• Title/Summary/Keyword: Colloidal nanoparticles

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Microstructure and Magnetic State of Fe3O4-SiO2 Colloidal Particles

  • Kharitonskii, P.V.;Gareev, K.G.;Ionin, S.A.;Ryzhov, V.A.;Bogachev, Yu.V.;Klimenkov, B.D.;Kononova, I.E.;Moshnikov, V.A.
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.221-228
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    • 2015
  • Colloidal particles consisted of individual nanosized magnetite grains on the surface of the silica cores were obtained by two-stage sol-gel technique. Size distribution and microstructure of the particles were analyzed using atomic force microscopy, X-ray diffraction and Nitrogen thermal desorption. Magnetic properties of the particles were studied by the method of the longitudinal nonlinear response. It has been shown that nanoparticles of magnetite have a size corresponding to a superparamagnetic state but exhibit hysteresis properties. The phenomenon was explained using the magnetostatic interaction model based on the hypothesis of iron oxide particles cluster aggregation on the silica surface.

Comparative Analyses of Commercial Detonation Nanodiamonds

  • Puzyr, A.P.;Burova, A.E.;Bondar, V.S.;Rhee, C.K.;Rhee, W.H.;Hwang, K.C.
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.297-302
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    • 2011
  • Colloidal stability is one of crucial factors for many applications of nanodiamond. Despite recent development, nanodiamonds available on the market often exhibit a high impurity content, wide size distribution of aggregates and low resistance to sedimentation. In the current study, four commercial nanodiamond powders synthesized by detonation synthesis were surface modified and then separated with respect to the size into six fractions by centrifugation. The fractions were evaluated by zeta potential, particle size distribution and elemental composition. The results showed that the modified nanodiamonds form stable colloidal suspensions without sedimentation for a long time.

Colloidal Photonic Crystals with Quasi-Amorphous Structure: Angle-Independent Electrically Tunable Full Color Photonic Pixels

  • Kim, Dae-Hyeon;Jeong, Jae-Yeon;Ji, Seung-Uk;Gang, Yeong-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.278-278
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    • 2010
  • Electrically tunable photonic band gap (PBG) materials based on crystalline structures have been developed for active components of display. Despite considerable advances, the intrinsic drawbacks of the crystalline PBG materials such as the strong angle dependent hue and difficulty of fabricating defect-free structures in large area have yet to be addressed for their practical applications. Here we report quasi-amorphous colloidal structures exhibiting angle-independent photonic colors in response to the electric stimuli. Moderately polydisperse colloidal Fe3O4@SiO2 nanoparticles dispersed in organic solvents exclusively form quasi-amorphous photonic materials at sufficiently high concentrations (> 30 wt%), and which reversibly reflect incident light in visible region ($\lambda$ peak = 490~655 nm) in response to the relatively low bias voltage (0~4 V). We show the angle-independent tunable photonic colors with the fast response time (50~170 ms) due to the isotropic nature of quasi-amorphous structures. Conventional vacuum injection technique is applicable for fabricating flexible full color photonic display pixels with various pre-defined shapes.

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Pulsed laser ablation of hydroxyapatite in ethanol

  • Lee, Jung-Il;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.5
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    • pp.219-223
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    • 2014
  • Pulsed laser ablation in liquid medium was successfully employed to synthesize hydroxyapatite colloidal nanoparticles. The crystalline phase, particle morphology, size distribution and microstructure of the hydroxyapatite nanoparticles were investigated in detail. The obtained hydroxyapatite nanoparticles had spherical shape with sizes ranging from 5 to 20 nm. The laser ablation and the nanoparticle forming process were discussed with explosive ejection mechanism by investigating change of surface morphology on target. The analytical results of XPS, FT-IR and Raman spectroscopy confirms that the stoichiometry and bonding properties of the hydroxyapatite nanoparticles are in good agreement with reported bulk hydroxyapatite materials.

A Novel Deposition Method of PLGA Nanoparticles on Coronary Stents

  • Joo, Jae-Ryang;Nam, Hye-Yeong;Nam, So-Hee;Baek, In-Su;Pakr, Jong-Sang
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1085-1087
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    • 2009
  • Bare metal stents which were used to treat coronary artery disease have several biochemical problems. Polymerbased drug-eluting stents (DES) have opened up a new paradigm in the treatment of in-stent restenosis. Many studies and research programmes have proved that DES can prevent restenosis. In our study, paclitaxel-loaded poly (lactic-co-glycolic acid) (PLGA) nanoparticles have been deposited along the three dimensional scaffold of coronary stents by a method using self-assembling properties of colloidal particles. We found that the nanoparticles were deposited uniformly and closely packed. The amount of paclitaxel was easily controlled by the drug content of the nanoparticles and the deposition count.

Colloidally stable organic-inorganic hybrid nanoparticles prepared using alkoxysilane-functionalized amphiphilic polymer precursors and mechanical properties of their cured coating film

  • Kim, Nahae;Li, Xinlin;Kim, Se Hyun;Kim, Juyoung
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.209-219
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    • 2018
  • Colloidally stable organic-inorganic (O-I) hybrid nanoparticles could be prepared using an alkoxysilanefunctionalized amphiphilic polymer (AFAP) precursor. O-I hybrid sols could maintain colloidal stability for six months even at 45% solid content and be coated onto glass as well as PET film to form transparent O-I hybrid films. The formation of O-I hybrid nanoparticles dispersed in cured coating films could be confirmed using scanning electron microscopy. The cured coating film showed 3H and 5H pencil hardness on PET and glass, respectively. Nanoindentation measurements also showed that their modulus and hardness was varied with the type of AFAP used in its preparation.

Synthesis and Optoelectronic Characteristics of Ag2Se Nanoparticle for NIR Sensor Application (근적외선 센서를 위한 Ag2Se 나노 입자 합성 및 광전기적 특성)

  • Jang, Jaewon
    • Journal of Sensor Science and Technology
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    • v.28 no.4
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    • pp.266-269
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    • 2019
  • In this study, $Ag_2Se$ nanoparticles were synthesized by employing the colloidal method. The synthesized $Ag_2Se$ nanocrystals were spherical in shape with a diameter of approximately 4 nm and had high crystallinity. These attributes of $Ag_2Se$ nanocrystals were determined through images obtained from a high resolution transmission electron microscope. Thin films comprising the synthesized $Ag_2Se$ nanoparticles had an optical band gap of 1.5 eV. Furthermore, fabricated NIR sensors comprising $Ag_2Se$ nanoparticles exhibited a high detectivity of $5.5{\times}10^9$ Jones (above $1{\times}10^9$) at room temperature, leading to low power consumption

Effects of Colloidal Silver Nanoparticles on Sclerotium-Forming Phytopathogenic Fungi

  • Min, Ji-Seon;Kim, Kyoung-Su;Kim, Sang-Woo;Jung, Jin-Hee;Lamsal, Kabir;Kim, Seung-Bin;Jung, Moo-Young;Lee, Youn-Su
    • The Plant Pathology Journal
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    • v.25 no.4
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    • pp.376-380
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    • 2009
  • Effects of silver nanoparticles on the phytopathogenic fungal growth were investigated. Fungal phytopathogens, especially for sclerotium-forming species Rhizoctonia solani, Sclerotinia sclerotiorum and S. minor, were selected due to their important roles in survival and disease cycle. Tests for the fungal hyphal growth revealed that silver nanoparticles remarkably inhibit the hyphal growth in a dose-dependent manner. Different antimicrobial efficiency of the silver nanoparticle was observed among the fungi on their hyphal growth in the following order, R. solani > S. sclerotiorum > S. minor. Tests for the sclerotial germination growth revealed that the nanoparticles showed significant inhibition effectiveness. In particular, the sclerotial germination growth of S. sclerotiorum was most effectively inhibited at low concentrations of silver nanoparticles. A microscopic observation revealed that hyphae exposed to silver nanoparticles were severely damaged, resulting in the separation of layers of hyphal wall and collapse of hyphae. This study suggests the possibility to use silver nanoparticles as an alternative to pesticides for scleotium-forming phytopathogenic fungal controls.

Dispersion of SmxCe1-xO2-2/x Nanoparticles which is Synthesized by Hydrothermal Process in Aqueous System (수열합성법으로 합성된 나노 SmxCe1-xO2-2/x 분말의 수계 분산)

  • Bae Dong-Sik;Kim Eun-Jung;Han Kyong-Sop
    • Korean Journal of Materials Research
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    • v.15 no.2
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    • pp.112-114
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    • 2005
  • Dispersion stability of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles, which was produced by hydrothermal process, was studied in aqueous suspension using ESA (Eletrokinetic Sonic Amplitude). The average particle size of the synthesized $Sm_xCe_{1-x}O_{2-2/x}$ at nanoparticles was about $5{\pm}2nm$. The dispersion and rheological behavior of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles aqueous suspension was investigated using $NH_4OH\;and\;HNO_3$ as a disperse agent. The colloidal stability of aqueous suspensions with $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles at different pH values has been investigated by means of zeta potential, average particle size, and the distribution of synthesized $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles. The isoelectric point of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles was at pH around 11 and the value of zeta potential was at its maximum near pH 6.5.

Photocurrent Characteristic of CdTe nanoparticles (CdTe 나노입자를 이용한 광전류 특성)

  • Kim, Jin-Hyong;Cho, Kyoung-Ah;Kim, Hyun-Suk;Lee, Joon-Woo;Park, Byoung-Jun;Kim, Sang-Sig
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.37-40
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    • 2004
  • CdTe nanoparticles were synthesized in aqueous solution by colloidal method. The absorption and photoluminescence(PL) spectrum of the synthesized CdTe nanoparticles revealed the strong exitonic peak in the visible region. Photocurrent of CdTe nanoparticles were observed in the structure of Al/CdTe/ITO that was fabricated by spin coating of CdTe nanoparticles. The wavelength dependence of photocurrent was very similar to the absorption spectrum, indicating the charges generated by the absorption of photons give direct contribution to photocurrent. This study suggests that CdTe nanoparticles are very prospective materials for optoelectronics.

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