• Title/Summary/Keyword: Colorless

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STUDIES FOR THE CHARACTER OF NANO-SIZED $TiO_2$ PARTICLE SYNTHESIZED BY MICRO-EMULSION METHOD AND GOLD-DEPOSITED $TiO_2$ PARTICLE

  • Jhun, Hyun-Pyo;Park, Jae-Kiel;Lee, Kyoung-Chul;Park, Jae-Eon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.2
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    • pp.52-69
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    • 1996
  • Nano-Sized TiO$_2$ particles with diameter between 2 and 5 nm are synthesized in Water/Triton X-100/n-Hexane microemulsion. Particles show the amorphous structure and partially hydroxide form. The optical absorbance of particles appears at 250nm and band edge at 340nm. Gold metal is deposited on the surface of TiO$_2$ particles by reduction reaction of Au(III) ion with sodium hypophosphite. The size of gold-deposited particles is 20nm, and the optical absorbance appears at 270nm and at 550nm. So particles show the red color. The dense precipitation is formed by aggregation in the TiO$_2$ nano-sized particles of about 5nm size. But the bulky precipitation is formed by agglomeration phenomena in the gold-deposited particles of 20nm size. And also gold-deposited particles is easily dispersed by being re-dispersed in PEG/Water solution. This study has compared those things measuring the SPF characteristics of the cosmetics made of the synthesized particles. If the particle size is controlled appropriately, then the SPF value will be higher, or more colorless cosmetics will be made.

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A New Rhodamine B Derivative As a Colorimetric Chemosensor for Recognition of Copper(II) Ion

  • Tang, Lijun;Li, Fangfang;Liu, Minghui;Nandhakumar, Raju
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3212-3216
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    • 2010
  • A new rhodamine-based sensor 1 was designed and synthesized by incorporating rhodamine B and benzimidazole moieties. Sensor 1 exhibits high selectivity and sensitivity to $Cu^{2+}$ in $CH_3CN$-water solution (HEPES buffer, pH = 7.0) with an obvious color change from colorless to pink. Other metal ions such as $Hg^{2+}$, $Ag^+$, $Pb^{2+}$, $Sr^{2+}$, $Ba^{2+}$, $Cd^{2+}$, $Ni^{2+}$, $Co^{2+}$, $Fe^{2+}$, $Mn^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Ce^{3+}$, $Mg^{2+}$, $K^+$ and $Na^+$ had no such color change and have no significant influence on $Cu^{2+}$ recognition process. The interaction of $Cu^{2+}$ and sensor 1 was proven to adopt a 1:1 binding stoichiometry and the recognition process is reversible.

The Dual-frequency (20/40 kHz) Ultrasound Assisted Photocatalysis with the Active Carbon Fiber-loaded Fe3+-TiO2 as Photocatalyst for Degradation of Organic Dye

  • Xiong, Shaofeng;Yin, Zhoulan;Zhou, Yuanjin;Peng, Xianzhong;Yan, Wenbin;Liu, Zhixiong;Zhang, Xiangyu
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3039-3045
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    • 2013
  • Dual-frequency ultrasound assisted photocatalysis (DUAP) method was proposed to degrade a stable organic model effluent, cresol red (CR), using the prepared $Fe^{3+}$-doped $TiO_2$ with active carbon fiber loading ($Fe^{3+}-TiO_2/ACF$) as photocatalyst. The influence of key factors, including Fe doping amount and power density of dual-frequency ultrasounds (20/40 kHz), on the degradation efficiency was investigated. The degradation efficiency rises to 98.7% in 60 min accompanied by the color removal of CR liquid samples from yellow to colorless transparent at optimal conditions. A synergy index of 1.40 was yielded by comparison with single ultrasound assisted photocatalysis (SUAP) and the photocatalysis without ultrasound assisted (UV/$TiO_2$), indicating that a clear synergistic effect exists for the DUAP process. Obvious enhancement of degradation efficiency for the DUAP process should be attributed to production of large amount of free radicals by strong cavitational effects of dual ultrasounds.

Syntheses of Colorless and Transparent Copolyimides and Comparison of the Properties of Their Copolyimides (무색 투명 폴리이미드 공중합체의 합성 및 물성 비교)

  • Ju, Jieun;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.275-280
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    • 2015
  • Two series of copolyimides (Co-PIs) were prepared by reacting 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) and 1,2,4,5-benzentetra carboxylic dianhydride (pyromellitic dianhydride) (PMDA), as dianhydrides based on 4,4'-biphthalic anhydride (BPA) and 2,2'-bis(trifluoromethyl)benzidine (TFB) by using thermal- and chemical imidizations. Co-PIs films with different dianhydride monomer compositions were compared in terms of their thermal properties and optical transparencies. The addition of PMDA was more effective than the addition of 6FDA for improving the thermal properties. Meanwhile, 6FDA is more effective in optical transparencies.

Characteristics of a Modified Nuruk Made by Inoculation of Traditional Nuruk Microorganisms (전통 누룩미생물들로 제조한 개량누룩의 특성)

  • 소명환
    • The Korean Journal of Food And Nutrition
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    • v.12 no.3
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    • pp.219-225
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    • 1999
  • In order to improve the quality of nuruk a Korean traditional fermenting agent for brewing nuruk was modified by a new method inoculating Rhizopus japonicus T2 Aspergillus oryzae L2 and hansenula sp. BC26 which had been isolated from traditional Nuruk. And the characteristics of modified Nuruk were investimgated as compared with current fermenting agents such as commercial Nuruk and rice koji of As-pergillus kawachii. The odor of modified Nuruk was savory but those of commercial Nuruk and rice koji were fetid andinodorous repectively. The extracted waters of modified Nuruk commercial Nuruk and rice koji were yellow pale yellow and colorless and showed 6.15, 6.01 and 3.30 of pH respectively. Mod-ified Nuruk had 7.6${\times}$106CFU/g of yeast but commercial uruk and rice koji had no yeast. Commercial Nuruk had 1.0${\times}$102CFU/g of lactic acid bacteria but modified Nuruk and rice koji had no lactic acid bacteria. The amylolytic and proteolytic activities of modified Nuruk were much higher than those of commercial Nuruk or rice koji. Seed mash of modified Nuruk had ester aroma but that of commercial Nuruk rather offensive odor and that of rice koji neither ester aroma or offensive odor. It seemed that if the modified Nuruk is used in seed mashing the supplement of acidulant is need to lower pH. The quality of modified Nuruk was thought to be much better than that of commercial Nuruk or rice koji.

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Screening of In vitro DNA-binding Activity from the Crude Drugs (생약으로부터 In vitro DNA 결합활성의 검색)

  • Kim, Youn-Seol;Jeong, Sei-Joon;Shin, Hwa-Woo;Kim, Youn-Chul
    • YAKHAK HOEJI
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    • v.42 no.2
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    • pp.144-148
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    • 1998
  • One hundred and seventeen crude drugs were screened for DNA-binding activity in vitro. The DNA-methyl green assay is a useful biochemical screen for the detection or development of biologically active compounds which bind to DNA. This assay is based upon the fact that free methyl green undergoes rapid spontaneous molecular rearrangement to its colorless carbinol base so that the liberation of the dye from DNA by displacement can be followed spectrophotometrically as a decrease in absorbance at 65Onm. Seven methanolic extracts of crude drugs including Cinnamomi Cortex spissus, Coicis Semen, Coptidis Rhizoma, Perillae Semen, Plantaginis Semen, Polygalae Radix and Zanthoxyli Fructus showed less than 2,000${\mu}$g/ml as their $IC_{50}$ values. The active principles of Plantaginis Semen and Zanthoxyli Fructus were transferred into organic solvents, which showed the $IC_{50}$ values with 588 and 574${\mu}$g/ml, respectively. These fractions have been selected for isolation of biologically active constituents.

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Radon Adsorption Characteristics of Blast Furnace Slag Matrix Using Bamboo Activated Carbon (대나무 활성탄을 활용한 고로슬래그 경화체의 라돈흡착 특성)

  • Park, Chae-Wool;Lee, Jae-Hun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.27-28
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    • 2019
  • Recently, a bed company detected a radon more than Red Politics and became a hot topic of conversation. This has led to increased interest in radon, and a number of free-of-charge bodies have also been established to recognize the dangers of radon. In addition, the Korean Institute of Geological and Resource Research is planning to assist the installation of radon alarm systems in 10,000 households nationwide, free of charge. Since radon is a colorless, odorless and tasteless gas that causes lung cancer, it aims to reduce lung cancer incidence by absorbing radon using bamboo activated carbon as a way to reduce it. Due to the use of bamboo activated carbon, radon concentration per hour tends to decrease as substitution rate increases, and table flow tends to decrease as substitution rate increases. Through this experiment, 30% of the replacement rate of bamboo activated carbon is judged to be the most suitable replacement rate.

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Pore Properties of Magnesium Oxide Matrix using Red Mud and Vermiculite (버미큘라이트 및 레드머드를 활용한 산화마그네슘 경화체의 공극 특성)

  • Lim, Hyun-Ung;Lee, Won-Gyu;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.120-121
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    • 2018
  • Radon is one of the substances that pollute the indoor air and is classified as a first-level carcinogen by the International Agency for Research on Cancer(IARC) together with asbestos, and it is reported that it can cause lung cancer. The World Health Organization(WHO) reports that lung cancer is the second leading cause of lung cancer, and 6-15% of lung cancer patients report lung cancer caused by radon. Radon occurs in cracks in concrete and aged buildings, and is detected in soil, rocks, groundwater, and so on. It is a colorless, odorless and tasteless gas which is adsorbed to dust in the air and enters through human respiratory system. This study used vermiculite (expanded vermiculite), which has excellent ion exchange ability and a large number of pores, and industrial by - product red mud which has heavy metal adsorption ability, in order to adsorb radon. A matrix capable of adsorbing radon was prepared, and the characteristics of each material were compared and analyzed.

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A Study on Developing Safety and Health Information Database of Pesticide Ingredients Used in Korea (국내 유통되는 농약 유효성분에 대한 안전보건정보 데이터베이스 구축)

  • Lim, Kyong-Che;Choi, Sang-Jun
    • Journal of the Korea Safety Management & Science
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    • v.12 no.3
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    • pp.27-35
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    • 2010
  • In this study, we have developed the database of safety and health information for pesticide active ingredients used in Korea. There were 1,283 pesticide items among which 296 were found to be out of use in current. A total of 349 pesticide ingredients were being used in Korea. The database consists of 32 types of information including chemical characteristics, acute toxicity, chronic toxicity (carcinogenic and reproductive toxicity), specific symptoms by exposure route and first aid. When pesticide ingredients were assessed in terms of key properties such as color, odor, acute toxicity, carcinogenic and reproductive toxicity, they were white, colorless and odorless, in general. When ingredients were classified by category of acute toxicity, 'Non-hazardous' represented 29%, followed by 'Slightly hazardous' at 16%, 'Moderately hazardous' at 14%, 'Highly hazardous' at 5%, and 'Extremely hazardous' at 2%. 85 out of 349, or 24% of ingredients were found to be possibly carcinogenic to human. This database is expected to provide an easy access for farmers, agriculture supervisors, researchers and consumers, and it can ultimately be used as basic data on farmer's safety and health.

A Case of Intoxication of Ingested Formalin (포르말린에 의한 급성 중독 1례)

  • Baek, Seon-Hee;Kim, Kyung-Hwan;Park, Jun-Seok;Shin, Dong-Wun;Roh, Jun-Young;Lee, Kyoung-Mi;Kim, Ah-Jin
    • Journal of The Korean Society of Clinical Toxicology
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    • v.7 no.1
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    • pp.38-40
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    • 2009
  • Formalin is a water-soluble, colorless, pungent, irritating and highly reactive gas. A 40% solution of formaldehyde in water, also known as formalin, is used as a disinfectant, antiseptic, deodorant, tissue fixative and embalming fluid. Ingestion can lead to immediate deleterious effects on almost all systems of the body including gastrointestinal tract, central nervous system, cardiovsacular system and hepato-renal system, causing gastrointestinal hemorrhage, cardiovsacular collapse, unconsciousness or convulsions, severe metabolic acidosis and acute respiratory distress syndrome. We treated a 39-year-old woman who ingested 300 ml formalin in a suicidal attempt. Despite hemodialysis, death occurred after 23 h.

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