• Korean Chemical Engineering Research
• /
• v.60 no.4
• /
• pp.582-587
• /
• 2022

Biphasic solvents are attracting attention as energy-reducing solvents for capturing CO₂ from flue gas in combustion process. In this study, considering diethylenetriamine (DETA) and diethylethanolamine (DEEA) mixed solvents, one of the biphasic solvents by blending of two types of amines, the CO₂ absorption rates of DETA and DEEA was measured by wetted wall column. The effects of DETA and DEEA concentrations and operating temperature on the overall mass transfer coefficient were investigated. As a result, the overall mass transfer coefficient was proportional to the DETA concentration. However, in the case of the DEEA concentration, the effect was small and when the concentration was exceeded, the overall mass transfer coefficient decreased. The DETA aqueous solution showed little change in the overall mass transfer coefficient with the operating temperature, whereas the DEEA aqueous solution increased the overall mass transfer coefficient with the operating temperature. As a result of obtaining the observed reaction rate constant under the pseudo-first-order reaction assumption, it was found that the observed reaction rate constant in DETA aqueous solution was proportional to the DETA concentration, but DEEA did not fit the pseudo-first-order reaction assumption.

• Korean Journal of Soil Science and Fertilizer
• /
• v.46 no.6
• /
• pp.502-509
• /
• 2013

To estimate greenhouse gas (GHG) emission, we established inventory of conventional rice cultivation from farmers in Gunsan and Iksan, Jeonbuk province in 2011~2012. This study was to calculate carbon footprint and to analyse the major factor of GHGs. We carried out a sensitivity analysis using the analyzed main factors of GHGs and estimated the mitigation potential of GHGs. Also we tried to suggest agricultural methods to reduce GHGs that farmers of this case study can apply. Carbon footprint of rice production unit of 1 kg was 2.21 kg $CO_2.-eq.kg^{-1}$. Although amount of $CO_2$ emissions is largest among GHGs, methane had the highest contribution of carbon footprint on rice production system after methane was converted to carbon dioxide equivalent ($CO_2$-eq.) multiplied by the global warming potential (GWP). Source of $CO_2$ in the cultivation of rice farming is incomplete combustion of fossil fuels used by agricultural machinery. Most of the $CH_4$ emitted during rice cultivation and major factor of $CH_4$ emission is flooded paddy field in anaerobic condition. Most of the $N_2O$ emitted from rice cultivation process and major sources of $N_2O$ emission is application of fertilizer such as compound fertilizer, urea, orgainc fertilizer, etc. As a result of sensitivity analysis due to the variation in energy consumption, diesel had the highest sensitivity among the energies inputs. If diesel consumption is reduced by 10%, it could be estimated that $CO_2$ potential reduction is about 2.5%. When application rate of compound fertilizer reduces by 10%, the potential reduction is calculated to be approximately 1% for $CO_2$ and approximately 1.8% for $N_2O$. When drainage duration is decreased until 10 days, methane emissions is reduced by approximately 4.5%. That is to say drainage days, tillage, and reducing diesel consumption were the main sources having the largest effect of GHG reduction due to changing amount of inputs. Accordingly, proposed methods to decrease GHG emissions were no-tillage, midsummer drainage, etc.

• Journal of Korean Society for Atmospheric Environment
• /
• v.26 no.3
• /
• pp.276-285
• /
• 2010

Recently the Korean government has tried to cut down the $PM_{10}$ concentration by the Special Law for Air Quality Improvement. But the concentrations of $PM_{10}$ have exceeded the air quality standard at most monitoring stations. Primary $PM_{10}$ emitted from various sources and emission data have large uncertainty. The biomass burning is one of the major sources of $PM_{10}$ emission. The biomass burning is composed of wood stove usage, meat cooking and agricultural combustion etc.. Activity data and emission factors for the biomass burning are limited, and it is hard to calculate the air pollution emissions from these sources. In this study, we tried to estimate the air pollution emission from residential wood stove usage. The number of total wood stoves is estimated by the survey of wood stove manufacturer. And air pollution emission factors for the wood stove are investigated using the flue gas measurement by U.S. EPA particulate test method (Method 5G). As the results, the $PM_{10}$ and CO emission factors of wood stove are estimated as 7.7 g/kg-wood and 78.8 g/kg-wood respectively. The annual $PM_{10}$ and CO emissions from wood stove are calculated as 1,200~3,600 ton/year and 12,600~36,400 ton/year in Korea. It is confirmed that wood stove is the one of major sources of biomass burning, and the survey for activity data and the measurement for emission factors are needed for reducing the uncertainty of these emission data.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• v.y2005m4
• /
• pp.88-91
• /
• 2005

The combustion characteristics of high burning HTPB/AP solid propellants have been investigated by means of a closed bomb method of interval volume of 200 co and 700 cc at pressures from 1000 to 30,000 psi. The burning rate data measured by closed bomb are in good agreement with strand burner test results at pressure from 1000 to 5000 psi using disc sample of 1 mm thickness. The burning rate dat by using 200 cc closed bomb are in general agreement with that of 700 cc closed bomb. At pressure between $5,000\sim7,000$ psi, a market increase in pressure dependence of the linear burning rate occurs for HTPB/AP propellant.

• Journal of the Korean Institute of Gas
• /
• v.11 no.1 s.34
• /
• pp.1-8
• /
• 2007

The purpose of this study is to conduct a survey of the flame stability range and the emission characteristics for the optimum design of turbulent premixed flat burner. For that, the flame stability range was selected by the direct photography of the flame. And the mean temperature and CO, HC, $CO_{2}\;and\;O_{2}$ concentration distributions by changing the excess air ratio were measured. As results of this study, the flame stability range turned out to be getting narrower as fuel flow was increased. The blue flame mode was more excellent than any other flame modes in the emission characteristics by excess air ratio change. And the emission characteristics by fuel flow change were best at fuel flow 1l/min. Also, we found combustion noise during experiment of flame stability range. It had nothing do with excess air ratio range.

• Resources Recycling
• /
• v.20 no.5
• /
• pp.52-57
• /
• 2011

This study was conducted to examine the possibilities to utilize the mixture of domestic and organic wastes from B-city as a fuel. All types of mixing ratio for uncarried waste, sludge cake, and food waste were found 10 generate heating value with 6,000 kcal/kg, and in case of sludge cake the concentration of toxic substance produced was found to be decreased as air-fuel ratio and temperature were increased. It was noted that toxic gases such as CO, NOx, and SOx were observed below concentration of emission standard, and temperature inside the incinerator was stabilized at 2 of air-fuel ratio and 800$^{\circ}C$. It was observed that a heating value of 6000 kcal/kg generated using RDF(Refuse Derived Fuel) was appropriate to utilize a fuel if a complete combustion was attained.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.31 no.6
• /
• pp.88-95
• /
• 2003

The weighted sum of gray gas model(WSGGM) is applied to arbitrary mixtures of CO$_2$ and H$_2$0 gases. To evaluate this model, the spectral and total intensities are obtained for two different problem types. One has uniform, parabolic and boundary layer type temperature profiles with uniform partial pressure, and the other has nonuniform partial pressure and temperature profile. The results obtained from the two different problem types show fairly good agreements with the results obtained by the statistical narrow band model(SNB model) which is regarded as the reference solutions. The WSGGM and its data base provided by this study can be used for analysis of radiative transfer by combustion gases with different thermal loadings and chemical compositions.

• Journal of the Korean Professional Engineers Association
• /
• v.28 no.4
• /
• pp.14-20
• /
• 1995

Discourses on global environment are not only limited to the matter of simple environmen-tal protection but also going to an imperative that every country should take the environ-mental aspects into more consideration, and if necessary even proceed to modify its own strategies for economic growth. It is because scores of existing International conventions and agreements on environmental caused tend to combine the environmental issues with trade sanctions and financial assistances in order to ensure a mandatory power in pushing themselves through on a global dimension. Particularly noteworthy is the so -called Green Round(GR) which substantially associates the Issues of environmental protection with some sanctions in international trade, its rationale is quite simple. The differentiated production costs rising from the difference in environmental standards among different countries may affect national competitiveness in in-ternational trade, therefore a need does exist to countervail this difference. In reality, however, severe dissention seems to have been exposed between the developed and developing countries around this matter, because national interests and priorities in national goals considerably differ among respective countries. Greenhouse gases such as carbon dioxide which caused global warming are mostly released from the combustion of fossil fuels. The perfect removal of released $CO_{2}$ is impossible with existing technologies, and moreover, it's not payable in economical terms. Therefore it will be more effective and desirable to make more efforts to prevent the release of the $CO_{2}$ it- self through energy conservation involving the development and promotion of clean and high-efficient energy technologies and energy sources, and the development and promotion of new & renewable energy resources, and so on. One of important national tasks In our country is to establish an Energy Policy consider-ing environmental impacts since Korea depends most of its energy consumption on the fossil fuels such as oil and coal.

• 기계와재료
• /
• v.24 no.2
• /
• pp.38-46
• /
• 2012

인구의 증가와 급속한 산업화 그리고 편안함을 추구하고자 하는 문명의 이기로 인한 에너지 사용량 증가는 환경오염을 가속화시키는 문제를 유발하고 있어 전 세계적으로 심각한 사회문제로 대두되고 있다. 이에 반해 삶의 질의 향상에 따라 보다 쾌적한 환경에 대한 욕구와 인식의 변화로 환경보호에 대한 관심이 증가하는 추세이며, 이에 따라 각 국의 환경규제는 날로 강화되고 있다. 이러한 환경문제를 해결하기 위한 국제협력이 활발해지면서 무역과 연계된 국제 환경규제가 가속화되고 있으며, 환경선진국은 이러한 환경규제를 무역장벽으로 이용하고 있어 국가의 대외경쟁력에도 직 간접적으로 영향을 미치고 있다. 환경오염물질 중 질소산화물(NOx), 황산화물(SOx), 일산화탄소(CO), 이산화탄소($CO_2$) 및 휘발성유기화합물(VOCs), 다이옥신 그리고 입자상물질(PM)과 같은 대기오염물질은 대기 중으로 쉽게 확산되는 특성에 의해 인접한 지역까지 영향을 미치기 때문에 국제적인 규제대상의 초점이 되고 있으며, 경제협력개발기구(OECD, Organization for Economic Cooperation and Development), 유엔산하 국제해사기구(IMO, International Maritime Organization) 및 국제연소기구협회(CIMAC, International Council on Combustion engines)등 여러 국제기구를 중심으로 각종 규제수단을 개발하여 적용하고 있다. 특히, 국제해사기구(IMO)에서는 선박에서 발생되는 오염물질 등에 대한 규제강화를 위하여 새로운 국제해양오염방지협약(MARPOL)을 채택, 발효하여 그 규제 범위를 넓혀감에 따라 선박에 대한 각종 환경규제가 대폭 강화되고 있어 친환경 선박 및 관련 기술 개발이 활발히 진행 중에 있다. 이 글에서는 선박에서 배출되는 대기오염물질 중 그 자체로도 인체에 유해하며, 산성비, 광화학스모그 등 다양한 환경문제를 유발시키는 대표적인 물질인 질소산화물(NOx)과 질소산화물 배출규제에 대한 대응기술인 선택적촉매환원법(SCR, Selective Catalytic Reduction)과 SCR 탈질시스템에 사용되는 SCR 촉매에 대해 소개하고자 한다.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.25 no.6
• /
• pp.788-794
• /
• 2019

Recently, global climate change caused by greenhouse gases has emerged as a significant air-environmental problem. Technical innovation in response to this phenomenon is ongoing, with an emphasis on the environmental impacts of unusually high temperatures and unexpected heavy rainfall. In this study, we investigated the effects of temperature change on air pollution for a concomitant rapid temperature increase. The test conditions include loading from 0 % to 100 % at 1400 rpm, 1600 rpm, and 1800 rpm for a change in the intake air temperature of a marine diesel engine from 20 ℃ to 50 ℃. The experimental results revealed that CO and HC decreased slightly, whereas the brake specific fuel consumption, NOx, and PM increased slightly when the intake air temperature changed. In addition, it was determined that the combustion temperature did not change significantly.