• 제목/요약/키워드: Coating layer behavior

검색결과 251건 처리시간 0.026초

TiN 코팅된 Ti 및 Ti-6Al-4V합금의 부식거동 (Corrosion behaviors of Cp-Ti and Ti-6Al-4V alloys by TiN coating)

  • 이순현;정용훈;최한철;고영무
    • 대한치과기공학회지
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    • 제30권1호
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    • pp.25-31
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    • 2008
  • Cp-Ti and Ti-6Al-4V alloys commonly used dental implant materials, particularly for orthopaedic and osteosynthesis because of its suitable mechanical properties and excellent biocompatibility. This alloys have excellent corrosion behavior in the clinical environment. The first factor to decide the success of dental implantation is sufficient osseointegration and high corrosion resistance between on implant fixture and its surrounding bone tissue. In this study, in order to increase corrosion resistance and biocompatibility of Cp-Ti and Ti-6Al-4V alloy that surface of manufactured alloy was coated with TiN by RF-magnetron sputtering method. The electrochemical behavior of TiN coated Cp-Ti and Ti-6Al-4V alloy were investigated using potentiodynamic (EG&G Co, PARSTAT 2273. USA) and potentiostatic test (250mV) in 0.9% NaCl solution at 36.5 $\pm$ 1$^{\circ}C$. These results are as follows : 1. From the microstructure analysis, Cp-Ti showed the acicular structure of $\alpha$-phase and Ti-6Al-4V showed the micro-acicular structure of ${\alpha}+{\beta}$ phase. 2. From the potentiodynamic test, Ecorr value of Cp-Ti and Ti-6Al-4V alloys showed -702.48mV and -319.87mV, respectively. Ti-6Al-4V alloy value was higher than Cp-Ti alloy. 3. From the analysis of TiN and coated layer, TIN coated surface showed columnar structure with 800 nm thickness. 4. The corrosion resistance of TiN coated Cp-Ti and Ti-6Al-4V alloys were higher than those of the non-coated Ti alloys in 0.9% NaCl solution from potentiodynamic test, indicating better protective effect. 5. The passivation current density of TiN coated Cp-Ti and Ti-6Al-4V alloys were smaller than that of the noncoated implant fixture in 0.9% NaCl solution, indicating the good protective effect resulting from more compact and homogeneous layer formation.

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SiCf-SiC 복합재료의 내환경 코팅 및 열, 기계적 내구성 평가 (Thermal and Mechanical Evaluation of Environmental Barrier Coatings for SiCf-SiC Composites)

  • 채연화;문흥수;김세영;우상국;박지연;이기성
    • Composites Research
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    • 제30권2호
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    • pp.84-93
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    • 2017
  • 본 논문에서는 탄화규소 섬유강화 탄화규소 복합재료에 내환경 코팅을 수행한 후, 열 기계적 특성평가에 대한 연구를 수행하였다. 초기분말은 성형공정도중 흐름성을 좋게 하기 위해 분무건조법으로 구형의 분말을 제조하였다. 내환경 코팅재는 복합재료가 산화되거나 고온 수증기와 반응하는 것을 방지하기 위해 행하여 지는데, 본 연구에서는 액상침투법(LSI)으로 제조한 복합재에 실리콘으로 본드코팅을 하고 그 위에 대기플라즈마용사법으로 뮬라이트(mullite)와 무게비로 12% 이터븀 실리케이트(ytterbium silicate)가 혼합된 복합재를 코팅하였다. 대기플라즈마 코팅공정 시 성형변수로서 분무거리를 100, 120 그리고 140 mm로 변화시켰다. 그 후 $1100^{\circ}C$의 온도에서 100시간동안 유지하는 실험과 $1200^{\circ}C$의 온도에서 열충격을 가하는 싸이클을 3000회 반복하였다. 열내구성 시험동안 계면 박리는 일어나지 않았지만, 현저한 균열들이 코팅층 내에서 발견되었다. 균열밀도와 균열의 길이는 코팅도중의 분무거리에 의존하여 변화하였다. 열 내구성 시험 후, 압흔 시험을 통해 기계적 열화거동을 분석하였는데, 시험의 방식이나 조건들이 하중-변위 곡선의 거동에 영향을 주었다.

PEMFCB금속분리판 코팅 기술 개발 : I. 표면 및 부식 특성 평가 (Development of Surface Coating Technology fey Metallic Bipolar Plate in PEMFC : I. Study on Surface and Corrosion Properties)

  • 정경우;김세융;양유창;안승균;전유택;나상묵
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.348-351
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    • 2006
  • Bipolar plate, which forms about 50% of the stack cost, is an important core part with polymer electrolyte membrane in PEMFC. Bipolar plates have been commonly fabricated from graphite meterial having high electrical conductivity and corrosion resistance. Lately, many researchers have concentrated their efforts on the development of metallic bipolar plate and stainless steel has been considered as a potential material for metallic bipolar plate because of its high strength, chemical stability, low gas permeability and applicability to mass production. However, it has been reported that its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions and an increase in contact resistance by the growth of passive film therefore, its corrosion resistance as well as contact resistance must be improved for bipolar plate application. In this work, several types of coating were applied to 316L and their electrical conductivity and corrosion resistance were evaluated In the simulated PEMFC environment. Application of coating gave rise to low interfacial contact resistances below $19m{\Omega}cm^2$ under the compress force of $150N/cm^2$. It also made the corrosion potential to shift in the posit ive direct ion by 0.3V or above and decreased the corrosion current from ca. $9{\mu}A/cm^2$ to ca. $0.5{\mu}A/cm^2$ in the mixed solution of $0.1N\;N_2SO_4$ and 2ppm HF A coat ing layer under potentiostatic control of 0.6V and $0.75V_{SCE}$ for 500 hours or longer showed some instabilities, however, no significant change in coat Ing layer were observed from Impedance data. In addition, the corrosion current maintained less than $1{\mu}A/cm^2$ for most of time for potentiostatic tests. It indicates that high electrical conductivity and corrosion resistance can be obtained by application of coatings in the present work.

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Sol-gel법으로 제조된 $\textrm{PbTiO}_3$ 박막의 온도에 따른 수축 및 응력거동 (In Situ Shrinkage and Stress Development for $\textrm{PbTiO}_3$, Films Prepared by Sol-gel Process)

  • 박상면
    • 한국재료학회지
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    • 제9권7호
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    • pp.735-739
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    • 1999
  • 본 연구에서는 sol-gel법으로 제조된 $PbTiO_3$ (PT) 단층박막내의 실시간 응력과 두께 수축거동, 그리고 다층박막의 미세경도를 온도의 함수로 측정하여 열처리에 따른 PT박막내의 물리화학적 변화를 설명하였다. 단층박막은 상온에서 $220^{\circ}C$까지 급격한 수축을 보였으며 총수축량의 83%가 이 온도구간에서 일어났다. as-spun된 박막 내에는 이미 75MPa의 인장응력이 존재하였으며 13$0^{\circ}C$부터 뚜렷이 증가하여 $250^{\circ}C$에서 147MPa의 최대 인장응력을 나타냈다. 인장응력의 급격한 감소가 일어나는 $370^{\circ}C$부터는 본격적으로 치밀화된 PT박막과 Si 기판과의 열팽창계수 차이가 주로 박막내의 응력을 결정하며, 이것은 다층박막의 미세경도가 $300^{\circ}C$ 이후에서 급격히 증가하는 사실로도 뒷받침된다. 한편 다층박막에서 단층박막과 달리 $550^{\circ}C$까지 열처리후 Perovskite 상이 많이 생성되었으며 이는 박막 두께의 증가에 따른 homogenous 핵생성 site의 증가 때문이라고 생각된다

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스핀코팅법으로 제작한 산화아연/산화구리 이종접합의 정류 및 일산화질소 가스 감지 특성 (Rectifying and Nitrogen Monoxide Gas Sensing Properties of a Spin-Coated ZnO/CuO Heterojunction)

  • 황현정;김효진
    • 한국재료학회지
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    • 제26권2호
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    • pp.84-89
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    • 2016
  • We present the rectifying and nitrogen monoxide (NO) gas sensing properties of an oxide semiconductor heterostructure composed of n-type zinc oxide (ZnO) and p-type copper oxide thin layers. A CuO thin layer was first formed on an indium-tin-oxide-coated glass substrate by sol-gel spin coating method using copper acetate monohydrate and diethanolamine as precursors; then, to form a p-n oxide heterostructure, a ZnO thin layer was spin-coated on the CuO layer using copper zinc dihydrate and diethanolamine. The crystalline structures and microstructures of the heterojunction materials were examined using X-ray diffraction and scanning electron microscopy. The observed current-voltage characteristics of the p-n oxide heterostructure showed a non-linear diode-like rectifying behavior at various temperatures ranging from room temperature to $200^{\circ}C$. When the spin-coated ZnO/CuO heterojunction was exposed to the acceptor gas NO in dry air, a significant increase in the forward diode current of the p-n junction was observed. It was found that the NO gas response of the ZnO/CuO heterostructure exhibited a maximum value at an operating temperature as low as $100^{\circ}C$ and increased gradually with increasing of the NO gas concentration up to 30 ppm. The experimental results indicate that the spin-coated ZnO/CuO heterojunction structure has significant potential applications for gas sensors and other oxide electronics.

Modern Paper Quality Control

  • Olavi Komppa
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2000년도 제26회 펄프종이기술 국제세미나
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    • pp.16-23
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    • 2000
  • The increasing functional needs of top-quality printing papers and packaging paperboards, and especially the rapid developments in electronic printing processes and various computer printers during past few years, set new targets and requirements for modern paper quality. Most of these paper grades of today have relatively high filler content, are moderately or heavily calendered , and have many coating layers for the best appearance and performance. In practice, this means that many of the traditional quality assurance methods, mostly designed to measure papers made of pure. native pulp only, can not reliably (or at all) be used to analyze or rank the quality of modern papers. Hence, introduction of new measurement techniques is necessary to assure and further develop the paper quality today and in the future. Paper formation , i.e. small scale (millimeter scale) variation of basis weight, is the most important quality parameter of paper-making due to its influence on practically all the other quality properties of paper. The ideal paper would be completely uniform so that the basis weight of each small point (area) measured would be the same. In practice, of course, this is not possible because there always exists relatively large local variations in paper. However, these small scale basis weight variations are the major reason for many other quality problems, including calender blacking uneven coating result, uneven printing result, etc. The traditionally used visual inspection or optical measurement of the paper does not give us a reliable understanding of the material variations in the paper because in modern paper making process the optical behavior of paper is strongly affected by using e.g. fillers, dye or coating colors. Futhermore, the opacity (optical density) of the paper is changed at different process stages like wet pressing and calendering. The greatest advantage of using beta transmission method to measure paper formation is that it can be very reliably calibrated to measure true basis weight variation of all kinds of paper and board, independently on sample basis weight or paper grade. This gives us the possibility to measure, compare and judge papers made of different raw materials, different color, or even to measure heavily calendered, coated or printed papers. Scientific research of paper physics has shown that the orientation of the top layer (paper surface) fibers of the sheet paly the key role in paper curling and cockling , causing the typical practical problems (paper jam) with modern fax and copy machines, electronic printing , etc. On the other hand, the fiber orientation at the surface and middle layer of the sheet controls the bending stiffness of paperboard . Therefore, a reliable measurement of paper surface fiber orientation gives us a magnificent tool to investigate and predict paper curling and coclking tendency, and provides the necessary information to finetune, the manufacturing process for optimum quality. many papers, especially heavily calendered and coated grades, do resist liquid and gas penetration very much, bing beyond the measurement range of the traditional instruments or resulting invonveniently long measuring time per sample . The increased surface hardness and use of filler minerals and mechanical pulp make a reliable, nonleaking sample contact to the measurement head a challenge of its own. Paper surface coating causes, as expected, a layer which has completely different permeability characteristics compared to the other layer of the sheet. The latest developments in sensor technologies have made it possible to reliably measure gas flow in well controlled conditions, allowing us to investigate the gas penetration of open structures, such as cigarette paper, tissue or sack paper, and in the low permeability range analyze even fully greaseproof papers, silicon papers, heavily coated papers and boards or even detect defects in barrier coatings ! Even nitrogen or helium may be used as the gas, giving us completely new possibilities to rank the products or to find correlation to critical process or converting parameters. All the modern paper machines include many on-line measuring instruments which are used to give the necessary information for automatic process control systems. hence, the reliability of this information obtained from different sensors is vital for good optimizing and process stability. If any of these on-line sensors do not operate perfectly ass planned (having even small measurement error or malfunction ), the process control will set the machine to operate away from the optimum , resulting loss of profit or eventual problems in quality or runnability. To assure optimum operation of the paper machines, a novel quality assurance policy for the on-line measurements has been developed, including control procedures utilizing traceable, accredited standards for the best reliability and performance.

니켈기 초합금의 고온산화거동과 표면개질에 관한 연구 (High temperature oxidation behavior and surface modification of Ni-based superalloys)

  • 설경원
    • 한국재료학회지
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    • 제4권2호
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    • pp.166-176
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    • 1994
  • Ni기 초합금은 Co, Cr, Mo, W등의 고용 강화 원소와 AI, Ti, Nb, Ta 등의 $\gamma '$ 석출 강화 원소로 구성되어 있다. 초합금의 기계적 성질과 내산화성을 개선하기 위하여 희토류 원소를 재료 내부에 첨가하거나, 코팅 재료로써 사용하고 있다. 이들 희토류 원소는 $Al_2O_3, Cr_2O_3$등의 산화물의 종류에 따라 산화물의 성장 속도와 밀착성에 영향을 미친다. Hf함유 Ni기 초합금 AF115와 $AI_2O_3$ 함유 MA6000초합금 2종을 이온 코터를 이용, Yttrium 표면개질후, 온도 1273K-1473K에서 고온 산화 수 산호 피막의 성장 속도, 결정립, 내부 구조 및 내박리성에 미치는 Yttrium 의 영향을 조사하였다. AF115와 MA6000 초합금에 Yttrium코팅을 한 결과 내부 산화물의 성장에 현저한 변화가 있었다. Yttrium의 표면 개질에 의하여, AF115의 경우는 $AI_2O_3$ 주성분의 입계 집중과 Hf의 우선 산확 억제되고, 삼각 형태의 내부 산화물이 plate형으로 변화되었다. MA6000의 경우 $AI_2O_3$ 주성분의 산화층이$Cr_2O_3$주성분의 외부 산화층과$AI_2O_3$ 주성분의 내부층으로 변화되었다.

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LSC가 코팅된 고체산화물 연료전지용 금속연결재의 특성 연구 (Characteristics of LSC coated Metallic Interconnect for Solid Oxide Fuel Cell)

  • 표성수;이승복;임탁형;박석주;송락현;신동열
    • Korean Chemical Engineering Research
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    • 제48권2호
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    • pp.172-177
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    • 2010
  • 본 논문에서는 SOFC 금속연결재로서 Crofer22APU를 적용하고자 표면에 전도성 산화막($La_{0.8}Sr_{0.2}CoO_3$)을 습식코팅 후, SOFC 작동환경에서 산화거동, 전기적 특성변화 및 미세구조 변화를 관찰하였다. 코팅 전 샌드블러스트 장치를 이용한 Crofer22APU 표면처리를 통하여 코팅막/금속의 접합특성을 개선시킬 수 있었으며, 320 mesh의 입자크기를 갖는 알루미나 분말을 이용하여 표면처리한 경우 접착특성이 극대화되었다.$La_{0.8}Sr_{0.2}CoO_3$ 코팅된 시편의 전기적 특성 평가는 4-wire 법을 이용하여 SOFC 작동환경에서 약 4,000 시간 장기성능 평가하였으며 $12mW{\cdot}cm^2$의 낮은 면저항값을 얻을 수 있었다. 실험종료 후 미세구조 분석결과에서도 전도성 산화막($La_{0.8}Sr_{0.2}CoO_3$) 코팅이 금속의 부식으로 인한 산화층의 생성속도를 늦추고 이로 인한 금속의 전기적 특성이 감소하는 것을 방지하는데 유효함을 확인하였다.

LSC/GDC (50 : 50 vol%) 활성층이 LSCF/GDC (20 : 80 vol%) 복합 분리막의 산소투과 거동에 미치는 영향 (The Effect of LSC/GDC (50 : 50 vol%) Active Layers on Oxygen Transport Properties of LSCF/GDC (20 : 80 vol%) Dual-phase Membrane)

  • 차다솜;유충열;주종훈;유지행;한문희;조철희
    • 멤브레인
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    • 제24권5호
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    • pp.367-374
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    • 2014
  • 본 연구에서는 LSCF/GDC (20 : 80 vol%) 복합 분리막 표면에 LSC/GDC (50 : 50 vol%) 활성층을 코팅한 후 활성층의 열처리 온도, 두께, 침투법을 이용한 STF 도입이 산소투과 특성에 미치는 영향을 고찰하였다. 활성층 도입은 복합 분리막의 산소 투과 유속을 급격히 증진시켰으며 이는 활성층 성분인 LSC/GDC (50 : 50 vol%)가 전자 전도성 및 표면 산소 분해 반응을 증진시켰기 때문이었다. 활성층의 열처리 온도가 $900^{\circ}C$에서 $1000^{\circ}C$로 증가한 경우, 산소 투과 유속은 증가하였고 이는 분리막과 활성층 사이 그리고 활성층의 결정입간 접촉이 증진하여 산소이온과 전자 흐름을 증진시켰기 때문으로 설명되었다. 코팅층의 두께가 약 $10{\mu}m$에서 약 $20{\mu}m$로 증가한 경우, 산소 투과 유속은 오히려 감소하였는데 이는 코팅층의 두께가 증가할수록 기공을 통한 공기 중의 산소 유입이 어려워지기 때문으로 설명되었다. 또한, 코팅층에 침투법을 이용하여 STF를 도입한 경우가 STF를 도입하지 않은 경우 보다 높은 산소 투과 유속을 보였는데 이는 도입된 STF가 산소 분해하는 표면 반응 속도를 촉진시키기 때문이다. 본 연구로부터 LSC/GDC (50 : 50 vol%) 활성층 코팅 및 특성 제어는 LSCF/GDC (20 : 80 vol%) 복합 분리막의 산소투과 증진에 매우 중요함을 확인하였다.

전기화학적 분석을 통해 산출된 코팅 결함율이 트라이볼로지적 특성에 미치는 영향 평가 (Influence of Coating Defect Ratio on Tribological Behavior Determined by Electrochemical Techniques)

  • 이영제;김우중;안승호;김호건;김정구;조정우
    • Tribology and Lubricants
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    • 제20권6호
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    • pp.306-313
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    • 2004
  • Many of the current development in surface modification engineering are focused on multilayered coatings, which have the potential to improve the tribological properties. Four different multilayered coatings were deposited on AISI D2 steel in this study. The prepared samples are designed as $WC-Ti_{0.6}Al_{0.4}N,\;WC-Ti_{0.53}Al_{0.47}N,\;WC-Ti_{0.5}Al_{0.5}N\;and\;WC-Ti_{0.43}Al_{0.57}N$. The multilayered coatings were investigated with respect to coating surface and cross-sectional morphology, roughness, adhesion, hardness, porosity and tribological behaviors. Especially, wear tests of four multilayered coatings were performed by using a ball-on-disc configuration with a linear sliding speed of 0.017 m/sec and a normal load of 5.38 N load. The tests were carried out at room temperature in air by employing AISI 52100 steel ball $(H_R\;=\;66) $ having a diameter of 10 mm. The surface morphology, and topography of the wear scars of samples and balls have been determined by using scanning electron spectroscopy (SEM). Also, wear mechanism was determined by using SEM coupled with energy-dispersive spectroscopy (EDS). Results have showed an improved wear resistance of the $WC-Ti_{1-x}Al_xN$coatings with increasing of Al (aluminum) concentration.