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http://dx.doi.org/10.5012/bkcs.2011.32.5.1613

Synthesis of Co(II), Ni(II) and Cu(II) Complexes from Schiff base Ligand and Reactivity Studies with Thermosetting Epoxy Resin  

Lakshmi, B. (Department of Studies in Chemistry, Central College Campus, Bangalore University)
Shivananda, K.N. (Department of Studies in Chemistry, Central College Campus, Bangalore University)
Prakash, Gouda Avaji (Department of Organic Chemistry, Indian Institute of Science)
Rama, Krishna Reddy K. (Department of Studies in Chemistry, Central College Campus, Bangalore University)
Mahendra, K.N. (Department of Studies in Chemistry, Central College Campus, Bangalore University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.5, 2011 , pp. 1613-1619 More about this Journal
Abstract
A hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) containing Co(II), Ni(II) and Cu(II) ions was prepared by curing N-MPGE and tetradentate Schiff base Co(II), Ni(II) and Cu(II) complexes. The curing polymerization reaction of N-MPGE with metal complexes as curing agents was studied. The cured samples were studied for thermal stability, chemical (acid/alkali/solvent) and water absorption resistance and homogeneity of the cured systems. The tetradentate Schiff base, 3-[(Z)-2-piperazin-1-yl-ethylimino]-1,3-dihydro indol-2-one was synthesized by the condensation of Isatin (Indole-2, 3-dione) with 1-(2-aminoethyl)piperazine (AEP). Its complexes with Co(II), Ni(II) and Cu(II) have been synthesized and characterized by microanalysis, conductivity, Uv-Visible, FT-IR, TGA and magnetic susceptibility measurements. The spectral data revealed that the ligand acts as a neutral tetradentate Schiff base and coordinating through the azomethine nitrogen, two piperazine nitrogen atoms and carbonyl oxygen.
Keywords
Isatin; Schiff base; Epoxy resin; Curing; Epichlorohydrin;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
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1 Lakshmi, B.; Shivananda, K. N.; Mahendra, K. N. Bull. Korean Chem. Soc. 2010, 31, 2272.   DOI   ScienceOn
2 Lee, G.S.; Lee, Y.-C.; Myoung, S. G. Bull. Korean Chem. Soc. 2001, 22, 1393.
3 Shivananda, K. N.; Mahendra, K. N. Intern. Cong. Chem. Envi. 2005, 2, 337.
4 Rama Krishna Reddy, K.; Madhusudan Reddy, K.; Mahendra, K. N. Ind. J. Chem. 2006, 45A, 377.
5 Gudasi, K. B.; Patil, M. S.; Vadavi, R. S.; Shenoy, R. V.; Patil, S. A.; Nethaji, M. Trans. Met. Chem. 2006, 31, 580.   DOI
6 Thimmaiah, K. N.; Lioyd, W. D.; Chandrappa, G. T. Inorg. Chim. Acta 1985, 160, 81.
7 Gudasi, K. B.; Patil, M. S.; Vadavi, R. S.; Shenoy, R. V.; Patil, S. A.; Nethaji, M. Trans. Met. Chem. 2006, 31, 580.   DOI
8 Jain, M. C.; Shrivastava, A. K.; Jain, P. C. Inorg. Chim. Acta 1977, 199.
9 Canpolat, E.; Yciazi, A.; Kaya, M. Trans. Met. Chem. 2006, 31, 653.   DOI
10 Jones, R. R. In Chemistry and Technology of Epoxy Resins; Ellis, B., Ed.; London: Chapman and Hall 1993, 8, 256.
11 Vanaja, A.; Ph.D Thesis, Bangalore University, Bangalore 2003.
12 Lin, K. F.; Wang, W. H. Polym. Comp. 1995, 16(4), 269.   DOI   ScienceOn
13 Lin, K. F.; Shu, W. Y.; Wey, T. L. Polymer 1993, 34(2), 277.   DOI   ScienceOn
14 Lin, K. F.; Shu, W. Y.; Wey, T. L. Polymer 1993, 34(10), 2162.   DOI   ScienceOn
15 Anand, M.; Srivastava, A. K. Polym. Eng. Sci. 1997, 37(1), 183.   DOI   ScienceOn
16 Anand, M.; Srivastava, A. K. Angew, Makromol. Chem. 1994, 219, 1.   DOI   ScienceOn
17 Konstantinovic, S.; Radovanovic, B.; Cakic, Z.; Vasic, V. J. Serb. Chem. Soc. 2003, 68, 641.   DOI   ScienceOn
18 Hassaan, M. A.; Shehata, K. Synth. React. Inorg. Met.-Org. Chem. 1993, 25(3), 815.
19 Konstantinovic, S.; Radovanovic, B.; Cakic, Z.; Vasic, V. J. Serb. Chem. Soc. 2003, 68, 641.   DOI   ScienceOn
20 Murukan, B.; Mohanan, K. Trans. Met. Chem. 2006, 31, 653.   DOI
21 Nakamoto, K. Infrared Spectra of Inorganic and Coordination Compounds, 2nd ed.; Wiley-Inter Science: 1963; 172.
22 Manhas, B. S.; Sardana, A. K.; Kalia, S. B. Syn. Rea. Inorg. Metal-Org. and Nano-Metal Chemistry 2005, 35, 171.   DOI   ScienceOn
23 Anand, M.; Srivastava, A. K. Polymer 1993, 34(13), 2860.   DOI   ScienceOn
24 Anand, M.; Srivastava, A. K. J. Appl. Polym. Sci. 1994, 51(2), 203.   DOI   ScienceOn
25 Anand, M.; Srivastava, A. K. J. Macromol. Sci., Pure Appl. Chem. 1993, A30(5), 435.
26 Lin, K. F.; Shu, W. Y.; Wey, T. L. Polymer 1993, 34(10), 2162.   DOI   ScienceOn
27 Shivananda, K. N.; Mahendra, K. N. Bull. Korean Chem. Soc. 2006, 27, 1542.   DOI   ScienceOn
28 Shivananda, K. N.; Mahendra, K. N. Ira. Poly. Journal 2007, 16(3), 161.
29 Weinberger, P.; Costisor, O.; Tudose, R.; Baumgartner, O. Linert, Mol. Struct. 2004, 21, 519.
30 Rama Krishna Reddy, K.; Mahendra, K. N. Molbank 2006, M, 516. 10.
31 Lakshmi, B.; Shivananda, K. N.; Mahendra, K. N. Bull. Korean Chem. Soc. 2010, 31, 2272.   DOI   ScienceOn
32 Lee, G.-S.; Lee, Y.-C.; Myoung, S. G. Bull. Korean Chem. Soc. 2001, 22, 1393.
33 Kurnoskin, A. V. Journal of Macromolecular Science Reviews in Macromolecular Chemistry and Physics 1996, C36(3), 457.
34 Corhnelissen, J. P.; Van, J. H.; Diemen, L. R.; Groeneveld, J. G.; Haasnoot, A. L.; Spek, J.; Reedisk, Inorg. Chem. 1992, 31, 198.   DOI
35 Dubey, S. N.; Kaushik, B. Indian J. Chem. 1985, 24, 950.
36 Kurnoskin, A. V. In Metal-containing Epoxy Polymers; Cheremisinoff, N. P., Cheremisinoff, P. N., Eds.; New York: Marcel Dekker: 1996; p 703.
37 Kurnoskin, A. V. JMS Rev. Macromol. Chem. Phys. 1995, C35(3), 419.
38 Kurnoskin, A. V. Polym. Comp. 1993, 14, 481.   DOI   ScienceOn
39 Kurnoskin, A. V. Polymer. 1993, 34(5), 1060.   DOI   ScienceOn
40 Kurnoskin, A. V. Polymer 1993, 34(5), 1077.   DOI   ScienceOn
41 Kurnoskin, A. V. Ind. Eng. Chem. Res. 1992, 31, 524.   DOI
42 Kurnoskin, A. V. Polymer 1993, 34(5), 1077.   DOI   ScienceOn
43 Kurnoskin, A. V. Ind. Eng. Chem. Res. 1992, 31, 524.   DOI