• Title/Summary/Keyword: Co-contaminants

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High-$T_c$ SQUID Application for Roll to Roll Metallic Contaminant Detector

  • Tanaka, S.;Kitamura, Y.;Uchida, Y.;Hatsukade, Y.;Ohtani, T.;Suzuki, S.
    • Progress in Superconductivity
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    • v.14 no.2
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    • pp.82-86
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    • 2012
  • A sensitive eight-channel high-Tc Superconducting Interference Device (SQUID) detection system for magnetic contaminant in a lithium ion battery anode was developed. Finding ultra-small metallic foreign matter is an important issue for a manufacturer because metallic contaminants carry the risk of an internal short. When contamination occurs, the manufacturer of the product suffers a great loss from recalling the tainted product. Metallic particles with outer dimensions smaller than 100 microns cannot be detected using a conventional X-ray imaging system. Therefore, a highly sensitive detection system for small foreign matter is required. We have already developed a detection system based on a single-channel SQUID gradiometer and horizontal magnetization. For practical use, the detection width of the system should be increased to at least 65 mm by employing multiple sensors. In this paper, we present an 8-ch high-Tc SQUID roll-to-roll system for inspecting a lithium-ion battery anode with a width of 65 mm. A special microscopic type of a cryostat was developed upon which eight SQUID gradiometers were mounted. As a result, small iron particles of 35 microns on a real lithium-ion battery anode with a width of 70 mm were successfully detected. This system is practical for the detection of contaminants in a lithium ion battery anode sheet.

FIXATION OF LEAD CONTAMINANTS IN Pb-DOPED SOLIDIFIED WASTE FORMS

  • Lee, Dong-Jin;Chung, David;Hwang, Jong-Yeon;Choi, Hyun-Jin
    • Environmental Engineering Research
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    • v.12 no.3
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    • pp.101-108
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    • 2007
  • Fixation of lead contaminants in the solidification/stabilization using Portland cement has been investigated by X-ray diffraction, scanning electron microscopy and compressive strength. The presence of lead was observed to produce lead carbonate sulfate hydroxide ($Pb_4SO_4(CO_3)_2(OH)_2$), lead carbonate hydroxide hydrate ($3PbCO_3{\cdot}2Pb(OH)_2{\cdot}H_2O$) and two other unidentified lead salts in cavity areas and was observed to significantly retard the hydration of cement. By 28 days, howevere, the XRD peaks of most of the lead precipitates have essentially disappeared with only residual traces of lead carbonate sulfate hydroxide and lead carbonate hydroxide hydrate evident. After 28 days of curing, hydration appears well advanced with a strong portlandite peak present though C-S-H gel peaks are not particularly evident. Lead species produced with the dissolution of lead precipitates are fixed into the cement matrix to be calcium lead silicate hydrate (C-Pb-S-H) during cement-based solidification.

Numerical evaluation of risk rates for contamination sources in a minienvironment (클린룸 국소환경에서 오염원의 위험율에 대한 수치해석적 평가)

  • Noh, Kwang-Chul
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.181-189
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    • 2018
  • In this study, the risk rates of different contamination sources of the contaminant in a minienvironment were analyzed through Computational Fluid Dynamics (CFD) simulation. The airflow pattern characteristics can only predict the qualitative variation of contaminant concentration, but cannot evaluate the quantitative variations in the risk rate of sources. From the results, the ambient contamination sources mainly affect wafers in the Front Opening Unified Pod (FOUP), whereas the internal contamination sources mainly affect wafers laid on the robot arm in the minienvironment. And the purging plenum system is very useful in protecting the wafers in the FOUP from contaminants transferred from the Fan Filter Unit (FFU). However, this system is unable to protect the wafers on the robot arm from internal contaminants and the wafers in the FOUP from sources of the interface between the FOUP and the minienvironment.

Contamination structure and process on SUS 316 under UHV, HV and air (초고진공, 고진공, 대기압에서 SUS 316의 오염 구조와 오염 과정 연구)

  • 서지근;이규장;신용현;홍승수;정광화
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.1-8
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    • 1997
  • The contamination structure and process on SUS 316 under various exposure conditions were investigated using x-ray photoelectron spectroscopy. The metal-oxide, metal-H-oxides, CO, COH, and $C_xH_y$ are the main components of contaminants on the SUS surface. The compositional profiles of the contaminants are shown to be $C_xH_y$/CO(COH)/metal-oxide on SUS. The contamination proceeds in two steps. The oxidation of the metallic constituents followed by adsorption of hydrocarbons. Under UHV conditions the contamination is mainly due to the oxidation, and, as the exposure time increases, the oxidation continues. In HV or higher pressure, most of the oxides are formed almost immediately after exposure and as the exposure time increases the contamination of hydrocarbons continues to grow. For the SUS sample exposed to atmosphere, the metal oxide is distributed deep inside the surface with an exponentially decreasing concentration, and its thickness is nearly in the order of photoelectron mean free path. It is also seen that the Fe oxide is segregated over Cr oxide in the highly oxidized samples.

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Design of local exhaust ventilation for preventive maintenance in semiconductor fabrication industry using CFD (전산유체역학을 이용한 반도체 제조공정의 PM 전용 후드 설계 연구)

  • Hong, Jwaryung;Koo, Jae-Han;Park, Chang-Sup;Choi, Kwang-Min
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.29 no.2
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    • pp.208-216
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    • 2019
  • Objective: The aim of this study is to control residual chemicals or by-products generated in chambers during preventive maintenance (PM) in the semiconductor manufacturing industry. We designed local exhaust ventilation using computational fluid dynamics (CFD). Methods: The air flow characteristics and capture efficiency between rectangular and slot hoods were compared numerically. The software Fluent 18.1 was used to estimate uniform velocity distribution and capture efficiency for contaminants. A metal from group 15 in the periodic table was released at the bottom of the chamber to simulate emissions. Results: The slot hood had a higher capture efficiency than a rectangular hood under the same conditions because the slot hood provided uniform air flow and higher face velocity. Also, there was no rotating swirl in the plenum for slot, that is why slot had better efficiency than rectangular even though they had similar face velocity. With less than 10 slots, the capture efficiencies for contaminants were nearly 95%. The optimum conditions for a hood to achieve high efficiency was 8 to 10 slots and a face velocity over 1 m/s. Conclusions: Well-designed ventilation systems must consider both efficiency and convenience. For this study, a slot hood that had high capture efficiency and no work disturbance was designed. This will contribute to protection of the worker's health in a PM area and other areas as well. Also, this study confirms the possibility of the application CFD in the semiconductor fabrication industry.

Present Deterioration Situation and Study on the Cleaning of the Surface of the Octagonal nine storied pagoda of Woljeongsa Temple (월정사팔각구층석탑의 손상현황과 표면오염물 제거연구)

  • Hwang, Jeong Eun;Kim, Sa Dug;Jung, Hee Soo
    • 보존과학연구
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    • s.33
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    • pp.125-148
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    • 2012
  • The Octagonal nine storied pagoda of Woljeongsa Temple consists mainly of granite with the rockforming minerals quartz, plagioclase, microcline, and biotite. The surface of the stone stupa is light brown that has been discolored by the rust from the metal ornament and aids. The surface of the stylobate and roof stone is colonized by biological contaminants. Therefore, a comprehensive deterioration diagnosis was carried out in this study, and conservation treatment was conducted. It was proven that the $Fe^{2+}$ yield increases depending on the count of poultice used with oxalic acid, but the $Mg^{2+}$, $Al^{3+}$, and $Ca^{2+}$ yields were marginal following the preliminary test. Therefore, the use of poultice is an effective way of removing the rust, and only marginally influences the rock. The biological contaminants were removed through dry cleaning, and the soil located under the contaminants was removed through wet cleaning. Based on this, the dry and wet cleaning of all the biological contaminants, and the use of poultice with oxalic acid, were done to remove the rust. For the conservation treatment of the metal ornament, the rust was removed through physical cleaning, and anticorrosion treatment was performed on the iron ornament using Renaissance wax and copper ornament by BTA.

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A Evaluation Study on Indoor Air Quality of the Apartment House through Field Measurement (현장실험을 통한 공동주택의 실내공기환경 평가)

  • Park, Yong-Seung;Bae, Sang-Hwan;Yoo, Bok-Hee;Hong, Cheon-Hwa
    • Proceeding of Spring/Autumn Annual Conference of KHA
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    • 2003.11a
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    • pp.83-87
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    • 2003
  • In recent days, IAQ(Indoor Air Quality) is regarded as one of the most important environmental factors as well as thermal and acoustic comfort. Various architectural materials are applied and air-tightness of the building is more strengthening to save energy consumption. This is why the air quality of the newly built houses became worse. In this study, contaminants(CO, CO$_2$, Radon, TVOCs, HCHO) density was measured in a newly built house and evaluation was carried out by ASHRAE and EPA Standards. As a result, CO, CO$_2$, TSP and Radon density of the newly built house was in a range of ASHRAE and EPA Standards, but it turned out TVOCs and HCHO density exceeds almost 3${\sim}$5 times in comparison with that of ASHRAE and EPA Standards.

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Removal of EDCs from Industrial Sludge by Electron Beam

  • Han, Bumsoo;Kim, Jinkyu;Kim, Yuri;Jung, Seungtae;Park, Junhyung;Choi, Jangseung
    • Journal of Radiation Industry
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    • v.8 no.2
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    • pp.71-76
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    • 2014
  • Endocrine disrupting chemicals (EDCs) and potential EDCs are mostly man-made, found in various materials such as pesticides, additives or contaminants in food, and personal care products. The high energy ionizing radiation has the ability to remove the EDCs with a very high degree of reliability and in a clean and efficient manner. The ionizing radiation interacts with EDCs both directly and indirectly. Direct interaction takes place with EDCs and the structure of EDCs is destroyed or changed. During indirect interaction, radiolysis products of water result in the formation of highly reactive intermediates which then react with the target molecules, culminating in structural changes. To confirm the radiation reduction of EDCs in industrial sludge, a pilot scale experiment up to 50 kGy of electron beam (EB) was conducted with samples from the textile dyeing industries. The experimental result showed the over 90% of reduction of Nonylphenol (NP) and Di(2-ethylhexyl) phthalate (DEHP) at around 10 kGy of absorbed doses.