Coagulation of the Metal-Plating Wastewater using Coal Fly Ash

비산회를 이용한 도금폐수의 응집처리

  • 연익준 (동림건설㈜ 기술개발연구소) ;
  • 김광렬 (충북대학교 환경공학과)
  • Published : 2002.09.01

Abstract

The Purpose of this study is to reduce environmental problems caused by landfill of bituminous coal fly ash emitted from the power plant and to reuse it. First of all, we experimented that Al and Si elements were extracted from fly ash and investigated that extracted Al and Si elements night use a coagulant. The extraction was carried out under various conditions ; concentration of the extraction solution, calcination temperature and calcination time. As the results, it was found that the optimum conditions of the extraction of Al and Si elements from fly ash were as follows, concentration of NaOH was 5N for both of them, calcination temperature was $700^{\circ}C$ and $600^{\circ}C$ and calcination time was 1hr and 1.5hr, respectively The extracted solution was used as a coagulant to treat the diluted metal-plating solutions which contained Pb and Cu, respectively. As the result of treatment on the diluted Pb-plating solution with 315NTU, the removal efficiency of turbidity was more than 90%, and the removal efficiency of Pb was about 80%. As for treatment of the non-turbid diluted Cu-plating solution, the removal efficiency of Cu was about 98%.

Keywords

References

  1. 석탄회의 재활용 현황 한전산업
  2. 월간폐기물 석탄회 처리 현황과 대책 오성원
  3. J. Korea Society of Wastes Management v.17 no.3 Effect of Coexiting Cations on Removal Ammonium Ion from Water by Synthesized Zeolite using Coal Fly ash Yeon I.J.(et al.)
  4. The Korean Journal Sanitation v.14 no.3 The Characteristics of Solidfication and Leachability of Lead Sludge Yeon I.J.(et al.)
  5. A Wiley-Interscience Publication The Chemistry of Silica Ralph. K. Iler
  6. Water Quality and Treatment(4th edition) A Handbook of Community Water Supplies Letterman, Raymond D.
  7. Hydrothermal Chemistry of Zeolite Barrer
  8. Chemical for environmental Engineering(4th) Clair N. Sawyer;Perry L. McCarty;Gane F. Parkin
  9. Handbook of Chemistry and Physics(68th)
  10. Env. Sci. Tech. v.1 Formulation of Polysilicated as Determine by Coagulation Effects W.Stumm(et al.) https://doi.org/10.1021/es60003a004
  11. Industrial & Engineering Chemisrty Research v.36 no.7 Production of Poly(Aluminium Chloride) and Sodium Silicate from Clay Park,K.Y.(et al.) https://doi.org/10.1021/ie9607863
  12. AIChE Symposium Series v.78 no.216 Extracton of Alumina from Anthracite Coal Waste Ash H.P.Hsieh
  13. J. of the Korean Institute of Chemical Engineers v.30 no.4 A Kinetic Study on the Extraction of Aluminium from Clay by Hydrochloric Acid Park.K.Y.(et al.)
  14. J. of the Korean Institute of Chemical Engineers v.34 no.3 Extraction of Al Component from Kaolin by the Hydrochloric Acid Leaching Cho,J.H.(et al.)
  15. Theis for degree of Doctor Synthesis of high-Purity Alumina and Aluminum Derivatives from Kaolin, and Their Characteristics Kang,H.K.
  16. Thesis for degree of Master The Recovery of Alumina from Water Treatment Plant Sludge by Ammonium Chloride Jeon,B.J