• Title/Summary/Keyword: Colloidal method

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Preparation and Characterization of High-purity Quartz Panel Using Wet-chemical Method (습식화학법을 이용한 고순도 석영유리 기판 제조 및 특성평가)

  • Park, Sung-Eun;Nam, Byeong-Uk;An, Jung-Sook;Shin, Ji-Shik;Oh, Han-Seog
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.4
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    • pp.33-38
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    • 2007
  • Quartz glass panel was prepared by a colloidal silica through the heat-treatment only without any additives in wet-chemical method. This colloidal silica used in slurry process has the uniform distribution of particle size and lower cost. The results show that 6N as a degree of purity and the 86 percentage of violet transmittance in 1mm thickness. AFM(Atomic Force Microscopy) pattern shows that the surface roughness are less than lnm. Also, we investigated the characteristic of quartz panel according to the concentration and distribution of hydroxyl group, viscosity and thermal expansion coefficient.

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PEDOT:PSS Thin Films with Different Pattern Structures Prepared Using Colloidal Template

  • Yu, Jung-Hoon;Lee, Jin-Su;Nam, Sang-Hun;Boo, Jin-Hyo
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.254-260
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    • 2014
  • Organic solar cells have attracted extensive attention as a promising approach for cost-effective photovoltaic devices. However, organic solar cell has disadvantage of low power conversion efficiency in comparison with other type of solar cell, due to the recombination ratio of hole and electron is too large in the active layer. Thus we have change the surface structure of PEDOT:PSS layers to improve the current density by colloidal lithography method using various-size of polystyrene sphere. The two types of coating method were applied to fabricate the different pattern shape and height, such as spin coating and drop casting. Using the organic solvent, we easily eliminate the PS sphere and could make the varied pattern shapes by controlling the wet etching time. Also we have measured the electrical properties of patterned PEDOT:PSS film to check whether it is suitable for organic photovoltaics.

A Study on the RuO2 Electrode Catalyst Prepared by Colloidal Method (콜로이드법으로 합성한 RuO2 전극촉매의 연구)

  • PARK, JIN-NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.193-200
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    • 2019
  • $RuO_2$, $PtO_2$, and various $(Ru,Pt)O_2$ colloidal solution were prepared using modified Watanabe method. Electrodes were manufactured by dipping of Ni mesh into the colloidal solution. Manufactured electrodes were characterized by XRD, SEM, and EDS. $(Ru,Pt)O_2$ electrodes showed $RuO_2$ crystal structure and high roughness. The hydrogen evolution reaction (HER) activities were evaluated by Linear Sweep Voltammetry. 1Ru2Pt electrode showed similar activity with commercial electrode, HER potentials are -0.9 V for both.

Synthesis of Electrode Catalyst for Polymer Electrolyte Membrane Fuel Cells Using Colloidal Method (콜로이드법을 이용한 고분자전해질 연료전지용 백금전극 촉매의 제조)

  • Park, Jin-Nam
    • Clean Technology
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    • v.19 no.1
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    • pp.59-64
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    • 2013
  • Pt/carbon Electrode catalysts for PEMFC were synthesized using colloidal method. PSA (platinum sulfite acid) was used as a Pt precursor and CPA (chloroplatinic acid) was also used to replace relatively expensive PSA. Electrode catalysts prepared using PSA showed Pt particle size less than 3.5 nm and Pt yield higher than 90% in 10~40 wt% Pt loading. Electrode catalysts prepared using CPA also showed Pt particle size less than 4.4 nm and Pt yield higher than 80% in 10~40 wt% Pt loading. The MEA (membrane electrode assembly) using 20 wt% Pt/VXC72 showed equivalent I-V curve comparing with commercial electrode catalyst in single cell test.

Synthesis and Sintering of Cordierite by using Coprecipitation Method (공침법에 의한 Cordierite분말의 합성 및 소결에 관한 연구)

  • 한문희;박금철
    • Journal of the Korean Ceramic Society
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    • v.27 no.7
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    • pp.899-906
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    • 1990
  • The cordierite powders were prepared from Mg(NO3)2.6H2O, Al(NO3)3.9H2O and colloidal silica by the coprecippitation method, and the sintering behavior of the powders were investigated. Two different methods were applied for producing the precursor powders. The one was to added the aqueous solution of Mg(NO3)2.6H2O and Al(NO3)3.9H2O to NH4OH to adjust pH at 10 where the colloidal silica of pH 10 was added. The other wa to add the aqueous solution of Mg(NO3)2.6H2O and Al(NO3)3.9H2O to the colloidal silica with NH4OH to control the final mixture to be at pH 10. It was confirmed that more homogeneous powders were obtained from the latter method. The firing linear shrinkage of the powder compacts fabricated from the calcined powder between 90$0^{\circ}C$ and 110$0^{\circ}C$ was found to be larger as the calcination temperature was low. But all of them stopped shrinking around 120$0^{\circ}C$. The powder compacts, fabricated using the calcined powders at 90$0^{\circ}C$ and 95$0^{\circ}C$ for 2hours and sintered at 142$0^{\circ}C$ for 2hours, showed relative density of 93-96%, 3-point bending strength of 81-83MPa, KIC of 1.9-2.4 MPam1/2 and thermal expansion coefficient of 0.213-0.732$\times$10-6$^{\circ}C$.

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Colloidal Textile Dye-Based Dipstick Immunoassay for the Detection of Infectious Flacherie of Silkworm, Bombyx mori L.

  • Sivaprasad, V.;Nataraju, B.;Renu, S.;Datta, R.K.
    • International Journal of Industrial Entomology and Biomaterials
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    • v.6 no.1
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    • pp.27-31
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    • 2003
  • Infectious flacherie of silkworm Bombyx mori is caused by B. mori infectious flacherie virus (BmIFV) and causes severe crop loss to sericulturists. In the present study, a colloidal textile dye-based dipstick immunoassay is developed for the detection of infectious flacherie in silkworms. Colloidal textile dye (blue D2R) with Aλ$_{max}$ at 620 nm was sensitised with 500 $\mu\textrm{g}$/ml of purified anti-BmIFV IgG. The dye-antibody reagent detects purified antigen up to 10 ng/ml and BmIFV infection in diseased larval extracts $(up to a dilution of {10^-5})$ and faecal matter extracts $(up to a dilution of {10^-2})$ by forming clear blue dot within 30 min. It was observed to be stable for three months period at $4^{\circ}C$. The efficacy of textile dye-based dipstick immunoassay was on pay with HRP-based dipstick immunoassay and fluorescent antibody test, and better than latex agglutination and ouchterlony tests in the detection of BmIFV The dye-based dipstick immunoassay method provides a simple, sensitive and less expensive test for the detection of BmIFV infection in silkworms.s.

Development of chemical conversion coating technology by environment friendly method for Zn electroplated steel (아연 전기 도금 강의 환경친화적인 화성처리 기술 개발)

  • Kim, Seong-Jong;Kim, Jeong-Il;Jang, Seok-Ki
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.271-272
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    • 2006
  • Zinc confers high corrosion resistance by acting as a sacrificial anode, and a zinc coating improves the appearance of steel. Chromate conversion coating (CCC) films are still one of the most efficient surface treatments for steel. Although such films can self-repair via the dissolution of Cr(VI), dissolved Cr(VI) have adverse effects on humans, and the environment. Therefore, we examined the corrosion protection property and morphology of colloidal silica conversion films as an alternative to CCC films. The corrosion behavior was investigated in 3% NaCl solution using electrochemical techniques, including electrochemical impedance spectroscopy, open circuit potential, and the salt spray test(SST). Corrosion was implied by the appearance of red rust on the specimen surface. In corrosion resistance at 3% NaCl solution, red rust appeared at 15-20, 55-70, and 83-98 days on Zn-electroplated steel, colloidal silica conversion-coated specimens, and CCC-coated specimens, respectively. In the salt spray test, the colloidal silica film provided better corrosion protection than CCC films, i.e., red rust appeared at 96 hours on the Zn-electroplated steel sheet, at 432 hours with the CCC films, and at 888 hours with silica conversion coating.

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Photoelectric Characteristics of Nanocrystalline TiO2 Film Prepared from TiO2 Colloid Sol for Dye‐Sensitized Solar Cell

  • Hwang, Kyung-Jun;Lee, Jae-Wook;Yoon, Ho-Sung;Jang, Hee-Dong;Kim, Jin-Geol;Yang, Jin-Suk;Yoo, Seung-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2365-2370
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    • 2009
  • A working electrode in dye-sensitized solar cells was fabricated using $TiO_2$ colloidal sol prepared from titanium isopropoxide used as a starting material by applying the sol-gel method. The effect of aging times and temperatures on physical and chemical properties of $TiO_2$ sol particles was systematically investigated. Results showed that the crystallinity and average particle size of $TiO_2$ colloidal sol can be successfully controlled by the adjustment of aging time and temperature. The conversion efficiency of the repetitive dry coating films fabricated using the dried $TiO_2$ colloidal sol particles and hydroxypropyl cellulose binder (15%) was 10.31% with a high transparency.

Fabrication of Wafer-scale Polystyrene (2+1) Dimensional Photonic Crystal Multilayers Via the Layer-by-layer Scooping Transfer Technique

  • Do, Yeong-Rak;O, Jeong-Rok;Lee, Gyeong-Nam
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.11.1-11.1
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    • 2011
  • We have developed a simple synthetic method for fabricating a wafer-scale colloidal crystal film of 2D crystals in a 1D stack based on a combination of two simple processes : the self-assembly of polystyrene (PS) nanospheres at the water-air interface and the layer-by-layer (LbL) scooping transfer technique. The main advantage of this approach is that it allows excellent control of the thickness (at a layer level) of the crystals and the formation of a vertical crack-free layer over a wafer-scale (4 inch). We investigate the optical and morphological properties of the PhC multilayers fabricated using various mono-sized colloidal crystals (250, 300, 350, 420, 580, 720, and 850 nm), and mixed binary colloidal crystals (300/350 and 250/350 nm).

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Microstructure and Magnetic State of Fe3O4-SiO2 Colloidal Particles

  • Kharitonskii, P.V.;Gareev, K.G.;Ionin, S.A.;Ryzhov, V.A.;Bogachev, Yu.V.;Klimenkov, B.D.;Kononova, I.E.;Moshnikov, V.A.
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.221-228
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    • 2015
  • Colloidal particles consisted of individual nanosized magnetite grains on the surface of the silica cores were obtained by two-stage sol-gel technique. Size distribution and microstructure of the particles were analyzed using atomic force microscopy, X-ray diffraction and Nitrogen thermal desorption. Magnetic properties of the particles were studied by the method of the longitudinal nonlinear response. It has been shown that nanoparticles of magnetite have a size corresponding to a superparamagnetic state but exhibit hysteresis properties. The phenomenon was explained using the magnetostatic interaction model based on the hypothesis of iron oxide particles cluster aggregation on the silica surface.