• Title/Summary/Keyword: Coercivity

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Effect of Annealing Temperature on Magnetic Properties of Dust Cores

  • Mitani, Hiroyuki;Akagi, Nobuaki;Houjou, Hirofumi;Kanamaru, Moriyoshi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1177-1178
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    • 2006
  • Magnetic Properties of dust cores made of mixtures of atomized pure iron powder and pure alumina powder has been investigated in the temperature range from 673 to 1073K. The effect of annealing on coercivity has been positive effect up to 973K and thus coercivity is gradually reduced form 280A/m (as-compressed) to 160A/m (973K). However, dust cores annealed at 1073K displayed a 15% increasing of coercivity by annealing at 973K. Hysteresis loss shows a tendency similar to coercivity. Microstructure observation of specimens shows grain refinement by recrystallization in the temperature range from 773 to 1073K.

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Structural and Magnetic Properties of perpendicular Recording Medium CoCrMo thin Film (수직자기기록매체 CoCrMo 박막의 구조와 자기적 성질)

  • 남인탁;홍양기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.46-46
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    • 1988
  • Structural and magnetic properties of Co-Cr-Mo films were investigated in connection with sputtering conditions. Films were prepared using a convention RF sputtering system. X-ray diffractometry, scanning electron microscopy and transmission electron microscopy were employed to investigate structure properties. Vibrating sample magnetometry was used for coercivity and saturation magnetization measurements. Co-Cr-Mo films displayed reasonable values of perpendicular coercivity and saturation magnetization for perpendicular recording media and showed good perpendicular orientation of the hcp c-axis to the film surface. Perpendicular coercivity was strongly dependent upon substrate technique showed better c-axis orientation than hose using the stationary substrate. Co-Cr-Mo films of 2.9 at. % Mo content showed maximum perpendicular coercivity and saturation magnetization. The films deposited at lower Ar pressure showed good magnetic properties. There was no explicit relationship between the columnar structure and c-axis orientation. Co-Cr-Mo films was found to have suitable structural and magnetic properties for perpendicular recording media.

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Magnetic Characterization of the Nd Based Permanent Magnet by Newly-Developed Bipolar Pulse-Type Hysteresis Loop Tracer

  • Rhee, J.R.
    • Journal of Magnetics
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    • v.4 no.3
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    • pp.73-75
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    • 1999
  • By appliying an slternate pulsed magnetic field -generated by using a sequential ignition circuit and a magnet exciting circuit- with peak value of about 10 T to the rod type Nd based magnet Nd2Fe12.7Cr1.3B with length of 5 mm and diameter of 3.6 mm, the basic magnetic properties such as saturation magnetization, residual magnetization, coercivity, maximum energy products, magnetic anisotropy and anisotropic field are investigated with obtaining the major and minor J-H loops of the magnet. The increase in coercivity due to eddy currents in ac measurement of coercivity is calculated considering eddy current loss by analyzing a wave of generating magnetic field. The average coercivity calculated for the magnet is about 12.2 kOe, anisotropy magnetic field and anisotropic constant are measured as 60 kOe 2.43 Mj/$m^3$, respectively.

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Shape Dependent Coercivity Simulation of a Spherical Barium Ferrite (S-BaFe) Particle with Uniaxial Anisotropy

  • Abo, Gavin S.;Hong, Yang-Ki;Jalli, Jeevan;Lee, Jae-Jin;Park, Ji-Hoon;Bae, Seok;Kim, Seong-Gon;Choi, Byoung-Chul;Tanaka, Terumitsu
    • Journal of Magnetics
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    • v.17 no.1
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    • pp.1-5
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    • 2012
  • The coercivity of a single 27 nm-spherical barium ferrite (S-BaFe) particle was simulated using three models: 1) Gibbs free energy (GFE), 2) Landau-Lifshitz-Gilbert (LLG), and 3) Stoner-Wohlfarth (S-W). Spherically and hexagonally shaped particles were used in the GFE and LLG simulations to investigate coercivity with the different shape anisotropies. The effect of shape was not included in the S-W model. It was found that the models using a spherical shape resulted in a coercivity higher than the models using the hexagonal shape with both shapes having the same diameter. The coercivity estimated with the S-W model was approximately the same as that for the spherical-shape models, which indicates that spherical shape has no significant effect on the particle's coercivity at nanoscale.

Coercivity Enhancement of Sintered Nd-Fe-B Magnets by Grain Boundary Diffusion with DyH3 Nanoparticles

  • Liu, W.Q.;Chang, C.;Yue, M.;Yang, J.S.;Zhang, D.T.;Liu, Y.Q.;Zhang, J.X.;Yi, X.F.;Chen, J.W.
    • Journal of Magnetics
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    • v.18 no.4
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    • pp.400-404
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    • 2013
  • Grain boundary diffusion technique with $DyH_3$ nanoparticles was applied to fabricate Dy-less sintered Nd-Fe-B permanent magnets with high coercivity. The magnetic properties and microstructure of magnets were systematically studied. The coercivity and remanence of grain boundary diffusion magnet were improved by 60% and reduced by 7% compared with those of the original magnet, respectively. Meanwhile, both the remanence temperature coefficient (${\alpha}$) and the coercivity temperature coefficient (${\beta}$) of the magnets were improved after diffusion treatment. Investigation shows that Dy is preferentially enriched as (Nd, Dy)$_2Fe_{14}B$ phase in the surface region of the $Nd_2Fe_{14}B$ matrix grains indicated by the remarkable enhancement of the magneto-crystalline anisotropy field of the magnet. As a result, the magnet diffused with a small amount of Dy nanoparticles possesses enhanced coercivity without remarkably sacrificing its magnetization.

Current Status and Research Trend of Rare-earth Permanent Magnet (희토류 영구자석의 현황 및 개발 동향)

  • NamKung, Seok;Cho, Sang-Geun;Kim, JinBae
    • Journal of the Korean Magnetics Society
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    • v.22 no.6
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    • pp.221-227
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    • 2012
  • High performance permanent magnets have become the subject of considerable attention because of the potential applications in the traction motors of hybrid and electric vehicles and wind generators. Nd-Fe-B magnets have attracted considerable interest due to a large maximum energy product. However, Nd-Fe-B magnet cannot be used in high temperature (${\sim}200^{\circ}C$) applications due to the thermal degradation of coercivity. Therefore, the development of high coercivity Nd-Fe-B permanent magnet is a challenging issue. In case of high coercivity Nd-Fe-B permanent magnet, an increment in the intrinsic coercivity can be easily achieved by substituting Nd atoms with Dy or Tb atoms. However, these heavy rare-earth elements are known to cause a decrease in remanence due to the antiferromagnetic coupling between Dy and Fe atoms. In addition, Dy is relatively expensive and being limited in quantity. Hence, a new technology that can increase the coercivity of Nd-Fe-B sintered magnet using only a small amount, or even, no amount of heavy rare-earth elements is being investigated. This article describes the research trend in reducing the heavy rare-earth elements in Nd-Fe-B magnets.

The Effect of Hydrogen Reduction Treatment on Properties of Ba-ferrite (환원처리가 Ba-ferrite의 물성에 미치는 영향)

  • 홍양기;정홍식;김현준
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.25-30
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    • 1997
  • Physical and magnetic behaviors of reduced Co-Zn-Ti-Sn substituted Ba-ferrite particles with hydrogen are different from those of reduced-pure Ba-ferrite particles. The coercivity of substituted Ba-feffite particles shows a peaking effect with the reduction temperature ranging from 250 to 520 $^{\circ}C$, while the coercivity of pure Ba-ferrite decreases monotonically. The reduction process of substituted Ba-ferrite has been found to be devided into three steps. At the first and second steps, the magneto-plumbite structure maintained. When the reduced-substituted Ba-ferrite particles are reoxidized, the coercivity is reversible at the first step but irreversible at the second step. During the third step of reduction process above 410 $^{\circ}C$. The magneto plumbite structure was collapsed with formation of $\alpha$-Fe and $BaFeO_{3-x}$ phases and consequently the coercivity distribution is broaden and the coercivity irreversible. The coercivity and saturation magnetization decreases and increases up to 130 emu/g respectively. In this study, it is found that the substituted elements prevent the magneto-plumbite structure from collapse during the reduction process and furthermore migrate from the magnetic sites of $2a+4f_{IV}$, 2b, and 12k to $4f_{VI}$ and 12k'. An increase in the coercivity before the collapse of magneto-plumbite structure is attributed to the migration of cations in hexagonal Ba-ferrite structure.

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The Effect of Mn Addition on Nitrogenation Behavior and Magnetic Properties of Sm-Fe Alloy Powder Produced by Reduction-diffusion Method (환원-확산법에 의해 제조된 Sm-Fe 합금분말의 질화거동 및 자기특성에 미치는 Mn첨가 효과)

  • Seo, Young-Taek;Baek, Youn-Kyoung;Lee, Jung-Goo;Choi, Chul-Jin
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.13-18
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    • 2013
  • In the present study, we systematically investigated the effect of Mn addition on nitrogenation behavior and magnetic properties of Sm-Fe powders produced by reduction-diffusion process. Alloy powders with only $Sm_2(Fe,Mn)_{17}$ single phase were successfully produced by the reduction-diffusion process. The coercivity of $Sm_2(Fe,Mn)_{17}$ powder rapidly increased during nitrogenation and reached the maximum of 637 Oe after 16 hours. After further nitrogenation, it decreased. In contrast, the coercivity of $Sm_2Fe_{17}$ powder gradually increased during nitrogenation for 24 hours. The coercivity of $Sm_2(Fe,Mn)_{17}$ powder was higher than that of $Sm_2Fe_{17}$ powder at the same condition of nitrogenation. It was considered that the Mn addition facilitates the nitrogenation of $Sm_2Fe_{17}$ powder and enhances the coercivity.