• Proceedings of the Korea Concrete Institute Conference
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• 1998.10a
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• pp.233-238
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• 1998

For substitution for crushed sand, high strength aggregate for cement and concrete using coal ash as a main material was prepared and then compared its physical properties with those of crushed sand. Effect of mix proportion change of raw materials on the property of aggregate was checked. On the basis of these experimental results we are going to comprehend the reutilization of coal ash and utilize a basic data for judging possibility the substitution of crushed sand.

• Elastomers and Composites
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• v.18 no.1
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• pp.8-12
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• 1983

The purpose of this study is to apply in various fields of products economically and practically using the characteristic of ash of holed briquette coal in maximum. According to the test results, the cure rate of ash of holed briquette coal is comparatively late. But it has shown nearly same level of physical properities compared with other fillers except hard clay and grey carbon.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.107-109
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• 2012

In Korean coal power plants, rising coal prices have recently led to the rapid utilization of low lank coals such as sub-bituminous coal with low calorific values and low ash fusion temperatures. Using these coals beyond the design range has resulted in important issues including slagging and fouling, which cause negative effects in boiler performances and unstable operations. The purpose of this study is to observe slagging and fouling characteristics resulted from burning various ranks of pulverized coals. We have tested 3 different coals: FLAME(bituminous), KCH(sub-bituminous) and MOOLARBEN(bituminous)coals in the pilot system $50kW_{th}$ scale. A stainless steel tube with preheated air inside was installed in the downstream in order to simulate water wall. Collected ash on the probe and the slag inside the furnace near burner were analyzed by SEM (scanning electron microscopy) to verify the formation degree, surface features and color changes of the pasty ash particles. Induced coupled plasma and energy dispersive X-ray spectroscopy were also performed to figure out the chemical characteristics of collected samples. As a result, KCH was observed that more slag was developed inside the walls of the furnace and on the probe than the other two kinds of coals, as shown in the calculate slagging and fouling indices as well.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.341-342
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• 2012

The effect of high ash coal which has relatively high ash content and low combustibility on unburned carbon and NOx emission was experimentally investigated at several excess air ratio and particle size conditions of four coals containing different ash content in a drop tube furnace. Flue gas was measured by Gas analyzer in order to figure out unburned carbon characteristics. The results show that the higher content of ash makes the higher unburned carbon rate, subsequent changes in NOx emission characteristics was investigated.

• Journal of Energy Engineering
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• v.27 no.1
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• pp.33-39
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• 2018

In this paper, we reviewed briefly about the barrier materials for the radioactive waste disposal. The primary concept of the radioactive waste disposal is safety. The goal of the radioactive waste management is to assure that the environment is not adversely affected and also public. There are a wide variety of materials are available for the radioactive waste disposal or storage. Among those coal fly ash is one of the significant materials are used as a barrier material. Here we reported, the Calcium sulfo aluminate (CSA) from coal fly ash is effectively suitable for the radioactive waste disposal. This is one of the ways of utilization of waste and manufactured the valuable materials for future indeeds.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.129-132
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• 2005

Reclamation coal ash, which is generated as a byproduct at a coal thermal power plant is not recycled but dumped into an ash landfill disposal site. Furthermore, various byproducts and wastes have been proposed for use from the point of reduction in the environmental load. Authors have started research to develope manufacturing technology of concrete mixture design method with large amount of land reclamation coal ash. In this study an optimum mix proportion design for utilizing the reclamation coal ash and containing copper slags as an aggregate for secondary concrete products such as a wave dissipating blocks was successfully developed.

• Journal of the Korean Chemical Society
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• v.57 no.1
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• pp.73-80
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• 2013

An efficient synthesis of quinoxalines derivatives is described using magnetic material separated from coal fly ash. Coal fly ash is a waste material generated in huge amount by burning of coal for the generation of electricity in thermal power station. It contains $SiO_2$, $Al_2O_3$ and magnetic material in significant amounts, from which magnetic material was separated by using magnetic separation method. These separated magnetic material further characterized by XPS, XRD, EDS, FTIR, SEM, TEM and BET techniques. The merits of present method are mild reaction conditions, and also excellent yields and short reaction times.

• Korean Journal of Environmental Agriculture
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• v.19 no.5
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• pp.401-418
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• 2000

1. Production of the artificial zeolite from coal ash Coal fly ash is mainly composed of several oxides including $SiO_2$ and $Al_2O_3$ derived from inorganic compounds remained after burning. As minor components, $Fe_2O_3$ and oxides of Mg, Ca, P, Ti (trace) are also contained in the ash. These components are presented as glass form resulting from fusion in the process of the combustion of coal. In other word, coal ash may refer to a kind of aluminosilicate glass that is known to easily change to zeolite-like materials by hydrothermal reaction. Lots of hot seawater is disposing near thermal power plants after cooling turbine generator periodically. Using seawater in the hydrothermal reaction caused to produce low price artificial zeolite by reduction of sodium hydroxide consumption, heating energy and water cost. As coal ash were reacted hydrothermally, peaks of quartz and mullite in the ash were weakened and disappeared, and new Na-Pl peaks were appeared strengthily. Si-O-Si bonding of the bituminous coal ash was changed to Si-O-Al (and $Fe^{3+}$) bonding by the reaction. Therefore the produced Na-Pl type zeolite had high CEC of 276.7 $cmol^+{\cdot}kg^{-1}$ and well developed molecular sieve structure with low concentration of heavy metals. 2. Utilization of the artificial zeolite in agro-environment The artificial zeolite(1g) could remove 123.5 mg of zinc, 164.7 mg copper, 184.4 mg cadmium and 350.6 mg lead in the synthetic wastewater. The removability is higher 2.8 times in zinc, 3.3 times in copper, 4.7 times in cadmium and 4.8 times in lead than natural zeolite and charcoal powder. When the heavy metals were treated at the ratio of 150 $kg{\cdot}ha^{-1}$ to the rice plant, various growth inhibition were observed; brownish discoloration and death of leaf sheath, growth inhibition in culm length, number of panicles and grains, grain ripening and rice yield. But these growth inhibition was greatly alleviated by the application of artificial zeolite, therefore, rice yield increased $1.1{\sim}3.2$ times according to the metal kind. In addition, the concentration of heavy metals in the brown rice also lowered by $27{\sim}75%$. Artificial Granular Zeolites (AGZ) was developed for the purification of wastewater. Canon exchange capacity was 126.8 $cmol^+{\cdot}kg^{-1}$. AGZ had Na-Pl peaks mainly with some minor $C_3S$ peaks in X-ray diffractogram. In addition, AGZs had various pore structure that may be adhere the suspended solid and offer microbiological niche to decompose organic pollutants. AGZ could remove ammonium, orthophosphate and heavy metals simultaneously. Mixing ratio of artificial zeolite in AGZs was related positively with removal efficiency of $NH_4\;^+$ and negatively with that of $PO_4\;^{3-}$. Root growth of rice seedling was inhibited severely in the mine wastewater because of strong acidity and high concentration of heavy metals. As AGZ(1 kg) stayed in the wastewater(100L) for 4days, water quality turned into safely for agricultural usage and rice seedlings grew normally.

• Journal of Radiation Protection and Research
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• v.24 no.4
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• pp.187-193
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• 1999

The specific radioactivity concentrations in the coal fly ash obtained from heat producing stations in Korea were analyzed and its radiological hazard for reuse in construction purpose was evaluated. The concentrations of uranium isotopes in the real fly ash measured by TBP solvent extraction method and $\alpha$-spectrometer were found to be about 116.1 Bq $kg^{-1}$ for $^{238}U$, 5.01 Bq $kg^{-1}$ for $^{235}U$, and 121.2 Bq $kg^{-1}$ for $^{234}U$, respectively. The activity ratio of $^{234}U/^{238}U$, in the coal fly ash was in $1.04\;{\pm}\;0.03$, which is similar to that of uncontaminated Korean soil in natural conditions (1.14). The specific radioactivities of $^{226}Ra,\;^{232}Th,\;and\;^{40}K$ in the coal fly ash were also determined using $\gamma$-spectrometer with a HPGe detector The results showed that $^{226}Ra,\;^{232}Th,\;and\;^{40}K$ in the coal fly ash were in concentrations of $101.7{\sim}113.9$, $39.5{\sim}54.2\;and\;315.0{\sim}990.6$ Bq $kg^{-1}$, respectively. With the specific radioactivities obtained from $\gamma$-spectrometric measurements of the coal fly ash, its radiological hazard for reuse was evaluated. The result showed that the radioactivity of the coal fly ash was in permissible level.

• Journal of Energy Engineering
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• v.11 no.1
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• pp.67-73
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• 2002

The carbon-in-ash system for simultaneously monitoring the unburned carbon in fly ash produced in a coal-fired power plan is designed and evaluated using the domestic fly ash produced in the coal-fired power plant. Real time monitoring is very important to control the combustion of the boiler in the coal-fired power plant and the purification system for fly ash recycling. The carbon-in-ash system based on the capacitance measurement consists of a LCR meter, a duct collector and an electrode cell. The capacitance of fly ash increases linearly with increasing fly ash carbon contents. The water content in fly ash plays an important role on the ash capacitance. The empirical equation for predicting the content of unburned carbon in fly ash produced in the domestic Boryung, Hadong and Samchenpo coal-fired power plants can be derived in the range of carbon content 0-20%.