• Title/Summary/Keyword: CoE

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Does High-Speed Rail Have Superiority over Motorway in Terms of CO2 Emission? (고속철도는 고속도로에 비하여 저탄소 친환경적인가?)

  • Kang, Taeseok;Chang, Hyunho
    • International Journal of Highway Engineering
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    • v.18 no.5
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    • pp.83-93
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    • 2016
  • PURPOSES : The aim of this article is to compare and identify eco-friendly competitiveness between (regional) motorway and high-speed rail(HSR) from the perspective of $CO_2$ emission in the Republic of Korea. METHODS : In order for an analysis of low-carbon competitiveness between the two modes, $CO_2e$ emission, $CO_2eppk$ (equivalent $CO_2$ gram per passenger kilometer), is employed as a comparison index. As for HSR, the index is calculated based on the passenger transport data and the gross of $CO_2e$ produced by Kyungbu high-speed line in 2013. Additionally, the gross of $CO_2e$ is computed by the greenhouse gas emission factors of domestic electricity generation mix. Regarding the index of motorway, it is directly calculated using both the official $CO_2e$ emission factor and the passenger-car occupancy of motorway. RESULTS : The results revealed, in the case of inter-regional transport, that the $CO_2e$ emission of displacement-based cars is 54.9% less than that of HSR, as the domestic electric power systems heavily relies on the thermal power plants over 66%. Note that internal combustion engines commonly used for vehicles are more energy-efficient than steam-driven turbines usually utilized for thermal power generation. CONCLUSIONS : It can be seen, at the very least in our study, that HSR has no superiority over motorway in the case of $CO_2e$ emission under the situations of domestic electricity generation mix. In addition, advanced eco-friendly vehicles have strong advantages over HSR. Therefore, all-out efforts should be made to develop and harvest renewable energy sources in order to achieve low-carbon HSR, sparing fossil fuels.

The Polarographic Wave of Co (III)-Triethanolamine Complex (코발트(III)-Triethanolamine 錯鹽의 폴라로그라프波에 對하여)

  • Hwang Am Kim
    • Journal of the Korean Chemical Society
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    • v.7 no.1
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    • pp.34-37
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    • 1963
  • Cobalt(Ⅲ) ion gives two step waves with $E_{1/2}$-0.1V(?)(vs.S.C.E.) and $E_{1/2}$-1.37V(vs. S.C.E.) from a base electrolyte consisting of 0.1 M TEA+sodium borate+0.0002% gelatin. The first wave results from the reduction Co(Ⅲ) to Co(Ⅱ). The second wave corresponding to the reduction Co(Ⅱ) to Co(0) and this wave is diffusion controlled. The diffusion current constant of the second wave is 2.7. Under these-conditions, diffusion current of the second wave is proportional to the concentration of Co (Ⅱ) in the range of $10^{-3}{\sim}10^{-4}$ M.

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3D-QSAR Study of Competitive Inhibitor for Acethylcholine Esterase (AChE) Nerve Agent Toxicity

  • San Juan, Amor A.;Cho, Seung-Joo
    • Molecular & Cellular Toxicology
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    • v.2 no.3
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    • pp.216-221
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    • 2006
  • The cholinesterase-inhibiting organophosphorous (OP) compounds known as nerve agents are highly toxic. The principal toxic mechanism of OP compounds is the inhibition of acethylcholine esterase (AChE) by phosphorylation of its catalytic site. The reversible competitive inhibition of AChE may prevent the subsequent OP intoxication. In this study, three-dimensional quantitative structure-activity relationship (3D-QSAR) was performed to investigate the relationship between the 29 compounds with structural diversity and their bioactivities against AChE. In particular, predictive models were constructed using the comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA). The results indicate reasonable model for CoMFA ($q^{2}=0.453,\;r^{2}=0.697$) and CoMSIA ($q^{2}=0.518,\;r^{2}=0.696$). The presence of steric and hydophobic group at naphtyl moiety of the model may lead to the design of improved competitive inhibitors for organophosphorous intoxication.

The development of the procurement process system for e-Biz of the plant business (플랜트 산업의 e-Biz화를 위한 구매 Process System 개발)

  • Kim Hoi-Sub;Lee Joo-Pyo;Han Sang-hoon;Cho Se-hyoung;Park Chang-Hyun;Han Jae-Bum;Kim Sung-Ho;Kim Gyu-Tae
    • Journal of Internet Computing and Services
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    • v.4 no.5
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    • pp.11-19
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    • 2003
  • Since B2C(Business to Customer) from which e-commerce had originated was replaced by B2B, e-Business has shown fast growth so fa., Recently, e-Procurement by l:n concept is on the development as self-purchase system associated with their own ERP In many conglomerates in the Korean market. However, in order to vitalize e-Biz in the plant industry, we need to set up e-marketplaces where many sellers and buyers can meet each other at the same time, which has become the essential part for success as an expanded business model. In this paper, we expect that the foundation for e-transformation in the plant industry is set up by developing Purchase Process System and related modules as the prerequisite for e-Biz in the plant industry, and this report will provide an exemplary model for e-commerce. The Purchase Process System consists of 1) e-Purchasing Module that manages bidding and contract information based on quotation inquiry, 2) e-Expediting Module that manages information to guarantee the on-time delivery, 3) e-Certification Module that controls user authentification, 4) e-Basic Module that manages the bulletin boards, Q&A, etc.

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Heterogeneous Oxidation of Liquid-phase TCE over $CoO_x/TiO_2$ Catalysts (액상 TCE 제거반응을 위한 $CoO_x/TiO_2$ 촉매)

  • Kim, Moon-Hyeon;Choo, Kwang-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.253-261
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    • 2005
  • Catalytic wet oxidation of ppm levels of trichloroethylene (TCE) in water has been conducted using $TiO_2$-supported cobalt oxides at a given temperature and weight hourly space velocity. 5% $CoO_x/TiO_2$ might be the most promising catalyst for the wet oxidation at $36^{\circ}C$ although it exhibited a transient behavior in time on-stream activity. Not only could the bare support be inactive for the wet decomposition reaction, but no TCE removal also occurred by the process of adsorption on $TiO_2$ surface. The catalytic activity was independent of all particle sizes used, thereby representing no mass transfer limitation in intraparticle diffusion. Characterization of the $CoO_x$ catalyst by acquiring XPS spectra of both fresh and used Co surfaces gave different surface spectral features of each $CoO_x$. Co $2p_{3/2}$ binding energy of Co species exposed predominantly onto the outermost surface of the fresh catalyst appeared at 781.3 eV, which is very similar to the chemical states of $CoTiO_x$ such as $Co_2TiO_4$ and $CoTiO_3$. The spent catalyst possessed a 780.3 eV main peak with a satellite structure at 795.8 eV. Based on XPS spectra of reference Co compound, the TCE-exposed Co surfaces could be assigned to be in the form of mainly $Co_3O_4$. XRD measurements indicated that the phase structure of Co species in 5% $CoO_x/TiO_2$ catalyst even before reaction is quite comparable to the diffraction lines of external $Co_3O_4$ standard. A model structure of $CoO_x$ present on titania surfaces would be $Co_3O_4$, encapsulated in thin-film $CoTiO_x$ species consisting of $Co_2TiO_4$ and $CoTiO_3$, which may be active for the decomposition of TCE in a flow of water.

(L, e)-filters on complete residuated lattices

  • Kim, Yong-Chan;Ko, Jung-Mi
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.12 no.3
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    • pp.232-237
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    • 2012
  • We introduce the notion of (L, e)-filters with fuzzy partially order e on complete residuated lattice L. We investigate (L, e)-filters induced by the family of (L, e)-filters and functions. In fact, we study the initial and final structures for the family of (L, e)-filters and functions. From this result, we define the product and co-product for the family of (L, e)-filters and functions.

Effects of Taurine and $\beta$-alanine on Blood Glucose and Blood Lipid Concentrations in Streptozotocin-induced Diabetic Rats (타우린과 베타알라닌이 실험적 당뇨유발 쥐의 혈당 및 혈정지질농도에 미치는 영향)

  • 장경자
    • Journal of Nutrition and Health
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    • v.32 no.3
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    • pp.213-220
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    • 1999
  • The purpose of this study was to determine the dose effects of taurine supplementation and effects of taurine depletion in diabetic rats. Sprague-Dawley male rats were fed the purified diets and supplemented with 1, 2 or 3% taurine in drinking water for 7 weeks(E1, E2 and E3, respectively). To induce taurine depletion, rats were treated with 5% $\beta$-alanine in drinkeng water (EA). Diabetes was induced by streptozotocin injection(50mg/kg B.W) after 3 weeks. Taurine-depleted diabetic rats(EA)had significantly lower body weight compared to those of nondiabetic(CO), nontaurine-supplemented diabetic(E0) and taurine-supplemented diabetic rats(E1, E2 and E3). E0 had significantly higher food intake compared to that of CO and EA. E1, E2 and E3, however, had significantly lower food intake compared to that of E0, and E3 had significantly lower food intake compared to that of E1 and E2. E0 had significantly higher water intake compare to that of CO and EA. EI had significantly lower water intake compared to that of E0. Blood glucose concentration of E0 was significantly increased compared to that of CO and EA. E2 and E3 had significantly lower blood glucose concentration compared to E0 and E1. Also there was a dose effect in blood glucose concentration between E2 and E3. The total cholesterol and LDL-cholesterol concentrations of EA were significantly increased compared to those of other groups. Therefore, it may be suggested that taurine supplementation is necessary for diabetes in order to prevent diabetic complications such as cardiac vascular diseases.

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Adsorbed Carbon Formation and Carbon Hydrogenation for CO2 Methanation on the Ni(111) Surface: ASED-MO Study

  • Choe, Sang-Joon;Kang, Hae-Jin;Kim, Su-Jin;Park, Sung-Bae;Park, Dong-Ho;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1682-1688
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    • 2005
  • Using the ASED-MO (Atom Superposition and Electron Delocalization-Molecular Orbital) theory, we investigated carbon formation and carbon hydrogenation for $CO_2$ methanation on the Ni (111) surface. For carbon formation mechanism, we calculated the following activation energies, 1.27 eV for $CO_2$ dissociation, 2.97 eV for the CO, 1.93 eV for 2CO dissociation, respectively. For carbon methanation mechanism, we also calculated the following activation energies, 0.72 eV for methylidyne, 0.52 eV for methylene and 0.50 eV for methane, respectively. We found that the calculated activation energy of CO dissociation is higher than that of 2CO dissociation on the clean surface and base on these results that the CO dissociation step are the ratedetermining of the process. The C-H bond lengths of $CH_4$ the intermediate complex are 1.21 $\AA$, 1.31 $\AA$ for the C${\cdot}{\cdot}{\cdot}H_{(1)}$, and 2.82 $\AA$ for the height, with angles of 105${^{\circ}}$ for ∠ $H_{(1)}$CH and 98${^{\circ}}$ for $H_{(1)} CH _{(1)}$.