• 한국군사과학기술학회지
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• 제23권5호
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• pp.475-484
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• 2020

Individual curing process of each layer in two resin composites can be caused the separation between two layers. In this study, co-curing process for two resin composites is suggested to improve the inter-layer bonding. Glass fiber reinforced composites with phenolic and epoxy resins were manufactured by co-curing process, and several types of glass/phenolic composites were considered to confirm the application on two resin composites. Experiments for smoke resistance, scratch resistance and flexural strength were carried out to verify requirements corresponding to thermal and mechanical environments. It was validated that two resin composites with phenolic resin impregnated prepreg exhibits good thermal and mechanical characteristics, and it can serve as highly effective composite structures in aerospace and many industry areas.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 추계학술발표대회 논문집
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• pp.83-87
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• 2004

In this work, the cure cycle of co-cured metal/composite structure was investigated to decrease fabricating thermal residual stresses between the metal and the composite material. DSC (Differential scanning calorimetry) experiment and static lap shear test of co-cured aluminum/composite double lap joint as well as the curvature experiment of co-cured steel/composite strip were performed to investigate the effect of curing cycle on the thermal residual stress of co-cured hybrid structures. From the experiments, it was found that post curing method after abrupt cooling of co-cured aluminum/composite hybrid structure at certain point of degree of cure during curing process could eliminate fabricating the thermal residual stresses.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.473-482
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• 2012

A novel malemide epoxy containing Co(II), Ni(II) and Cu(II) ions have been synthesized by curing malemide epoxy resin (MIEB-13) and Co(II), Ni(II) and Cu(II) complexes of macrocyclic bis-hydrazone Schiff base. The Schiff base was synthesized by reacting 1,4-dicarbnyl phenyl dihydrazide with 2,6-diformyl-4-methyl phenol. The Schiff base and its Co(II), Ni(II) and Cu(II) complexes have been characterized by elemental analyses, spectral (IR, $^1H$ NMR, UV-vis., FAB mass, ESR), thermal and magnetic data. The curing reaction of maleimide epoxy compound with metal complexes was studied as curing agents. The stability of cured samples was studied by thermo-gravimetric analyses and which have excellent chemical (acid/alkali/solvent) and water absorption resistance. Further, the scanning electron microscopy (SEM) and definitional scanning colorimetric (DSC) techniques were confirmed the phase homogeneity of the cured systems.

• Elastomers and Composites
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• 제55권2호
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• pp.95-102
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• 2020

Currently, peroxide cure is a widely used cure system for rubber materials. To improve its effectivity, co-agents are used to enhance the peroxide efficiency and mechanical properties of rubber materials. Co-agents are multifunctional organic compounds that are highly reactive towards free radicals. These co-agents provide higher cross-link densities for a given peroxide concentration and improve the mechanical properties of peroxide-cured rubber composites. In this study, trimethylolpropane trimethacrylate (TMPTMA) and high vinyl 1,2-polybutadiene (HVPBD) were used as co-agents. In order to obtain a concentration that achieves a favorable balance between mechanical properties and co-agent concentration, this research investigated the effects of co-agent content on the curing characteristics, chemical structures, and mechanical properties of HNBR composites. Additionally, the heat aging properties and compression sets of HNBR composites were investigated. Based on the results, we found that the HNBR composites with TMPTMA co-agents exhibited higher Shore A hardness and 10% modulus and better heat aging resistance and compression set than that of the HVPBD co-agent. The heat aging resistance and compression set deteriorated with increasing HVPBD content.

• 자원리싸이클링
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• 제23권4호
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• pp.37-46
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• 2014

건설 분야 중 건설 재료와 건자재 산업에서 발생하는 $CO_2$는 약 6,700만톤으로 건설 분야에서 발생하는 $CO_2$의 약 30 %를 점유하고 있다. 건설 분야에서 $CO_2$ 저감은 건자재 산업에서 $CO_2$를 발생시키는 2차, 3차 양생을 줄여 소비되는 화석연료 사용과 배출가스 저감의 조절이 필수적이다. 따라서 본 연구는 시멘트 결합재를 기초로 하여 결합재를 40 % 까지 대체하여 모르타르를 제조한 후 양생방법을 달리하여 응결 및 강도 특성을 분석하였다. 결합재 치환율에 따른 강도 특성 결과 증기양생 후 고로슬래그와 CSA 15%, CAMC 5%를 치환한 시험체의 강도 증진이 활발하였다. 특히 고로슬래그 50%, CSA 15%, CAMC 5%를 치환한 시험체가 가장 높게 강도가 증진되었다. 하지만 CAMC 10%의 경우 열팽창에 의한 균열과 온도차에 의한 건조수축, 과도하게 생성된 에트린가이트에 의해 강도가 저하되는 결과를 가져왔다.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1613-1619
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• 2011

A hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) containing Co(II), Ni(II) and Cu(II) ions was prepared by curing N-MPGE and tetradentate Schiff base Co(II), Ni(II) and Cu(II) complexes. The curing polymerization reaction of N-MPGE with metal complexes as curing agents was studied. The cured samples were studied for thermal stability, chemical (acid/alkali/solvent) and water absorption resistance and homogeneity of the cured systems. The tetradentate Schiff base, 3-[(Z)-2-piperazin-1-yl-ethylimino]-1,3-dihydro indol-2-one was synthesized by the condensation of Isatin (Indole-2, 3-dione) with 1-(2-aminoethyl)piperazine (AEP). Its complexes with Co(II), Ni(II) and Cu(II) have been synthesized and characterized by microanalysis, conductivity, Uv-Visible, FT-IR, TGA and magnetic susceptibility measurements. The spectral data revealed that the ligand acts as a neutral tetradentate Schiff base and coordinating through the azomethine nitrogen, two piperazine nitrogen atoms and carbonyl oxygen.

• 한국연초학회지
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• 제20권1호
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• pp.19-25
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• 1998

The bulk curing experiment to the improve the quality of flue-cured leaves were carried out to evaluate relationship between cyclic curing and conventional curing method. We studied the effect of the cyclic change of wet bulb temperature at the yellowing stage of flue curing on chemical properties of cured leaves. The wet bulb temperature was automatically controlled between preset high($38^{\circ}C$) and low point ($35^{\circ}C$) everyone hour cyclically during 12 hours after starting luring. As a result, the acceleration of the increase in the chemical properties of cured leaves were observed. As to the chemical properties, there was decreased in citric acid, increased in malic acid of the nonvolatile organic acids and all higher fatty acids content of leaves cured by this method compared with in that of conventional curing method, while a major chemical compounds in relation to aromatic essence of cigarette smoke in essential oil components of lured leaves was mostly higher in this method than those of conventional ones, and it was evaluated that there was decreased in CO, TPM, Tar, and $CO_2$ content of the cigarette smoke comparing to the conventional luring method.

• Elastomers and Composites
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• 제52권4호
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• pp.266-271
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• 2017

This study describes the influence of the amount of curing agent and curing temperature on the kinetics of polyurethane elastomers. The urethane prepolymer series was prepared by reacting toluene diisocyanate with polytetramethylene ether glycol at $80^{\circ}C$ for 1 h, and 4,4'-methylene bis(2-chloroaniline) was used as the curing agent. The ratio of the amine group of the curing agent to the isocyanate group of the urethane prepolymer was controlled from 0.85 to 1.05 at curing temperatures ranging from 80 to $120^{\circ}C$. The curing rate of the urethane prepolymer was monitored by observing the change in heat flow during the curing process using differential scanning calorimetry (DSC). As either the content of curing agent or the curing temperature was higher, the conversion rate to the polyurethane elastomer was high. The DSC results were compared with those obtained from using real-time FT-IR.

• 자원리싸이클링
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• 제24권2호
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• pp.13-22
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• 2015

건설 분야 중 건설 재료와 건자재 산업에서 발생하는 $CO_2$는 약 6,700만톤으로 건설 분야에서 발생하는 $CO_2$의 약 30%를 점유하고 있다. 건설 분야에서 $CO_2$ 저감은 건자재 산업에서 $CO_2$를 발생시키는 2차, 3차 양생을 줄여 소비되는 화석연료 사용과 배출 가스 저감의 조절이 필수적이다. 따라서 본 연구는 저에너지양생용 혼합재(Low energy curing Admixture 이하 LA)를 압출성형패널에 적용한 후 그 혼입량, 섬유종류, 섬유 혼입율에 따른 물리적 특성을 관찰하였다. 섬유종류가 강도에 영향을 나타내는 주요한 인자는 아닌 것으로 나타났으며, LA 혼입율과 섬유 혼입량은 강도에 영향을 주는 주요한 인자인 것으로 나타났다. 특히 LA 혼입율 dl 40% 일 때 가장 높은 강도발현을 나타냈으며, 50% 인 시험체의 경우 강도가 하락하는 결과를 나타냈다, 또한 섬유 혼입율은 휨강도에 크게 영향을 주었으며 혼입율이 증가할수록 휨강도는 증가하는 것으로 나타났다.

• 한국군사과학기술학회지
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• 제20권5호
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• pp.620-632
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• 2017

A chemical vapor curing method(CVC) was developed to cure polycarbosilane(PCS) fibers by using cyclohexene vapour as a non-oxygen active reactant, instead of air in oder to prepare the silicon carbide(SiC) fiber with low oxygen content. A cross-linked PCS fibers by cyclohexene vapor showed a completely different variation in IR spectra in comparison to the air-cured PCS fiber. CVC method resulted in less than 3 wt% in oxygen content. In this experiment conditions, The average tensile strength and modulus of SiC fiber obtained by CVC had 1995 MPa and 183 GPa respectively, which is higher than that of SiC fiber prepared by air-curing process.