• Title/Summary/Keyword: Coal waste

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Evaluation of Field Applicability with Coal Mine Drainage Sludge (CMDS) as a Liner: Part I: Physico-Chemical Characteristics of CMDS and a Mixed Liner (차수재로의 광산슬러지 재활용 적용성 평가: Part I: 광산배수슬러지 및 혼합차수재의 물리·화학적 성질)

  • Lee, Jai-Young;Bae, Sun-Young;Woo, Seung-Hyun
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.2
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    • pp.67-72
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    • 2011
  • CMDS (Coal Mine Drainage Sludge) is mainly generated from acid mine drainage during physicochemical treatment or electrical purification. CMDS is well worth considering on recycling possibilities in various areas. This research applies the liner and cover materials using waste disposal landfill generally to treat acid mine drainage sludge. In this Part I of the two parts paper, physico-chemical characteristics of CMDS, bentonite and cement to prepare the liner have been identified using XRD, XRF, FESEM. In addition, combining their physicochemical characteristics, the optimum mixing ratio has been determined to be 1: 0.5: 0.3 for CMDS: bentonite: cement by the batch tests. Initial permeability of CMDS was $7.10{\times}10^{-7}cm/s$. Through the leaching test, it was confirmed that its mixture was environmentally safe. In the Part 2, a large-scale Lysimeter was used to simulate the effects of the layer on the freeze/thaw for evaluation on field applicability and stability.

Effect of Contamination by the Abandoned Coal Mine Drainage on the Stream Water in Keumsan, Chungnam (금산(錦山) 폐탄광지역(廢炭鑛地域)의 오염(汚染)이 하천수(河川水)에 미치는 영향(影響))

  • Kim, Myung Hee;Min, Ell Sik;Song, Suckhwan
    • Journal of Korean Society of Forest Science
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    • v.86 no.4
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    • pp.435-442
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    • 1997
  • The research was carried out to investigate the contamination of stream water by the acid mine drainage originated from the abandoned coal mines and coal waste rock in Keumsan, Chungnam. The pH, sulfate and chemical compositions in the stream water were analyzed. At the polluted sites, the pH of stream water was the strong acid, ranging from 3.46 to 4.29. The pH shows negative correlations with sulfate, manganese, copper, zinc, iron and magnesium concentrations. Sulfate concentrations of the polluted stream water, 236.73-310.53mg/l, had 10 times more than those of the non-polluted stream water. The concentrations of heavy metals, Mn and Fe, in the polluted water were 0.56 - 0.83mg/l and 5.89 - 10.58mg/l, respectively. The Mn concentrations were 20 times higher than those of the non-polluted stream water. Compared with those in the non-polluted stream water, the Mg and Ca concentrations in the polluted stream water were high because of leaching from rock and soil to water by the acidifications. Calculated AMDI(Acid Mine Drainage Index) values are low in the polluted stream water, relative to those of the non-polluted water.

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Application of Granulated Coal Ash for Remediation of Coastal Sediment (연안 저질 개선을 위한 석탄회 조립물의 활용)

  • Kim, Kyunghoi;Lee, In-Cheol;Ryu, Sung-Hoon;Saito, Tadashi;Hibino, Tadashi
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.1
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    • pp.1-7
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    • 2014
  • This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

Life Cycle Assessment on Pump and Treatment Remediation of Contaminated Groundwater (오염 지하수 양수 및 처리 공정에 대한 전과정평가)

  • Cho, Jong-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.6
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    • pp.405-412
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    • 2011
  • Environmental impact by proposed pump and treatment remediation of groundwater contaminated with TCE over 0.6 mg/L down to 0.005 mg/L was assessed for 30 years operation in an industrial park. Total amount of groundwater treated was $2.96{\times}10^7m^3$ and the amount of TCE removed was 17.6 kg at most. The life cycle assessment was used to estimate the environmental cost and environmental benefit and their effects on the environment could be analyzed. Most of the environmental cost was accrued from electricity generation for 30 years pump operation, which includes energy consumption, resources consumption such as coal, crude oil, emission of global warming gas and acid gas into air, waste water production, and waste generation. Environmental impact could be quantified with a Life Cycle Assessment (LCA) model for soil and groundwater remediation and normalized based upon consumption and emission quantities per capita in the world. Among the normalized values, acidification material release was the most significant.

Evaluation of TDF ash as a Mineral Filler in Asphalt Concrete (TDF ash를 채움재로 사용한 아스팔트 콘크리트 물성 평가)

  • Choi, MinJu;Lee, JaeJun;Kim, HyeokJung
    • International Journal of Highway Engineering
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    • v.18 no.4
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    • pp.29-35
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    • 2016
  • PURPOSES : The new waste management policy of South Korea encourages the recycling of waste materials. One material being recycled currently is tire-derived fuel (TDF) ash. TDF is composed of shredded scrap tires and is used as fuel in power plants and industrials plants, resulting in TDF ash, which has a chemical composition similar to that of the fly ash produced from coal. The purpose of this study was to evaluate the properties of an asphalt concrete mix that used TDF ash as the mineral filler. METHODS : The properties of the asphalt concrete were evaluated for different mineral filler types and contents using various measurement techniques. The fundamental physical properties of the asphalt concrete specimens such as their gradation and antistripping characteristics were measured in accordance with the KS F 3501 standard. The Marshall stability test was performed to measure the maximum load that could be supported by the specimens. The wheel tracking test was used to evaluate the rutting resistance. To investigate the moisture susceptibility of the specimens, dynamic immersion and tensile strength ratio (TSR) measurements were performed. RESULTS : The test results showed that the asphalt concrete containing TDF ash satisfied all the criteria listed in the Guide for Production and Construction of Asphalt Mixtures (Ministry of Land, Infrastructure and Transport, South Korea). In addition, TDF ash exhibited better performance than that of portland cement. The Marshall stability of the asphalt concrete with TDF ash was higher than 7500 N. Further, its dynamic stability was also higher than that listed in the guide. The results of the dynamic water immersion and the TSR showed that TDF ash shows better moisture resistance than does portland cement. CONCLUSIONS : TDF ash can be effectively recycled by being used as a mineral filler in asphalt, as it exhibits desirable physical properties. The optimal TDF ash content in asphalt concrete based on this study was determined to be 5%. In future works, the research team will compare the characteristics of asphalt concrete as function of the mineral filler types.

Experimental study on chemical activation of recycled powder as a cementitious material in mine paste backfilling

  • Liu, Yin;Lu, Chang;Zhang, Haoqiang;Li, Jinping
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.341-349
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    • 2016
  • To improve the utilization rate of construction waste as mine backfilling materials, this paper investigated the feasibility of using recycled powder as mine paste backfilling cementitious material, and studied the pozzolanic activity of recycled construction waste powder. In this study, alkali-calcium-sulfur served as the activation principle and an orthogonal test plan was performed to analyze the impact of the early strength agent, quick lime, and gypsum on the pozzolanic activity of the recycled powder. Our results indicated that in descending order, early strength agent > quick lime > gypsum affected the strength of the backfilling paste with recycled powder as a cementitious material during early phases. The strength during late phases was affected by, in descending order, quick lime > gypsum > early strength agent. Using setting time and early compressive strength as an analysis index as well as an extreme difference analysis, it was found that the optimal ratio of recycled powder cementitious material for mine paste backfilling was recycled powder:quick lime:gypsum:early strength agent at 78%:10%:8%:4%. X-ray diffraction analysis and scanning electron microscope were used to show that the hydration products of recycled powder cementitious material at the initial stages were mainly CH and ettringite. As hydration time increased, more and more recycled powder was activated. It mainly became calcium silicate hydrate, calcium aluminate hydrate, etc. In summary, recycled powder exhibited potential pozzolanic activities. When activated, it could replace cementitious materials to be used in mine backfill.

Development of moveable instrument for fuel of cement production and of clean process for cement production using waste plastics from agriculture (농업용 폐비닐을 이용한 이동식 시멘트 연료 제조 장치 및 이를 이용한 시멘트 제조 청정 공정 개발)

  • Seo, Hyung-Nam;Goo, Sang-Ser;Choi, Young-Ki;Min, Kyung-So;Kang, Seong-Gu;Oh, Hea-Kap
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.109-113
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    • 2004
  • In this study, we tried to develop the moveable instrument for fuel of cement production by using waste plastics from agriculture that was not recycled. First we investigated the burning character of recycled fuel and feasibility of second pollution. Then we made the instrument which can produce the solid fuel under 1cm size. In changing the inputting method from pre-heater to main burner, this reduces the NOx and O2 emission rate. and When we input it 0.5ton/hour, we obtain 0.2-0.3 ton/hour reduction of coal amount.

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Conversion of Wood Waste into Solid Biofuel Using Catalytic HTC Process (촉매 열수탄화(Hydrothermal carbonization)공정을 이용한 폐목재의 고형연료 제조 및 특성 연구)

  • Joo, Bokyoung;Yeon, Hyejin;Lee, Sangil;Ahn, Soojeung;Lee, Kyeongjae;Jang, Eunsuk;Won, JongChoul
    • New & Renewable Energy
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    • v.10 no.2
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    • pp.12-18
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    • 2014
  • The objective of this work is to produce solid biofuel from sawdust using the HTC (Hydrothermal carbonization) process. The HTC process of feedstock involves the raw material coming into contact with high temperature and pressurized water. The HTC process could produce gaseous, liquefied and solid products, but this study focused on solid product only as an alternative to coal. In this study, sawdust used for a feedstock and its moisture content was under 5%. Water was added with the feedstock to raise moisture content to 80% and also used catalysts. The HTC process was performed at temperature range from 200 to $270^{\circ}C$ and reaction time was 15 to 120 min. Rising temperature resulted in increasing the higher heating value (HHV) of HTC product. In case of adding catalyst, HHV of solid biofuel was higher and reaction occurred at lower temperature and pressure. Also, HTC solid product had been characterized and found to be hydrophobic, increased HHV (over 40%), and pelletized easily compared to raw material.

Synthesis of Cement Raw Materials by Melting of Industiral Wastes(II) (폐기물의 용융처리에 의한 시멘트 원료의 합성(II))

  • Hwang, Y.;Sohn, Y. U.;Chung, H. S.;Lee, H. K.;Park, H. S.
    • Resources Recycling
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    • v.6 no.1
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    • pp.29-34
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    • 1997
  • The feasibility of using the industrial inorganic waste materials such as l~mestone sludge. Soundly sand. coal fly 'ash, and chemical glasses as a raw material for cement clinker by melting treatmeut was iovestigated. The slag wh~ch is obtained from thc melts of the mixtnres of waste materials is composed of P-C,S(ZCaO - SIOJ and C,AS(ZCaO . AI,O, . SiO,) phases. The effect of melting tempcrabre, coaling condition and CIS ratio on the fo~mation of P-C,S phasc was examed. In order to obtain thc P-CiS phase which is useful in thc utilhtion as a clinkcr malcrid, it B found that sudl considerations as low melting temperature as possible of the wastc mixhire, quenching the melts and law CIS ratio of the mlxhlre are necessary.

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A study on the properties of artificial aggregates containing bottom ash from the power plant and waste catalyst slag (화력발전소 바닥재와 폐촉매 슬래그로 제조된 인공골재의 특성 연구)

  • Jo, Si-Nae;Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.4
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    • pp.200-206
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    • 2012
  • The artificial aggregate composing of coal bottom ash and waste catalyst slag (7 : 3, wt%) were fabricated using direct sintering method and, the bloating properties of aggregates were investigated as a function of raw material particle size and sintering temperature. Most of the artificial aggregates sintered at over $1150^{\circ}C$ showed the bloating phenomenon regardless of particle size of the raw materials. Consequently, the specific gravity of the aggregates was drastically decreased to below 1.4. The aggregates containing waste catalyst slag of $90{\mu}m$ under among the W-series specimens, however, did not show the noticeable bloating phenomenon. For the aggregates sintered at lower temperature as $1050{\sim}1150^{\circ}C$, the specific gravity increased with particle size of raw materials. Also, the water absorption of all aggregates decreased with the sintering temperature. The aggregates fabricated in this study met the lightweight aggregate standard showing the specific gravity 1.7~1.4 and water absorption 8~19 % and, therefore, can be applicable for the various fields.