• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1763-1768
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• 2006

The application of poly(Co(II)-(1,8-diaminonaphthalene))(poly(Co-DAN)) and poly(1,8-diaminonaphthalene) (Poly(1,8-DAN)) to the electrocatalytic reduction of molecular oxygen was investigated, which were electrochemically grown by the potential cycling method on the glassy carbon electrodes. The reduction of oxygen at the polymer and its metal complex polymer coated electrodes were irreversible and diffusion controlled. The Poly(1,8-DAN) and Poly(Co-DAN) films revealed the potential shifts for the oxygen reduction to 30 mV and 110 mV, respectively, in an aqueous solution, compared with that of the bare electrode. Hydrodynamic voltammetry with a rotating ring-disk electrode showed that Poly(1,8-DAN) and Poly(Co-DAN) coated electrodes converted respectively 84% and 22% of $O_2$ to $H_2O$ via a four electron reduction pathway.

• Bulletin of the Korean Chemical Society
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• v.20 no.10
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• pp.1149-1152
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• 1999

1H NMR spectrum of a DMF-d7 solution containing 4-aminopyrimidine and [SiW11CoIIO39]6- (SiW11Co) shows separate peaks from two linkage isomers, a and b, in which N(1) and N(3) of the pyrimidine ring are coordinated to SiW11Co, respectively. The signal from the amine group in the isomer a exhibits temperature dependence that is characteristic of a two-site exchange problem. Rates of internal rotation of the amine group were determined by simulating the NMR spectra at 5-35℃. The amine group of free 4-aminopyrimidine also shows temperature-dependent spectra at lower temperatures; rates of internal rotation at (-25)-25℃ were determined. The internal rotation of the amine group in the complex is much slower than that for free 4-aminopyrimidine, indicating that π-character of the C-N bond increases on coordination to SiW11Co. The amine group in the isomer b does not show such behavior. It is probable that hydrogen bonding between N-H and a bridging oxygen atom of SiW11Co prevents it from rotating at low temperatures.

• Journal of Microbiology
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• v.41 no.2
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• pp.73-77
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• 2003

Four proteolytic bacteria were isolated and identified from a rotating biological contactor based on Bacillus. The four isolates, Ni 26, 36, 39 and 49 were identified as B. vallismortis, B. subtilis, Aeromonas hydrophila and B. amyioliquefaciens, respectively, based on their biochemical properties and 16S rDNA sequence analyses. The optimal proteolytic activity was observed in the temperature and pH ranges of 40-70$^{\circ}C$ and 8.0-8.5, respectively. The proteolytic activities of all the isolates were partially inhibited by phenylmethylsulfonylfluoride (PMSF), and the isolates Ni 26, Ni 39 and Ni 49 were inhibited by the metalloprotease inhibitor, 1,10-phenanthroline. Zymographic analyses of the culture supernatants revealed the presence of at least two pretenses in all isolates.

• Proceedings of the KIEE Conference
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• 2006.07b
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• pp.725-726
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• 2006

In large scale superconducting rotating machine, HTS field coils are constructed with many stacks of single or double pancake coils connected in series. In spite of its higher thermal stability, HTS field coil experiences some quench, which results in some part of burn-out in the field coils. Thus in the view point of the HTS rotating machine field coil design and testing, it was very important to predict the possibility of quench occurrence in the designed field coils. In this paper, a HTS racetrack coil constructed with two single pancake coils and one double pancake coil was tested in LN2 and cooling by GM refrigerator. It is wound using the Bi-2223 tape. The experimental details and results are presented in this paper.

• Journal of the Korean Society of Visualization
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• v.20 no.3
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• pp.128-135
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• 2022

Cavitation occurs inevitably in marine propellers rotating at high speed in the water, which is a major cause of underwater radiated noise. Cavitation-induced noise from propellers rotating at a specific frequency not only reduces the sonar detection capability, but also exposes the ship's location, and it causes very fatal consequences for the survivability of the navy vessels. Therefore cavity inception speed (CIS) is one of the important factors determining the special performance of the ship. In this study, we present a method using computer vision that can detect and quantitatively estimate tip vortex cavitation on a propeller rotating at high speed. Based on the model test results performed in a large cavitation tunnel, the effectiveness of this method was verified.

• International Journal of Fluid Machinery and Systems
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• v.9 no.3
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• pp.194-204
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• 2016

Floating ring seals offer an opportunity to reduce leakage flows significantly in rotating machinery. Accordingly, they have been applied successfully to rotating machinery within the last several decades. For rocket turbopump applications, fundamental behavior and design philosophy have been revealed. However, further work is needed to explore the rotordynamic characteristics associated with rotor vibrations. In this study, rotordynamic forces for floating ring seals under rotor's whirling motions are calculated to elucidate rotordynamic characteristics. Comparisons between numerical simulation results and experiments demonstrated in our previous report are carried out. The three-dimensional Reynolds equation is solved by the finite-difference method to calculate hydrodynamic pressure distributions and the leakage flow rate. The entrance loss at the upstream inlet of the seal ring is calculated to estimate the Lomakin effect. The friction force at the secondary seal surface is also considered. Numerical simulation results showed that the rotordynamic forces of this type of floating ring seal are determined mainly by the friction force at the secondary seal surface. The seal ring is positioned almost concentrically relative to the rotor by the Lomakin effect. Numerical simulations agree quite well with the experimental results.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05d
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• pp.38-42
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• 2003

The use of VPI impregnated mica tape as high voltage insulation for large rotating electric machines requires a careful balance of processes and materials to obtain the desired electrical, mechanical and thermal characteristics. The stator insulation systems such as epoxy bonded high voltage mica tape have been produced for many years. One such system employing an epoxy and anhydride impregnating resin developed by Hyundai Heavy Industries, Co. (hereafter, HHI), to satisfy customer requests for an epoxy bonded insulation system. HHI applies the following electrical and thermal evaluations such as dielectric breakdown, voltage endurance, dissipation factor vs. temperature, isothermal weight loss, and so on. A detailed laboratory evaluation can describe specific physical limitations for an insulation system and permit development of long-term operation guidelines that permit full utilization of the proposed system. HHI has found these evaluations very helpful in qualifying insulation system for the repair of both large motors and generators.

• 제어로봇시스템학회:학술대회논문집
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• 1993.10b
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• pp.440-445
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• 1993

A two dimensional large scale laser digitizer with a cordless cursor was developed. The coordinate detecting scheme of this digitizer is fundamentally based on the triangulation method, in which two laser-rays are scanned by the rotating plane mirros, reflected backward by the cursor, reflected again by the rotating mirrors, and detected by optical sensors. From angles in which the cursor reflections are detected, we can determine the position of the cursor. But this method involves several problems about optical alignment and its calibration especially when it is applied to a large scale digitizer. In this paper, especially we propose simulation for error analysis with connection to angles measured at five control points which are needed to decide an appropriate model for calculating coordinates and optimal simulation for deciding the position of five control points to give the better coordinate accuracy. In this way, we realized the on-site calibration and on-site insurance of measurement accuracy with our appropriate model for calculating coordinates. The time required for on-site calibration is within 5 minutes and the average accuracy of 4m * 3m digitizer is about .+-.0.12mm.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.495-499
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• 2009

본 논문에서는 상호역회전 풍력발전기와 New Yaw System 실증시험에 대하여 제시한다. 상호역회전 풍력발전기는 공기의 유동을 가진 운동에너지의 공기역학적(aerodynamic) 특성을 이용하여 동일한 바람방향에 대해 상호 반대방향으로 회전하는 Front Blade와 Rear Blade를, Generator의 Rotor와 Stator에 각각 결합 형성한 것으로, Generator와 Dual Blade의 회전력이 원심력이 아닌 구심력으로 변환되어 무게중심이 균형을 이루게 한다. 이렇게 변환된 구심력은 회전구동부분의 편마모 현상, 소음발생 현상 및 불균형 톨크 발생 현상 감소효과가 공히 구현되도록 하여 풍력발전기의 구조적 안정성 및 발전효율 증대효과를 얻을 수 있도록 한 기술이다.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2004.11a
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• pp.201-208
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• 2004

In this study a general Galerkin FE lubrication analysis method was utilized to analyze the complex lubrication performance of a spiral groove seal having an additional inner circular groove, which was designed for a chemical process mixer operating at a low speed of the maximum 500 rpm. Equilibrium seal clearance analyses under varying outer pressure revealed that the seal maintains a certain levitation seal clearance under the outer pressure of more than about 1.5 bar, regardless of a rotating speed. Also, under the normal outer pressure of 11 bar, the axial stiffness of the seal was predicted to have a high value of more than 7.0e+07 N/m, regardless of a rotating speed and thereby, the seal is expected to maintain a stable thickness of lubrication film under a certain external excitation acting.