• Journal of Korean Society for Atmospheric Environment
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• v.9 no.2
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• pp.160-167
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• 1993

As the major methanol fueled vehicle exhaust components, formaldehyde & methanol conversion over the existing commercial 3-way catalyst was examined in a labolatory tains different Ag loadings on commercial 3-way catalyst, and german commercial catalysts for methanol engine exhaust manufactured by a commercial manufacturer. Silver catalysts were prepared by the wet impregnation of silver nitrate solution on commercial 3-way catalyst. These catalysts were characterized with BET Surface area and pore size distribution. In general, the formaldehyde(HCHO) conversion of the tested catalysts was similar to that of methanol$(CH_3OH)$. At 100$^\circ$C, which is equivalent to the cold start condition, 5wt% Ag cat. showed the most excellent HCHO and $CH_3OH$ conversion. The order of activity for conversion of HCHO & $CH_3OH$ to carbon dioxide and water vapor was as follows ; 5wt% Ag/3-way cat.>2wt% Ag/3-way cat.>german cat. front(1) > german cat. rear(2) > 10wt% Ag/3-way cat.> commercial 3-wat catalyst. However there was no significant activity difference between those tested catalysts in the hot run condition of 400$^\circ$C. Therefore, it could be concluded that the Ag-modified 3-way catalyst was the most effective and practical catalyst system which could be capable of removal the HCHO and methanol at the special condition of low temperature such as cold start condition.

• Journal of ILASS-Korea
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• v.28 no.3
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• pp.150-155
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• 2023

Cold-start emissions are given great importance under the Euro-7 emission standard due to their significant impact on overall vehicle emissions. When an engine is started from a cold state, the combustion process is not yet optimized, leading to higher emissions. Hybrid vehicles, in particular, may face additional challenges, as their engine may remain inactive for extended periods, causing their catalysts to cool down and potentially become less effective in reducing emissions. In the present study, the performance of an electric heater was investigated as a means to enhance the catalyst heating during the start-up time. A simulation tool was utilized to develop a model for the gasoline exhaust aftertreatment system. The result indicates that the heater was able to increase the three-way catalyst temperature to 500℃ in 4 s using 20 kW power. In addition, the implementation of a secondary air supply resulted in reduced temperature overshoot and improved conversion efficiencies.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.7-14
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• 2002

In order to reduce exhaust omissions of spark ignition engine, it is important not only to improve catalyst conversion efficiency but also to directly reduce engine out exhaust emissions, during cold starting and warm up process. Therefore many researchers have been attracted to develop an early fuel evaporator(EFE) by Introducing a ceramic heater fur a solution of engine out exhaust emissions in SI engine. But, the performance of the EFE in MPI engine to reduce the exhaust emissions and to improve the cold startability has not been clarified yet. The purpose of this study is to evaluate the feasibility of a glow plug far EFE. Impinging spray using heated and unheated glow plug helps the vaporization of the fuel and heat up the three way catalyst sufficiently. The amount of CO, and UHC is reduced overall. The amount of NOx is higher at the initial stage, but become lower as time goes on than without glow plug.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.4
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• pp.90-96
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• 2005

The improvement of combustion stability is very important because it is closely related to the exhaust emission concentrations as well as the fuel consumption during the cold start of SI engine. In our previous studies, the spark and exhaust valve timings were retarded individually from the baseline case to increase the exhaust gas temperature far fast warmup of a close-coupled catalyst. In the study, it was found that combustion stability during cold start becomes worse when the valve timing is retarded from the baseline conditions. The spark and valve timings were simultaneously changed from the baseline conditions to find out the variation of combustion stability during cold start of an Sl engine. Through the study. retarded spark timing by $5^{\circ}$ CA helps improvement of $COV_{imep}$ by $2\%$ and $15^{\circ}C$ increase of exhaust temperature. Retarded exhaust valve timing makes the exhaust gas temperature increase by $30^{\circ}C$, but it also deteriorates the $COV_{imep}$ by $1\%$.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.5
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• pp.114-122
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• 1997

Nowadays, gasoline direct injection engines are being commercialized by virtue of improvement in control technology of spray, flow, air fuel ratio. The stratified charge type has the advantage of improving lean limit. The homogeneous type has the advantage of reducing engine-out hydrocabon emissions in the first 30 seconds after a cold start, in addition, improving transient air fuel ratio control. The vaporization and mixing if injected fuel with air has to e completed in a short time and the fuel film in cylinder and on piston has to be minimized. So, the flow and injection should be well controlled. This paper surveyed the spray characteristics of gasoline direct injection by using laser equipment and the combustion characteristics of the single cylinder engine using homogeneousas-mixture type gasoline direct injection.

• Journal of Mechanical Science and Technology
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• v.14 no.6
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• pp.699-703
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• 2000

Experiments were carried out to investigate the characteristics of the hydrocarbon (HC) emissions and to reduce cold start hydrocarbons in gasoline engines. An HC adsorber was, used and it coated was by Pd/Rh catalyst with zeolite on a honeycomb monolith. The HCs were efficiently trapped at temperatures below $100^{\circ}C by physical adsorption. After adsorption, they were reduced gradually by the catalytic oxidation of Pd/Rh catalysts as the adsorber temperature increased above $100^{\circ}C. Increasing amounts of methane, ethylene and n-butane were emitted as the fuel-air mixture became richer and the engine speed decreased. As the temperature of adsorber increased, high-number carbons into low-number carbons. Thus, the C4 concentration decreased significantly during the first 30 seconds, and the C2 concentration increased continuously.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.1
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• pp.64-70
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• 2007

Raising exhaust gas temperature during cold-start period is very crucial to improve emission performance of SI engines because it enhances the performance of catalyst in the early stage of engine start. In this study, control variables such as ignition timing, idle speed actuator(ISA) opening and fuel injection duration were extensively investigated to analyze variations in exhaust gas temperature and engine stability during cranking period. Experimental results showed that spark timing affected engine stability and exhaust gas temperature but the effects were small. On the other hand, shortened injection duration and increased ISA opening led to a significant increase in exhaust gas temperature. Under such conditions, increase in cranking time was also observed, showing that it becomes harder to start the engine. Based on these observations, a pseudo fuel-air ratio, defined as a ratio of fuel injection time to degree of ISA opening, was introduced to analyze the experimental results. In general, decrease in pseudo fuel-air ratio raised exhaust gas temperature with the cost of stable and fast cranking. On the contrary, an optimal range of the pseudo fuel-air ratio was found to be between 0.3 to 0.5 where higher exhaust gas temperatures can be obtained without sacrificing the engine stability.

• Journal of ILASS-Korea
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• v.21 no.3
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• pp.130-136
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• 2016

NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.6
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• pp.87-100
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• 2000

HC and CO emissions during the cold start contribute the majority of the total emissions in the legislated driving cycles. Therefore, in order to minimize the cold-start emissions, the fast light-off techniques have been developed and presented in the literature. One of the most encouraging strategies for reducing start-up emissions is to place the light-off catalyst, in addition to the main under-body catalyst, near the engine exhaust manifold. This study numerically consider three-dimensional, unsteady compressible reacting flow in the light-off and under body catalyst to examine the impact of a light-off catalyst on thermal response of the under body catalyst and tail pipe emission. The effect of flow distribution on the temperature distribution and emission performance have also been examined. The present results show that flow distribution has a great influence on the temperature distribution in the monolith at the early stage of warm-up process and the ultimate conversion efficiency of light-off catalyst is severly deteriorated when the space velocity is above $100,000hr^{-1}$.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.796-801
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• 2001

During cold operation period, fuel injection system directly contributes the unburned hydrocarbon formation in spark ignition engines. The relationship between injection parameters and HC emission behavior was investigated through a series of experiments. Spray behavior of port fuel injectors was characterized through a quantitative evaluation of mass concentration of liquid fuel by a patternator and PDA. 6-hole injector was found to produce finer spray than single hole one. Using a purpose-built test rig, the wall wetting fuel was measured, which was mostly affected by wall temperature. Varying coolant temperature($20{\sim}80^{\circ}C$), HC emissions were measured in a production engine. With respect to the different types of injectors, HC emission was also measured. In the 6-hole injector application, the engine produced less HC emission in low coolant temperature region. Though it produces much more amount of wetting fuel, it has the advantages of finer atomization quality. In high coolant temperature region, there was little effect between different types of injectors. The control schemes to reduce HC emissions during cold start could be suggested from the findings that the amount of fuel supply and HC emission could be reduced by utilizing fine spray and high intake wall temperature.