• Title/Summary/Keyword: Co-Evolution

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Enzyme Kinetics Based Modeling of Respiration Rate for 'Fuyu' Persimmon (Diospyros kaki) Fruits (효소반응속도론에 기초한 단감의 호흡 모델에 관한 연구)

  • Ahn, Gwang-Hwan;Lee, Dong-Sun
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.580-585
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    • 2004
  • Respiration of 'Fuyu' persimmon (Diospyros kaki) fruits were measured in terms of oxygen consumption rate and carbon dioxide evolution by closed system experiments at 0, 5, and $20^{\circ}C$. Enzyme kinetics-based respiration model was used to describe respiration rate as function of $O_2\;and\;CO_2$ gas concentrations $(R=V_m[O_2]/K_m+(1+[CO_2]/K_i)[O_2])$, and Arrhenius equation was applied to analyze temperature effect. $V_m\;and\;K_m$ increased, while $K_i$ decreased, with increasing temperature. $K_m\;of\;O_2$ consumption was greater than that of $CO_2$ evolution at equal temperature. Inhibitory effect of reduced $O_2$ level on $O_2$ consumption was more prominent than that on $CO_2$ evolution. Activation energy of respiration decreased with reduced $O_2$ and elevated $CO_2$ concentrations. Activation energy of $CO_2$ evolution was greater than that of $O_2$ consumption. Permeable package experiments verified respiration model parameters by showing good agreement between predicted and experimental gas concentrations in package.

Performance Analysis of Coordinated Multi-Point with Scheduling and Precoding schemes in LTE-Advanced System (LTE-Advanced 시스템에서 스케줄링 및 프리코딩을 결합한 다중 포인트 협력 통신 기법의 성능 분석)

  • Kim, Bora;Moon, Sangmi;Malik, Saransh;Kim, Cheolsung;Hwang, Intae
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.7
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    • pp.27-33
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    • 2013
  • In this paper, we design and analyze the performance of Coordinated Multi-Point (CoMP) techniques to the number of users for next-generation cellular systems. We perform Monte Carlo simulations with Long Term Evolution-Advanced (LTE-Advanced) and confirm the performance from the graph of the Cumulative Distribution Function (CDF). From simulation results, we show the significant performance gain when CoMP technique is used and also show better performance when we apply the various schemes additionally as scheduling and precoding.

A Numerical Investigation of Hydrogen Absorption Reaction Based on ZrCo for Tritium Storage (I) (삼중수소 저장을 위한 ZrCo 저장재에서의 수소 흡장에 대한 수치해석적 연구 (I))

  • Yoo, Haneul;Yun, Seihun;Chang, Minho;Kang, Hyungoo;Ju, Hyunchul
    • Journal of Hydrogen and New Energy
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    • v.23 no.5
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    • pp.448-454
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    • 2012
  • In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

Synthesis and Evaluation of Ir/TiO2 OER catalyst for PEM water electrolysis (수전해용 Ir/TiO2 산소 발생 촉매의 제조 및 성능 평가)

  • SONG, MINAH;JUNG, HYEYOUNG;LEE, HAEJI;CHOI, YUNKI;MOON, SANGBONG
    • Journal of Hydrogen and New Energy
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    • v.27 no.5
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    • pp.471-477
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    • 2016
  • In this research, the Ir supported $TiO_2$ (P25) catalyst was prepared by precipitation method for oxygen evolution reaction. The $Ir/TiO_2$ catalyst was synthesised by reduction reaction using reducing agent. Physiochemical characterizations of synthesized $Ir/TiO_2$ catalyst was studied by means of SEM, EDS mapping, TEM and XRD. The Electrochemical characterizations were tested by using the technique of CV and LSV by RDE and Potentiostat. Physicochemical properties were characterized with XRD where Iridium metal morphology and Ir(111) and Ir(222) peaks were founded. $Ir0.2Ru0.8O_2$ exhibited higher OER activity than $Ir0.5Ru0.5O_2$ followed by $Ir/TiO_2$ and $IrO_2$.

Synthesis and Electrochemical Evaluation of La1-xSrxCoO3 Cathode Material for Zinc Air Secondary Batteries Application (아연공기이차전지용 La1-xSrxCoO3 양극촉매의 제조 및 이를 적용한 양극의 전기화학적 특성연구)

  • Eom, Seung-Wook;Sun, Yang-Kook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.5
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    • pp.447-452
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    • 2008
  • We synthesized nano-sized $La_{1-x}Sr_xCoO_3$ ($x=0.1{\sim}0.4$) cathode catalyst for the zinc air secondary batteries by citrate method, And we measured the cathode's electrochemical characteristics according to content of strontium compose the cathode catalyst. We controlled the pH of precursor solution by 10 in the process of manufacturing the precursor, We heat treated the prepared precursor at various calcination temperature ($500{\sim}900^{\circ}C$), and examined the optimum calcinations temperature by XRD analysis and electrochemical evaluation. We examined the ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) performance of the prepared $La_{1-x}Sr_xCoO_3$ catalyst powder. When we consider ORR and OER performance simultaneously, $La_{0.7}Sr_{0.3}CoO_3$ catalyst has shown the best performance because of its lowest voltage deference between charge and discharge.

ALMA/ACA CO (1-0) observations of group galaxies

  • Lee, Bumhyun;Wang, Jing;Chung, Aeree;Ho, Luis C.;Wang, Ran;Shao, Li;Michiyama, Tomonari;Wang, Shun;Peng, Eric W.;Kilborn, Virginia
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.64.1-64.1
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    • 2020
  • Galaxy groups are the place where many galaxies feel the impact of the surroundings (e.g., merging, tidal interaction, ram pressure stripping) before joining bigger structures like (sub)clusters. A significant fraction of galaxies is quenched in the group environment. Such "pre-processing" of galaxies in groups is likely to affect galaxy evolution tremendously. To better understand how environmental processes in galaxy groups affect molecular gas, star formation activity, and galaxy evolution, we carried out CO imaging observations of group galaxies, using the Atacama Compact Array (ALMA/ACA). We selected all the targets that have been detected in the GEMS-HI survey for two groups, making the sample of 40 galaxies (18 galaxies in IC 1459 group and 22 galaxies in NGC 4636 group). Our ALMA/ACA observation is the first CO imaging survey for two groups. In this work, we present CO images of group galaxies, together with their star formation maps and HI images. Our ACA CO data show the asymmetric distribution of molecular gas in some of our samples. We discuss the impact of the group environment on molecular gas and star formation activity.

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Investigating the cosmic evolution of the black hole mass-bulge luminosity scaling relation

  • Park, Daeseong;Woo, Jong-Hak;Treu, Tommaso;Bennert, Vardha N.;Malkan, Matthew A.;Auger, Matthew W.
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.42.2-42.2
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    • 2013
  • We investigate the cosmic evolution of the black hole mass-bulge luminosity relation with a sample of 52 moderate-luminosity AGNs at $z{\simeq}0.36$ and $z{\simeq}0.57$, corresponding to look-back times of 4 and 6 Gyrs. By employing robust multi-component spectral and structural decomposition methods to the obtained high-quality Keck spectra and high-resolution HST images, black hole masses ($M_{BH}$) are estimated from the Hbeta broad emission line with the 5100A nuclear luminosity, and bulge luminosities ($L_{bul}$) are derived from the surface photometry. Based on these consistent measurements, we constrain the redshift evolution of the $M_{BH}-L_{bul}$ relation by performing the Monte Carlo simulations designed to account for selection effects. We provide implications of our results in terms of the black hole-galaxy co-evolution and discuss possible bulge growth mechanisms.

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A Study on Oxygen Evolution Activity of Co3O4 with different morphology prepared by Ultrasonic Spray Pyrolysis for Water Electrolysis (분무열분해로 합성한 수전해용 Co3O4의 입자형태에 따른 산소발생 활성에 관한 연구)

  • Kim, Ingyeom;Nah, In Wook;Park, Sehkyu
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.854-862
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    • 2016
  • As the demand for a clean energy to replace fossil fuel being depleted increases, hydrogen energy is considered as a promising candidate for future energy source. Water electrolysis which produces hydrogen has high energy efficiency and stability but still has a large overpotential for oxygen evolution reaction (OER). In this study, $Co_3O_4$ catalysts with different morphology were prepared by spray pyrolysis from solutions which contain Co precursor and various organic additives (urea, sucrose, and citric acid), followed by post heat treatment. For the catalysts synthesized, X-ray diffraction (XRD) measurements were performed to identify their crystal structure. Morphology and surface shape of the catalysts were observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Surface area and pore volume were examined by nitrogen adsortpion & desorption tests and X-ray photoelectron spectroscopy (XPS) was conducted to confirm nitrogen doping. Linear sweep voltammetry (LSV) was carried out to investigate OER activity of $Co_3O_4$ catalysts. As a result, bare-$Co_3O_4$ which has high surface area and small particle size determined by spray pyrolysis showed high activity toward OER.

Synthesis of CoFe2O4 Nanoparticles as Electrocatalyst for Oxygen Evolution Reaction (산소 발생 반응 용 전기화학촉매로 사용되는 CoFe2O4 나노 입자 합성 및 특성 분석)

  • Lee, Jooyoung;Kim, Geulhan;Yang, Juchan;Park, Yoo Sei;Jang, Myeong Je;Choi, Sung Mook
    • Journal of the Korean Electrochemical Society
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    • v.23 no.4
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    • pp.97-104
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    • 2020
  • One of the main challenges of electrochemical water splitting technology is to develop a high performance, low cost oxygen-evolving electrode capable of substituting a noble metal catalyst, Ir or Ru based catalyst. In this work, CoFe2O4 nanoparticles with sub-44 nmsize of a inverse spinel structure for oxygen evolution reaction (OER) were synthesized by the injection of KNO3 and NaOH solution to a preheated CoSO4 and Fe(NO3)3 solution. The synthesis time of CoFe2O4 nanoparticles was controlled to control particle and crystallite size. When the synthesis time was 6 h, CoFe2O4 nanoparticles had high conductivity and electrochemical surface area. The overpotential at current denstiy of 10 mA/㎠ and Tafel slope of CoFe2O4 (6h) were 395 mV and 52 mV/dec, respectively. In addition, the catalyst showed excellent durability for 18 hours at 10 mA/㎠.