• 자원환경지질
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• 제28권2호
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• pp.147-154
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• 1995

Coal fly ashes collected from the Samcheonpo and the Seocheon Power Plants were analyzed for major and minor components and heavy metals such as As, Cd, Co, Cr, Cu, Ga, Hg, Mo, Ni, Pb, Sb, V and Zn in order to suggest basic data to apply coal fly ash as fertilizer or soil ameliorator. The specific gravity of the samples was less than 2.0, and amounts of organic matter range from 5.0% to 12.3%. The identified minerals by XRD were mainly quartz, mullite and pyrite in anthracite coal, and mainly quartz and mullite in bituminous coal. Generally, the contents of heavy metal elements analyzed were lower less than those of soil, though higher in some samples. Element couples of some elements( e.g., As-Mo, Zn ; Mo-As, Sb, V, Zn ; Sb-Zn ) show positive correlations with each other, but the high correlations of toxic elements such as As, Pb, Cd and Hg indicate to give attention to apply coal fly ash as fertilizer or soil ameliorator.

• 한국분말재료학회지
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• 제13권2호
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• pp.102-107
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• 2006

Recycling industrial wastes such as fly ash from a coal burning heat power plant and shell from an oyster farming were investigated to prevent environment contamination as well as to enhance the value of recycling materials. In this study, the lightweight aggregates and the red bricks were fabricated from fly ashes with other inorganic materials and wastes. The starting materials of the lightweight aggregate were fly ash powder and water glass, and the compacts of these materials were heat treated at $1100^{\circ}C$. The fabricated lightweight aggregates had low bulk density, $0.9-1.2\;g/cm^3$, hence floated on the water and had the strength of 7.0-11.0 MPa and the modulus of 2900-3300 MPa which indicates it has enough strength as the aggregate. Another type of the light weight aggregate was prepared from fly ashes, shell powders and clays. The bulk density, porosity, and compressive strength of these aggregates were $1.19-1.34\;g/cm^3,\;18.3{\sim}56.1%$ and 5-12 MPa, respectively. The addition of a small amount of fly ash powder prevented hydration of the light weight aggregates. The red brick was also fabricated from the fly ash containing materials. It is suitable for the brick facing of a building as it has moderate strength and low water absorption rate.

• 환경위생공학
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• 제17권3호
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• pp.37-45
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• 2002

The Purpose of this study is to reduce environmental problems caused by landfill of bituminous coal fly ash emitted from the power plant and to reuse it. First of all, we experimented that Al and Si elements were extracted from fly ash and investigated that extracted Al and Si elements night use a coagulant. The extraction was carried out under various conditions ; concentration of the extraction solution, calcination temperature and calcination time. As the results, it was found that the optimum conditions of the extraction of Al and Si elements from fly ash were as follows, concentration of NaOH was 5N for both of them, calcination temperature was $700^{\circ}C$ and $600^{\circ}C$ and calcination time was 1hr and 1.5hr, respectively The extracted solution was used as a coagulant to treat the diluted metal-plating solutions which contained Pb and Cu, respectively. As the result of treatment on the diluted Pb-plating solution with 315NTU, the removal efficiency of turbidity was more than 90%, and the removal efficiency of Pb was about 80%. As for treatment of the non-turbid diluted Cu-plating solution, the removal efficiency of Cu was about 98%.

• Korean Chemical Engineering Research
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• 제51권4호
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• pp.493-499
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• 2013

저급탄의 가스화에서 얻은 비산재를 활용하기 위한 목적으로 비산재의 열분해와 비산재 촤의 $CO_2$ 가스화반응에 대한 실험을 비등온의 승온 조건(10, 20, $30^{\circ}C$/min)에서 TGA를 이용하여 수행하였다. 비산재의 열분해 속도는 1차의 열분해 모델(Kissinger법)에 의해 해석하였지만, 비산재에 포함된 휘발분의 함량이 낮아 모델의 신뢰도는 낮게 평가되었다. 비산재 촤의 $CO_2$ 가스화반응에 대한 실험결과는 미반응핵 모델, 균일반응 모델 및 랜덤 기공 모델 등으로 해석하여 석탄 촤의 $CO_2$ 가스화반응 결과와 비교하였다. 저탄소가 함유된 비산재 촤(LG탄)는 200.8 kJ/mol의 활성화 에너지로 균일반응 모델의 의해 잘 모사되었으며, 고탄소가 함유된 비산재 촤(KPU탄)의 경우에는 198.3 kJ/mol의 활성화 에너지로 석탄 촤의 $CO_2$ 가스화 특성과 유사하게 랜덤 기공 모델의 의해 잘 모사되었다. 결과로서, 두 비산재 촤의 $CO_2$ 가스화반응에 대한 활성화 에너지는 큰 차이를 나타내지는 않았지만, 고정탄소의 함량에 따라 적용할 수 있는 모델이 다르다는 것을 확인할 수 있었다.

• 자원환경지질
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• 제30권5호
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• pp.443-450
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• 1997

The main purpose of this study is to investigate mineralogical and chemical changes during natural weathering, and assess the mobility of major and trace elements. Yongwol power plant utilize anthracite coal which is mainly composed of illite, kaolinite, pyrophyllite and quartz in mineralogy. Coal and coal-derived fly ash samples were sampled by the electrostatic precipitator in Yongwol coal-fired power plant in Korea. Short term weathered fly ash were also collected in ash disposal mound, and two profile soil samples were taken from an ash near the power plant. Amorphous materials are the main component of the fly ash, and mullite, quartz, magnetite and heamatite are present in all coal-derived fly ash. In chemistry, Si and Al are the most abundant elements of the total content. The ash samples were fractionated into upper $90{\mu}m$ and under $45{\mu}m$ size. Finer particles show higher concentrations in metal contents including Co, Cr, Cu, Ni, V, Zn and Pb. Concentration of Zn and Pb are nearly 4 times higher concentration in the finer particles. For the profile samples, the concentrations of $SiO_2$, $Na_2O$, MgO and $K_2O$ generally show increasing trends with depth, whereas those of $Fe_2O_3$ and $TiO_2$ appear to decrease with depth. Content of MnO does not show any specific depth trend. For the trace elements, Co, Cu, Ni and V show increasing concentrations with depth.

• 한국연소학회지
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• 제4권1호
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• pp.67-83
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• 1999

The objective of this study is development of low emission pulverized coal combustor for reducing pollutant emission generated from coal combustion. Low emission combustion technology for reducing NOx and fly ash was investigated by using 2 stage coaxial cyclone combustor. Staged combustion was employed for NOx reduction and high temperature slagging combustion was also studied for fly ash removal in the combustor. The result of this study shows that the low emission combustion system can reduce the amount of atmospheric pollutions with improved boiler efficiency and performance.

• 유기물자원화
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• 제7권1호
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• pp.43-52
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• 1999

본 연구는 축산분뇨 퇴비화시 부자재인 톱밥을 석탄회로 대체하기 위하여 수행하였다. 축산분뇨와 톱밥의 혼합비율을 부피비 1:1로 고정하고 이때 톱밥을 어느 정도 석탄회로 대체 가능한지를 조사하였다. 각 혼합비율에 대해 조사된 톱밥과 석탄회의 혼합비율은 부피비로 40:10, 35:15, 30:20, 25:25, 20:30, 15:35, 10:40이었다. 축사에서 스크레퍼 방식과 슬러리 방식에 의하여 배출되는 축산분뇨, 톱밥과 석탄회를 앞에서와 같은 혼합비율로 섞은 부자재를 부피비 1:1로 혼합하여 퇴비화하면서 온도, 수분, pH, 유기물, 질소 및 유기물/질소 비 등을 조사하여 다음과 같은 결과를 얻었다. 온도의 변화는 슬러리 방식보다 스크레파 방식에서 톱밥비율이 높을수록 빨리 최고온도($63.5^{\circ}C$)에 도달하였다. 수분 함량의 변화는 스크레파 방식 및 슬러리 방식 공히 톱밥과 석탄회를 부피비로 동일비율(1:1) 혼합하였을 때 42 %와 54 % 범위의 수분함량으로 발효에 비교적 좋은 조건을 유지하였다. pH는 분뇨, 톱밥, 석탄회 비율 50 : 25 : 25 투입시 전체적으로 pH 7~10으로 약알카리성 내지 알카리성이었다. 유기물함량은 톱밥 혼입량이 석탄회보다 많을수록 증가되나 퇴비화가 진행됨에 따라 별다른 변화는 보이지 않았다. 질소함량은 톱밥 혼입량 증가에 따라 늘어났으나, 발효과정 진행에 따라서는 일정한 경향을 나타내지 않았다. 유기물/질소 비는 톱밥 혼입량이 증가할수록 증가하였지만, 발효과정 중 큰 변화는 볼 수 없었다.

• 한국환경과학회지
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• 제23권12호
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• pp.1987-1998
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• 2014

Zeolite was synthesized from power station waste, coal fly ash, as an alternative low-cost adsorbent and investigated for the removal of Sr(II) and Cs(I) ions from single- and binary metal aqueous solutions. In order to investigate the adsorption characteristics, the effects of various operating parameters such as initial concentration of metal ions, contact time, and pH of the solutions were studied in a batch adsorption technique. The Langmuir model better fitted the adsorption isotherm data than the Freundlich model. The pseudo second-order model was found more applicable to describe the kinetics of system. The adsorption capacities of Sr(II) and Cs(I) ions obtained from the Langmuir model were 1.7848 mmol/g and 0.7640 mmol/g, respectively. Although the adsorption capacities of individual Sr(II) and Cs(I) ions was less in the binary-system, the sum of the total adsorption capacity (2.3572 mmol/g) of both ions in the binary-system was higher than the adsorption capacity of individual ion in the single-system. Comparing the homogeneous film diffusion model with the homogeneous particle diffusion model, the adsorption was mainly controlled by the particle diffusion process.

• 한국환경과학회지
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• 제31권10호
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• pp.833-844
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• 2022

A zeolite material with a Si/Al molar ratio of 1.2 was synthesized by changing the NaOH/CFA ratio of coal fly ash (CFA) via a fusion/hydrothermal reaction in the HD thermal power plant. The change in the crystal structure of the zeolite was confirmed using XRD and SEM, and the ammonia adsorption capacities of the synthesized zeolitic materials and a commercial zeolite (Na-A zeolite) were analyzed via an ammonia temperature-programmed desorption (NH₃-TPD) process. The SEM and XRD results revealed out the zeolitic materials from the coal fly ash maintained a hexagonal Linde-type crystal structure similar to that of Na-A zeolite, but the crystallinity of the synthesized zeolitic material was reduced due to impurities. The NH₃ adsorption capacity, determined from the NH₃-TPD analysis of was 1.122 mmol/g of the synthesized zeolitic material, which was lower than the NH₃ adsorption capacity of the Na-A zeolite.

• 한국지반공학회지:지반
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• 제12권1호
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• pp.73-86
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• 1996

본 연구에서는 국내 8개 석탄화력발전소에서 발생하는 석탄회중 영월화력발전소에서 부산되는 석탄회를 주 대상으로 순수 비회(FA)와 저회(BA), 회사장에 투기되는 흔합회(FA:BA=8:2), 적정비로 혼합된 석탄회(FA:BA=5:5),그리고 일반도로성토재에 대하여 토질역학시험을 통해 공학적 특성이 비교, 분석되었으며 석탄회를 성토재 및 매립재로서 대규모로 이용할 경우의 변형해석을 위해 Hyperbolic Mode야 적용시 필요한 제반 변수를 산정하였다. 석탄회의 토공재로서의 활용 가능성을 검토한 결과 석탄회는 동일입도의 일반 홀에 비해 강도 정수 등 유리한 공학적 특성을 갖고 있으며,특히 연약지반상에 매립 또는 구조물 됫채움재로서 사용할 경우 자경성, 경량성 등 우수한 조건을 지니고 있다.