• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.116-120
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• 2013

Characteristics of photocatalytic CO removal process conducting CO conversion by using Pt loaded $TiO_2$ photocatalyst were investigated in a photocatalytic tubular reactor. Effects of Pt loading method onto $TiO_2$, linear velocity of gas stream containing CO gas, CO concentration and moisture content in the gas stream on the conversion of CO to $CO_2$ were examined. It was found that the CO gas could be removed almost 100% by using photocatalytic tubular reactor internally coated with Pt/$TiO_2$ photocatalyst under UV irradiation, when the linear velocity of gas stream was in the range of 0.01~0.25 m/s and CO concentration in the gas stream was ranged from 20 to 100 ppm and the relative humidity of the gas stream was in the range of 20~40%. The conversion of CO gas decreased gradually with increasing linear velocity of gas stream and CO concentration in the gas stream. The moisture in the gas stream could promote the removal of CO gas by means of the generation of OHradicals.

• Korean Journal of Materials Research
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• v.4 no.1
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• pp.81-89
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• 1994

Ti film of lOnm thickness and Co film of 18nm thickness were sequentially e-heam evaporated onto Si (100) substrates. Metal deposited samples were rapidly thermal-annt.aled(KTA) in thr N1 en vironment a t $900^{\circ}C$ for 20 sec. to induce the reversal of metal bilayer, so that $CoSi_{2}$ thin films could be formed. The sheet resistance measured by the 4-point probe was 3.9 $\Omega /\square$This valur was maintained with increase in annealing time upto 150 seconds, showing high thermal stab~lity. Thc XRII spectra idrn tified the silicide film formed on the Si substrate as a $CoSi_{2}$ epitaxial layer. The SKM microgr;iphs showed smooth surface, and the cross-sectional TKM pictures revealed that the layer formed on the Si substrate were composed of two Co-Ti-Si alloy layers and 70nm thick $CoSi_{2}$ epl-layer. The AES analysis indicated that the native oxide on Si subs~rate was removed by TI ar the beginning of the RTA, and Ihcn that Co diffused to clean surface of Si substrate so that epitaxial $CoSi_{2}$ film could bt, formed. In thc rasp of KTA at $700^{\circ}C$. 20sec. followed by $900^{\circ}C$, 20sec., the thin film showed lower sheet resistance, but rough surface and interface owing to $CoSi_{2}$ crystal growth. The application scheme of this $CoSi_{2}$ epilayer to VLSI devices and the thermodynarnic/kinetic mechan~sms of the $CoSi_{2}$ epi-layer formation through the reversal of Co/Ti bdayer were discussed.

• Journal of Powder Materials
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• v.10 no.4
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• pp.228-234
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• 2003

In the present study, the focus is on the synthesis of titanium carbide/cobalt composite powder by the spray thermal conversion process using metallic salt solution as the raw materials. Two types of oxide powders of Ti-Co-O system were prepared by the spray drying of two types of metallic salt solutions : titanium chloride-cobalt nitrate and $TiO_2$ powder-cobalt nitrate solutions. These oxide powders were mixed with carbon black, and then these mixtures were carbothermal reduced under a flowing argon atmosphere. The changes in the phase structure and thermal gravity of the mixtures during carbothermal reduction were analysed using XRD and TG-DTA. In the case of using the titanium chloride-cobalt nitrate solution, it could not be obtained TiC/Co composite powder due to contamination of the impurities during the spray drying of the solution. However, in tile case of using the $TiO_2$ powder-cobalt nitrate scullion, TiC-15 wt. %Co composite powder could be synthesized by the spray thermal conversion process. The synthesized TiC-15 wt. %Co composite powder at 120$0^{\circ}C$ for 2 hours has average particle size of 150 nm.

• Journal of the Korean Ceramic Society
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• v.55 no.4
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• pp.381-391
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• 2018

In this work, photocatalytic $CO_2$ reduction over a CdSe-graphene-$TiO_2$ nanocomposite has been studied. The obtained material was successfully fabricated via ultrasonic technique. The physical properties of the as-synthesized materials were characterized by some physical techniques. The $TiO_2$ and CdSe dispersed graphene nanocomposite showed excellent results of strong reduction rates of $CO_2$ compared to the results of bare $TiO_2$ and binary CdSe-graphene. An outstanding point of the combination of CdSe-$TiO_2$ and graphene appeared in the form of great photocatalytic reduction capability of $CO_2$. The photocatalytic activity of the asfabricated composite was tested by surveying for the photoreduction of $CO_2$ to alcohol under UV and visible light irradiation, and the obtained results imply that the as-prepared CdSe-graphene-$TiO_2$ nanocomposite is promising to become a potential candidate for the photocatalytic $CO_2$ reduction.

• Proceedings of the KWS Conference
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• 1994.05a
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• pp.152-154
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• 1994

• Clean Technology
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• v.25 no.4
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• pp.296-301
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• 2019

This study was conducted to investigate the characteristics of CO oxidation by NO poisoning in Pt/TiO₂ catalyst prepared by wet impregnation method and calcined at 400 ℃. In order to confirm the NO poisoning effect of the Pt/TiO₂ catalyst, the change of reaction activity was observed when NO was injected during the CO+O₂ reaction where it was ascertained that the CO conversion rate rapidly decreased below 200 ℃. Also, CO conversion was not observed below 125 ℃. Recovery of initial CO conversion was not verified even if NO injection was blocked at 125 ℃. Accordingly, various analyses were performed according to NO injection. First, as a result of the TPD analysis, it was confirmed that NO pre-adsorption in catalyst inhibited CO adsorption and conversion desorption from adsorbed CO to CO₂. When NO was pre-adsorbed, it was confirmed through H₂-TPR analysis that the oxygen mobility of the catalyst was reduced. In addition, it was validated through FT-IR analysis that the redox cycle (Pt²⁺→Pt⁰→Pt²⁺) of the catalyst was inhibited. Therefore, the presence of NO in the Pt/TiO₂ catalyst was considered to be a poisoning factor in the CO oxidation reaction, and it was determined that the oxygen mobility of the catalyst is required to prevent NO poisoning.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3031-3038
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• 2009

Cobalt-loaded activated carbon fibers (ACFs) supported titanium dioxide ($TiO_2$) photocatalyst was developed by sol-gel method. The Co-ACFs/$TiO_2$ photocatalyst were characterized by scanning electron microscope (SEM), X.ray diffraction patterns (XRD), energy dispersive X.ray analysis (EDX) and UV-vis absorption spectroscopy. Decomposition efficiency of methylene blue (MB) solution by Co-ACFs/$TiO_2$ photocatalyst reached almost 100% under 300 min reaction. The MB molecules in the bulk solutions were supposed to be condensed around $TiO_2$ particles by adsorption of ACFs. Therefore, the photocatalyst possesses the combined effect of adsorption by activated carbon fibers and photocatalytic reactivity of $TiO_2$ on MB degradation. Due to the cobalt has electron transition effece, thus improved the photodegradation of MB solution.

• Journal of the Korean Society for Heat Treatment
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• v.37 no.4
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• pp.172-181
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• 2024

In this study, the effect of addition of Ti and Co elements on microstructural evolution and characteristics of vacuum-casted Cu-25%Cr electrical contact material was investigated. The coarse and insoluble Cr phases with an average size of 300 ㎛ in commercial Cu-25%Cr alloy were reduced to tens of micrometers in vacuum casted Cu-25%Cr-X(X=Ti, Co) alloy, which can be interpreted as result controlling coarsening and the work-frame structure of the insoluble Cr phase by the formation of intermetallic compounds such as Cr₂Ti or Cr_0.5Co_1.5Ti around the Cr phase As a result, the electrical properties such as weight loss and fusion resistance against the repeated arc generation of the electrical contact material as well as the mechanical properties were greatly improved.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.352-353
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• 2006

The effect of TiC content on oxidation behavior of the sintered WC-TiC-TaC alloys with 2 mass% TaC and different TiC amounts of 3-45 mass% was investigated through oxidation tests in air at 973K. As a result of the tests, it was revealed that with increasing TiC content in the alloys, mass changes caused by oxidation and thickness of the scale decreased. Thus, it is considered that the main component of the scales changed gradually from $WO_3$ to $TiO_2$ with increasing TiC content in the alloys, and oxygen diffusion through the scale to the alloys was inhibited gradually.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.4
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• pp.236-240
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• 2004

Effect of plasma power on PECVD process were investigated in this study. TiN and TiCN films were deposited on nitrided STD11 steel with 600W, 1,200W and 1,600W plasma power. As the plasma power was increased, the preferred orientation was reinforced from (200) to (111) and the hardness of films was improved. The low plasma power was, however, effective for improving of adhesion force of films. Regarding above properties, TiN and TiCN films were deposited by gradient plasma power. It was possible to get high hardness as well as adhesion force through gradient plasma power.