane-air and Syngas-air Premixed Flames)

  • 박정;권오붕;길상인;윤진한
    • 한국연소학회지
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    • 제21권1호
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    • pp.8-17
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    • 2016
  • Downstream interactions between lean premixed flames with mutually different fuels of syngas and $CH_4$ have been numerically investigated particularly on and near lean extinction limits. The interaction characteristics between lean premixed (50% $H_2$ + 50% CO)-air and $CH_4$-air flames were shown to be quite different from those between the same hydrocarbon flames. The lean extinction boundaries were of slanted shape, thereby implying strong interactions. The weaker flames had negative flame speeds on the upper extinction boundaries, whereas the weaker flame speeds on the lower extinction boundaries were both negative and positive. The results also showed that the flame interaction characteristics did not follow the general tendency with the dependency of Lewis number in downstream interactions between the same hydrocarbon flames. Importance of chemical interaction in flame characteristics is discussed in the downstream interactions between lean premixed (50% $H_2$ + 50% CO)-air and $CH_4$-air flames.

일차원 액적 배열의 화염 퍼짐에 있어서 연료의 혼합 효과에 관한 연구 (A Study on Blend Effect of Fuel in Flame Spread Along An One-Dimensional Droplet Array)

  • 박정;소림수소;신강숭
    • 한국연소학회지
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    • 제3권2호
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    • pp.1-11
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    • 1998
  • Experimental investigation on flame spread of blended fuel droplet arrays has been conducted for droplet diameters of 1.0mm and 0.75mm using high-speed chemiluminescence images of OH radical. The flame spread rate is measured with blended fuel composition, droplet diameter, and droplet spacing. Flame spread is categorized into two: a continuous mode and an intermittent one. There exist a limit droplet spacing, above which flame does not spread, and a droplet spacing of maximum flame spread, which is closely related to flame diameter. It is seen that flame spread rate is mainly dependent upon the relative position of flame zone within a droplet spacing. In case of large droplet, the increase of % volume of Heptane induces the shift of limit droplet spacing to a larger spacing since volatile Heptane plays a role of an enhancer of flame spread rate. In case of small droplet, the increase of % volume of Heptane leads to the shift of limit droplet spacing to a smaller droplet spacing. This is so because of the delayed chemical reaction time by the rapid increase of mass flux of fuel vapor for small droplet.

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메탄/순산소 혼합층에서 edge flame의 구조 (Structure of Edge Flame in a Methane-Oxygen Mixing Layer)

  • 최상규;김준홍;정석호;김종수
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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    • pp.149-156
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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과농/희박 메탄 예혼합화염의 안정성에 관한 연구 (A Study on the Stability of Rich/Lean Methane Premixed Flame)

  • 이원남;서동규
    • 한국자동차공학회논문집
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    • 제13권2호
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    • pp.170-177
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    • 2005
  • The fuel-lean premixed flame has been considered one of the most efficient ways to reduce $NO_X$ emission during a combustion process. However, it is difficult to achieve stable fuel-lean premixed flames over the wide range of equivalence ratios: therefore, the application of fuel-lean flames to a practical combustion system is rather limited. In this study, the stability characteristics of fuel-lean flames stabilized by fuel-rich flames are investigated experimentally using a slot burner as a part of the basic research for practical application such as lean burn engines. Spontaneous emission of radical species were examined to understand the stability mechanisms of rich-lean premixed flames. The presence of fuel-rich flames could significantly lower the lean limit of fuel-lean flames. The stability of a fuel-lean flame is enhanced with the increase of fuel flow rate in a fuel-rich flame; how ever, it is not sensitive to the equivalence ratio of fuel-rich flames in the range of 1.2-2.4. The mechanisms of stable rich-lean premixed flames could be understood based on the characteristics of triple flame.

비열 플라즈마에 의한 NO의 산화에서의 탄화수소 첨가 효과와 그 반응역학에 대한 수치적 연구 (Numerical Study of the Effects of Hydrocarbon Addition and Corresponding Chemical Kinetics on the Promotion of NO Oxidation in Nonthermal Plasma DeNOx Treatment)

  • 신현호;윤웅섭
    • 한국연소학회지
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    • 제5권2호
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    • pp.37-50
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

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와동과 상호작용하는 대향류 비예혼합화염의 비정상 응답특성 (Unsteady Response of Counterflow Nonpremixed Flames Interacting with a Vortex)

  • 오창보;박정;이창언
    • 한국연소학회지
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    • 제9권2호
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    • pp.10-17
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    • 2004
  • A two-dimensional direct numerical simulation is performed to investigate the flame structure of $CH_4/N_2-Air$ counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman#s detailed reaction mechanism are adopted in this calculation. To quantify the strain on flame induced by a vortex, a scalar dissipation rate (SDR) is introduced. The results show that fuel-side and air-side vortex cause an unsteady extinction. In this case, the flame interacting with a vortex is extinguished at much larger SDR than steady flame. It is also found that air-side vortex extinguishes a flame more rapidly than fuel-side vortex. The unsteady effect induced by flame-vortex interaction does not lead to a transient OH overshoot of the maximum steady concentration observed in experiment, while $HO_2$ radical increases more than the maximum steady concentration with increasing SDR. In addition, it is seen that NO and $NO_2$ are not sensitive to the unsteady variation of SDR.

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메탄/순산소 예혼합 화염의 선회 특성 (Combustion Characteristics of Methane/Oxygen Gas in Pre-mixed Swirl Flame)

  • 최원석;김한석;조주형;김용모;안국영;우타관
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.1979-1983
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    • 2008
  • The effects of carbon dioxide addition to oxygen have been investigated with swirl-stabilized premixed methane flame in a laboratory-scale pre-mixed combustor. The methane fuel and oxydant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of carbon dioxide addition to the methane fuel and different swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensity of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of dilution gas in the reaction zone.

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마이크로파가 인가된 화염에서의 화염안정성 및 오염물질 배출특성 (Characteristics of the Microwave Induced Flames on the Stability and Pollutant Emissions)

  • 전영훈;이의주
    • 한국안전학회지
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    • 제29권4호
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    • pp.23-27
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    • 2014
  • The use of electromagnetic energy and non-equilibrium plasma for enhancing ignition and combustion stability is receiving increased attention recently. The conventional technologies have adapted the electrical devices to make the electromagnetic field, which resulted in various safety issues such as high-maintenance, additional high-cost system, electric shock and explosion. Therefore, an electrodeless microwave technology has an advantage for economic and reliability compared with conventional one because of no oxidation. However, the application of microwave has been still limited because of lack of interaction mechanism between flame and microwave. In this study, an experiment was performed with jet diffusion flames induced by microwaves to clarify the effect of microwave on the combustion stability and pollutant emissions. The results show that microwave induced flames enhanced the flame stability and blowout limit because of abundance of radical pool. However, NOx emission was increased monotonically with microwave intensity except 0.2 kW, and soot emission was reduced at the post flame region.

Slit-jet 노즐을 통해 분사되는 초음파 무화 케로신 화염의 정상초음파 가진에 의한 거동 변이 (Behavioral Change of the Ultrasonic Standing Wave-affected Flame in the Reaction Zone of the Ultrasonically-atomized Kerosene Injected through a Slit-jet Nozzle)

  • 배창한;강윤형;안현종;김정수
    • 한국추진공학회지
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    • 제26권1호
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    • pp.60-67
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    • 2022
  • 본 연구는 정상초음파 가진 유무에 따른 초음파 무화 케로신 화염의 거동변이를 분석하기 위해 수행되었다. Slit-jet 노즐을 통과하며 생성된 연소영역은 DSLR, ICCD 및 초고속카메라와 슐리렌 기법을 통해 가시화되었고, 연료소모량은 정밀저울을 통해 측정하였다. 그 결과, 정상초음파 가진시, OH 라디칼의 강도가 증가하는 것이 관찰되었고 정상파장 상단부에서 최적 연소 조건이 형성됨을 확인하였다.

저부하 라디칼 착화 압축천연가스 엔진의 성능연구 (Study on the Combustion Characteristics of Light-Load RI-CNG Engine)

  • 류우;동용;염정국;정성식
    • 동력기계공학회지
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    • 제15권1호
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    • pp.11-17
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    • 2011
  • 본 연구는 라디칼 착화(Radical Ignition이하 RI) 기술을 적용한 부실직분식 CNG(Compressed Natural Gas) 엔진의 구동특성에 관한 것이다. 실험엔진은 단기통 디젤엔진을 개조하여 사용하였으며, 이는 부실식 디젤엔진처럼 연소실이 주실과 부실로 나누어져 있다. 부실에 분사된 CNG는 스파크플러그로 점화하며, 부실로 부터의 연소가스가 주실 희박 혼합기를 시켜 구동하는 엔진이다. RI 기술은 연소속도를 향상시킬 수 있다. 본 연구는 주로 저부하 RI-CNG 엔진의 성능을 연구하였다. 연료분사기간은 9 ms, 공기과잉률은 1.0, 1.2, 1.4로 하였다. 연료분사시기는 엔진의 배가밸브가 닫히는 ATDC $20^{\circ}CA$ 부터 $120^{\circ}CA$ 사이로, $20^{\circ}CA$ 간격으로 지각시켜 가며 실험하였다. 본 연구는 연료분사시기 및 공기과잉률이 연소최고압력 ($P_{max}$), 연소최고압력시기(${\Theta}_{pmax}$), 도시평균유효압력(IMEP), 사이클 변동계수($COV_{imep}$), 연소속도에 미치는 양향 등을 구하고 분석하였다.