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http://dx.doi.org/10.7473/EC.2020.55.2.95

Effects of Co-agent Type and Content on Curing Characteristics and Mechanical Properties of HNBR Composite

Lee, Young Seok (Jinyang Oilseal Co., Ltd)
Ha, KiRyong (Department of Chemical Engineering, Keimyung University)

Publication Information

Elastomers and Composites / v.55, no.2, 2020 , pp. 95-102 More about this Journal

Abstract

Currently, peroxide cure is a widely used cure system for rubber materials. To improve its effectivity, co-agents are used to enhance the peroxide efficiency and mechanical properties of rubber materials. Co-agents are multifunctional organic compounds that are highly reactive towards free radicals. These co-agents provide higher cross-link densities for a given peroxide concentration and improve the mechanical properties of peroxide-cured rubber composites. In this study, trimethylolpropane trimethacrylate (TMPTMA) and high vinyl 1,2-polybutadiene (HVPBD) were used as co-agents. In order to obtain a concentration that achieves a favorable balance between mechanical properties and co-agent concentration, this research investigated the effects of co-agent content on the curing characteristics, chemical structures, and mechanical properties of HNBR composites. Additionally, the heat aging properties and compression sets of HNBR composites were investigated. Based on the results, we found that the HNBR composites with TMPTMA co-agents exhibited higher Shore A hardness and 10% modulus and better heat aging resistance and compression set than that of the HVPBD co-agent. The heat aging resistance and compression set deteriorated with increasing HVPBD content.

Keywords

HNBR; co-agent; curing characteristics; mechanical properties; peroxide;

Citations & Related Records

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