• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.207-208
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• 2019

In this study, compressive strength was measured to evaluate the initial strength of cement mortar substituted with coal gasification slag containing desulfurized gypsum, and the reactivity of desulfurized gypsum was confirmed. In order to improve the reactivity, 2% gypsum mixed type and gypsum unfedged type specimens were fabricated and the influence of desulfurization gypsum on compressive strength of coal gasification slag and blast furnace slag fine powder replacement cement mortar was compared and confirmed. As a result of the experiment, it was confirmed that the initial compressive strength of the specimen containing the desulfurized gypsum was improved at the initial stage.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.122-123
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• 2021

This study examines the performance of pretreatment process system as the initial construction stage of the pretreatment process system to use CGS, a by-product generated in IGCC, as a concrete fine aggregate of construction materials. The process undergoes a grinding process capable of grinding to a predetermined particle size during primary grinding and a sorting plant through sieve grading of 2.5 mm or less for particle size correction. Afterwards, it is hoped that the use of coal gasification slag of Korean IGCC as a fine aggregate for concrete will be distributed and expanded by producing quality-improved CGS fine aggregate using water as a medium for removing impurities and particulates.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.528-532
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• 2009

Integrated Gasification Combined Cycle (IGCC) power plant converts coal to syngas, which is mainly composed with hydrogen and carbon monoxide, by the gasification process and produces electric power by the gas and steam turbine combined cycle power plant. The purpose of this study is to investigate the influence of gasification process to type and structure of gasifier. For this purpose, the performance characteristics of gasification reaction are analyzed with the operation characteristic of pilot-scale 2-stage coal gasifier. It is found that gasification reaction, floating characteristic of melted slag, particle stick of inside of the gasifier, particle stick and deposit of Syngas cooler are the causes in the different performance characteristics.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.11a
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• pp.159-160
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• 2018

In this study, the characteristics of the Mock-up test were reviewed to analyze the applicability of the coal gasification slag (CGS) from the integrated gasification combination Cycle (IGCC) to the concrete fine aggregate. The analysis shows that CGS and crushed sand mix is the best combination of CGS combined with about 50 % of CGS based on the effects of promoting liquidity and strength. This is expected to be a positive factor in securing the strength and flexibility of concrete given the optimal mix of CGS, and may also contribute to the improvement of quality.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.11a
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• pp.21-22
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• 2018

In this study, the characteristics of the Mock-up test were reviewed to analyze the applicability of the coal gasification slag (CGS) from the integrated gasification combination Cycle (IGCC) to the concrete fine aggregate. The analysis shows that CGS and crushed sand mix is the best combination of CGS combined with about 50 % of CGS based on the effects of promoting liquidity and strength. This is expected to be a positive factor in securing the strength and flexibility of concrete given the optimal mix of CGS, and may also contribute to the improvement of quality.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.4
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• pp.352-359
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• 2009

KEPRI is developing a Korean type coal-gasification system and the scale is 20 ton/day. Prior to this pilot plant, a 1 ton/day class gasification system will be used for pre-testing of several coal types. This paper introduces the configuration and design conditions of this 1 ton/day class system, presenting the gas/coal ratio, oxygen/coal ratio, cold gas efficiency, CFD analysis of gasifier, and others. The existing combustion furnace for residual oil was retrofitted as a coal gasifier and a vertical and down-flow type burner was manufactured. Ash removal is carried out through a water quencher and a scrubber following the quencher, and the sulfur is removed by adsorption in the activated carbon tower. The gas produced from the gasifier is burned at the flare stack. In this paper, the results of design conditions and initial operation conditions of I ton/day gasification system are compared together.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.653-662
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• 2015

In general, the coal gasification has to be operated under high temperature ($1300{\sim}1400^{\circ}C$) and pressure (30~40 bar). However, to keep this conditions, it needs unnecessary and excessive energy. In this work, to reduce the temperature of process, alkali catalysts such as $K_2CO_3$ and $Na_2CO_3$ were added into Cyprus coal. We investigated the kinetic of Cyprus char-$CO_2$ gasification. To determine the gasification conditions, the coal (with and without catalysts) gasified with fixed variables (catalyst loading, catalytic effects of $Na_2CO_3$ and $K_2CO_3$, temperatures) by using TGA. When catalysts are added by physical mixing method into Cyprus coal the reaction rate of coal added 7 wt% $Na_2CO_3$ is faster than raw coal for Cyprus char-$CO_2$ gasification. The activation energy of coal added 7 wt% $Na_2CO_3$ was calculated as 63 kJ/mol which was lower than raw char. It indicates that $Na_2CO_3$ can improve the reactivity of char-$CO_2$ gasification.

• Journal of Energy Engineering
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• v.24 no.3
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• pp.150-163
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• 2015

Gasification technology is one of the representative next-generation fossil fuel utilization technologies, converting low grade fossil fuels such as coal, heavy residue oil, pet-coke into highly clean and efficient energy sources. Accordingly, related market demand for gasification technology is ever increasing steadily and rapidly. A few years ago, conventional pulverized coal utilization technology had an edge over the gasification technology but the most significant technical barrier of limited capacity and availability has been largely overcome nowadays. Futhermore, it will be more competitive in the future with the advancement of related technologies such as gas turbine, ion transfer membrane and so on. China has recently completed a commercialization-capable large-scale coal gasification technology for its domestic market expansion and foreign export, rapidly becoming a newcomer in the field and competing with existing US and EU technical leadership at comparable terms. Techno-economic aspect deserves intensive attention and steady R&D efforts need to continue in organized, considering that gasification technology is quite attractive combined with $CO_2$ capture process and coal to SNG plant is economically viable in Korea where natural gas is very expensive. In the present paper, recent technology development and commercialization trend of many leading companies with coal gasification expertise have been reviewed with significant portion of literature cited from the recently held '2014 Gasification Technology Conference'.

• Journal of Energy Engineering
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• v.16 no.1 s.49
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• pp.32-39
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• 2007

Coal pyrolysis processes vary with the origin and rank of coal. It is difficult to generalize the characteristics of coal pyrolysis reaction because the process consists of numerous reactions including pyrolysis, gasification, and combustion. To find out the optimum process condition it is necessary to determine the condition fur each coal from the smatter scale experiment. In this study pressurized ($2kg_{f}/cm^{2}$) fluidized bed, low temperature ($735{\sim}831^{\circ}C$) gasification using Kideco coal was performed. The reaction condition and product gas composition were determined from the variables including steam flow rate, coal feed rate and air flow rate. Optimum reaction condition was determined from the concentrations of $H_{2}$, and CO in the product gas. The ratio of air/coal was 4.45 and that of steam/coal was 0.21 respectively. The concentrations of CO and $H_{2}$ decreased with the increase of $CO_{2}$. It is important to control the feed rates of coal and steam because the reaction temperature rapidly increased when the combustion reaction dominates over the gasification reaction. The concentrations of CO and $H_{2}$ were 18%, 17% respectively from the continuous operating condition.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.93-96
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• 2015

Commercial coal gasifiers typically use entrained flow type reactors, but have unique features in terms of reactor shape, gasifying agent, coal feeding type, ash/slag discharge, and reaction stages. The MHI gasifier is characterized as air-blow dry-feed entrained reactor, which incorporates a short combustion stage at the bottom and a tall gasification stage above. This study investigates the flow and reaction characteristics inside a MHI gasifier by using computational fluid dynamics (CFD) in order to understand its design and operation features. For its pilot-scale system at 200 ton/day capacity, the distribution of coal and air supply between the two reaction stages was varied. It was found that the syngas composition and carbon conversion rate were not significantly influenced by the changes in the distribution of coal and air supply. However, the temperature, velocity and flow pattern changed sensitively to the changes in the distribution of coal and air supply. The results suggest that one key factor to determine the operational ranges of coal and air supply would be the temperature and flow pattern along the narrower wall between the two reaction stages.