• 제목/요약/키워드: Co-phosphate

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Antioxidation Characteristics of Surface-Modified Carbon in ${Al_2}{O_3}$-C Refractory (${Al_2}{O_3}$-C계 내화물에서 표면개질된 탄소의 산화특성)

  • 홍영호;김동한;심광보
    • Journal of the Korean Ceramic Society
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    • v.37 no.6
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    • pp.583-588
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    • 2000
  • Antioxidation characteristics of carbon at high temperature with the co-addition of Al and Si powder in Al2O3-C system refractory were analyzed. The use of surface-modified phosphate carbon as a starting material was found to be very effective in improving the mixing effect of raw materials and antioxidation behavior of carbon. In particular, this effect was dominant at higher temperatures than 130$0^{\circ}C$.

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New vanadate-phosphate phosphors for lighting application

  • Toda, Kenji
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.125-126
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    • 2009
  • In this study, we report the room temperature synthesis and luminescence properties of white-light-emitting Rb(V,P)$O_3$. The vanadate phosphor, RbV$O_3$, was synthesized by simple mixing of $RbCO_3$ and $V_2O_5$ at room temperature in air. New direct room temperature solidstate reaction is a cost-effective method to synthesize the above luminescent materials.

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Photoelectrochemical Water Oxidation Using ZnO Nanorods Coupled with Cobalt-Based Catalysts

  • Jeon, Tae-Hwa;Choi, Sung-Kyu;Jeong, Hye-Won;Kim, Seung-Do;Park, Hyun-Woong
    • Journal of Electrochemical Science and Technology
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    • v.2 no.4
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    • pp.187-192
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    • 2011
  • Photoelectrochemical performances of ZnO electrodes are enhanced by coupling with cobalt-based catalyst (CoPi) in phosphate electrolyte (pH 7). For this study, hexagonal pillar-shaped ZnO nanorods are grown on ZnO electrodes through a chemical bath deposition, onto which CoPi is deposited with different photodeposition times (10-30 min). A scanning electron microscopic study indicates that CoPi deposition does not induce any change of ZnO morphology and an energy-dispersive X-ray spectroscopic analysis shows that inorganic phosphate ions (Pi) exist on ZnO surface. Bare ZnO electrodes generate the current of ca. $0.36mA/cm^2$ at a bias potential of 0.5 V vs. SCE, whereas ZnO/CoPi (deposited for 10 min) has ca. 50%-enhanced current ($0.54mW/cm^2$) under irradiation of AM 1.5G-light ($400mW/cm^2$). The excess loading of CoPi on ZnO results in decrease of photocurrents as compared to bare ZnO likely due to limited electrolyte access to ZnO and/or CoPi-mediated recombination of photogenerated charge carriers. The primary role of CoPi is speculated to trap the photogenerated holes and thereby oxidize water into molecular oxygen via an intervalency cycle among Co(II), Co(III), and Co(IV).

Histometrical evaluation of biphasic calcium phosphate in surgically created 1-wall periodontal intrabony defects in dogs (성견 일벽성 치주 결손부에 이식한 biphasic calcium phosphate의 조직계측학적 평가)

  • Yon, Je-Young;Kim, Dong-Jin;Hong, Sung-Bae;Hong, Ji-Yeon;Kim, Sung-Tae;Lee, Yong-Ho;Cho, Kyu-Sung;Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.38 no.2
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    • pp.171-178
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    • 2008
  • Purpose: The aim of this study was to evaluated biphasic calcium phosphate applied in surgically created 1-wall periodontal intrabony defects in dogs by histometrical analysis. Material and Method: Critical sized($4\;mm\;{\times}\;4\;mm$), one wall periodontal intrabony defects were surgically produced at the proximal aspect of mandibular premolars in either right and left jaw quadrants in four canines. The control group was treated with debridement alone, and experimental group was treated with debridement and biphasic calcium phosphate application. The healing processes were histologically and histometrically observed after 8 weeks. Results: In biphasic calcium phosphate group, more new bone and cementum formation, less epithelium and connective tissue attachment were observed compared to other groups. But there was no statistical significance. Conclusion: Though the statistically significant difference could not be found, it seemed that there was more new bone and cementum formation with applying biphasic calcium phosphate in 1 wall intrabony defects in dogs by preventing junctional epithelium migration.

Effects of Phosphate Complex Treatment on the Quality of Dried Garlic Flakes (인산염 처리가 건마늘 플레이크의 품질에 미치는 영향)

  • Kim, Hyun-Ku;Jo, Kil-Suk;Shin, Dong-Hwa;Kim, Il-Hwan
    • Korean Journal of Food Science and Technology
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    • v.19 no.1
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    • pp.75-80
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    • 1987
  • In order to prevent browning during drying of garlic flakes, the effect of dipping in phosphate complex solution prior to drying on the development of brown pigment in the flakes were studied. The browning color development during drying of the flakes was greatly dependent on phosphate complex concentration and their dipping time. A reciprocal relationship between browning color formation and reducing sugar content of dried garlic flakes was found. The browning color development during drying of the flakes was effectively impeded by dipping in 0.3% phosphate complex solution for 3 minute. The reduction of pyruvate content during drying of the flakes was greatly influenced by phosphate complex concentration and drying temperature, and a maximum retention was acieved by 3 minute dipping in 0.2-0.3% phosphate complex solution. The dried yield of the flakes dipped in phosphate complex solution was 1.62-1.75% lower than control and it was mainly caused by the dissolution of soluble solids during dipping.

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Application of magnetic activated sludge process for a milking parlor wastewater treatment with nitrogen and phosphorus recovery

  • Onodera, Toshihito;Sakai, Yasuzo;Kashiwazaki, Masaru;Ihara, Ikko;Lal, Saha Mihir
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.3
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    • pp.20-25
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    • 2021
  • Milking parlor wastewater contains high concentration suspended solid (SS), nitrogen, and/or phosphate as well as organic compounds. A new biological wastewater process by magnetic separation, magnetic activated sludge (MAS) process, was applied to milking parlor wastewater treatment process. A three step wastewater treatment process of coagulation sedimentation / ammonia stripping (C/S), magnetic activated sludge process and contact oxidation (CO) was proposed for removal of these pollutants. First step, C/S process recovered 96% TN and 96% PO43--P as resource for fertilizer from the wastewater. 81% biochemical oxygen demand (BOD) in wastewater was removed after MAS process. As a results, all pollutant concentrations satisfied Japanese effluent standards. Most of residual BOD and SS were removed by the CO process. It was estimated that the proposed process could reduce the process space to 1/7.

Characteristics of Bacillus sphaericus PSB-13 as Phosphate Solublizing Bacterium Isolated from Citrus Orchard Soil (감귤원 토양에서 분리한 인산염 가용화 미생물 Bacillus sphaericus PSB-13의 특성)

  • Joa, Jae-Ho;Lim, Han-Cheol;Han, Seung-Gap;Chun, Seung-Joung;Suh, Jang-Sun
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.5
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    • pp.405-411
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    • 2007
  • This study was carried out to measure insoluble phosphorus fractions content fixed in different soil type and isolate a superior phosphate solublizing bacteria(PSB) producing free phosphate in citrus orchard soil. Distribution of insoluble phosphate fraction ordered Al-P>Ca-P>Fe-P in the investigated citrus orchards. Insoluble phosphate fraction such as Al-P, Ca-P, Fe-P were higher in volcanic ash than in non-volcanic ash soil. A PSB with high holo zone in PDA-P medium isolated from citrus orchard soil. This strain identificated by MIDI system as Bacillus sphaericus. The optimum growth of pH and temperature were at 4~5, $30^{\circ}C$, respectively. When Bacillus sphaericus cultured at $25^{\circ}C$, 150 rpm condition in LB broth medium included different phosphate. Bacillus sphaericus produced free phosphate in the culture broth medium from tricalcium-phosphate(207.0 ppm), aluminium phosphate(324.5 ppm) and hydroxyapatite(334.8 ppm) and Phosphatase activity of Bacillus sphaericus was higher at $35^{\circ}C$ culture condition than that of $25^{\circ}C$. Two type preparation inoculated Bacillus sphaericus made with carrier materials such as Bentonite, $CaCO_3$, Sodium alginate. Density of PSB in this preparation conserved at $10^5c.f.u.\;g^{-1}$ level during storage in different temperature condition for 7 month. It also showed that free phosphate produced at PDA-P medium.

Effects of Streptomyces sp. MG 121 on Growth of Pepper Plants and Antifungal Activity (토양 방선균 Streptomyces sp. MG 121의 항균활성 및 고추 생육에 미치는 효과)

  • Lim, Tae-Heon;Cho, Sung-Hyun;Kim, Jin-Ho
    • Research in Plant Disease
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    • v.13 no.2
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    • pp.93-97
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    • 2007
  • The microorganisms with the antifungal activity against Phytophthora capsici and Colletotrichum acutatum and the plant growth promotion activity were screened from forest soils of Moon-gyeong (Juheul Mountain), Gyeongsangbuk-do. One of the isolates, strain MG 121 showed antifungal activity against P. capsici and C. acutatum and possessed phosphate solubilization activity was selected to development biocontrol agent. The strain MG 121 was identified as Streptomyces sp. by analysis of 16S rDNA. On the test with pepper fruits, the strain inhibited disease incidences of late blight and anthracnose over 80%. In greenhouse test, plant height, the number of leaf, fresh weight and roots length of pepper plants upon treatment of culture suspension of Streptomyces sp. MG 121 were significantly higher than those without the bacterial cells. In addition, strain MG 121 was capable to solublize rock-phosphate after incubation for 144 hours in potato dextrose broth. The concentration of soluble phosphate in PDB amended with 0.5% rock-phosphate was increased up to $765{\mu}g/ml$.

Phosphate Associated Cadmium Immobilization Mechanism Depending on the Original Concentration of Cd in Soil

  • Lee, Hyun Ho;Hong, Chang Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.429-433
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    • 2016
  • Adsorption and precipitation of cadmium (Cd) could be dependent on rate of P addition and Cd level in soil. Therefore, the objective of this study was to examine how addition rate of P affect mechanisms of Cd immobilization such as adsorption and precipitation in different levels of Cd in soil. Arable soils were spiked with inorganic Cd ($CdCl_2$) to give a total Cd concentration of 10, 100, and $1,000mg\;Cd\;kg^{-1}$. Monopotassium phosphate ($KH_2PO_4$, MPP) was selected as phosphate material and mixed with the pretreated arable soil at the rates of 0, 800, 1,600 and $3,200mg\;P\;kg^{-1}$. The mixture soils were incubated at $25^{\circ}C$ for 8 weeks in dark condition. Soil pH decreased with increasing MPP addition rate in all levels of Cd but negative charge of soil increased, thereby reducing 1 M $NH_4OAc$ extractable Cd. Soil solutions were undersaturated with respect to $CdCO_3$ and $Cd_3(PO_4)_2$ with all P addition rate in soil with low Cd level (${\leq}100mg\;Cd\;kg^{-1}$) but supersaturated in soil with high Cd level ($1,000mg\;Cd\;kg^{-1}$). From the above results, Cd solubility was controlled by precipitation of Cd minerals such as $CdCO_3$ and $Cd_3(PO_4)_2$ in soil with high Cd level but by Cd adsorption induced by increase in negative charge of soil with low level of Cd.