• Title/Summary/Keyword: Co-Based alloy

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Effect of Boron Additions on Glass Formation and Magnetic Properties of Fe-Co-Ti-Zr-B Amorphous Ribbons

  • Kim, Sumin;Han, Bo Kyeong;Choi-Yim, Haein
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.164-167
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    • 2016
  • The effect of the B additions on glass formation and magnetic properties is reported for the $Fe_{(87-x-y)}Co_yTi_7Zr_6B_x$ (x = 2, 4, 6 and y = 35, 40) alloy system. The ribbon samples with the width of 2 mm for each composition were prepared by the melt spinning technique; furthermore, their phase information was obtained from X-ray diffraction. Glass formation and magnetic properties were measured using differential scanning calorimetry and vibrating sample magnetometer respectively. The $Fe_{45}Co_{40}Ti_7Zr_6B_2$ (x = 2 and y = 40) system has the nanocrystalline phase identified as ${\alpha}-Fe$, as well as the amorphous phase, whereas all other alloys are fully amorphous. It is associated with the role of B on the glass formation. The widest supercooled liquid region is obtained as 71 K at x = 4 (both y = 35 and 40). The saturation magnetization decreases with the increase of the amount of the B addition, and the highest value is 1.59 T as x = 2 and y = 35 for this alloy system.

Development of Metal Composite Powder Non-corrosive Flux for Low Temperature Forming of the Aluminum Brazing Filler Material (비부식성 플럭스를 이용한 알루미늄 브레이징용 필러 소재의 저온 성형용 금속 복합 분말 개발)

  • Kim, Dae-Young;Jang, Ha-Neul;Yoon, Dae-Ho;Shin, Yun-Ho;Kim, Seong-Ho;Choi, Hyun-Joo
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.16-21
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    • 2019
  • In aluminum brazing processes, corrosive flux, which is used in preventing oxidation, is currently raising environmental concerns because it generates many pollutants such as dioxin. The brazing process involving non-corrosive flux is known to encounter difficulties because the melting temperature of the flux is similar to that of the base material. In this study, a new brazing filler material is developed based on aluminum and non-corrosive flux composite powder. To minimize the interference of consolidation aluminum alloy powder by the flux, the flux is intentionally embedded in the aluminum alloy powder using a mechanical milling process. This study demonstrates that the morphology of the composite powder can be varied according to the mixing process, and this significantly affects the relative density and mechanical properties of the final filler samples.

Modeling of Dynamic Hysteresis Based on Takagi-Sugeno Fuzzy Duhem Model

  • Lee, Sang-Yun;Park, Mignon;Baek, Jaeho
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.13 no.4
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    • pp.277-283
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    • 2013
  • In this study, we propose a novel method for modeling dynamic hysteresis. Hysteresis is a widespread phenomenon that is observed in many physical systems. Many different models have been developed for representing a hysteretic system. Among them, the Duhem model is a classical nonlinear dynamic hysteresis model satisfying the properties of hysteresis. The purpose of this work is to develop a novel method that expresses the local dynamics of the Duhem model by a linear system model. Our approach utilizes a certain type of fuzzy system that is based on Takagi-Sugeno (T-S) fuzzy models. The proposed T-S fuzzy Duhem model is achieved by fuzzy blending of the linear system model. A simulated example applied to shape memory alloy actuators, which have typical hysteretic properties, illustrates the applicability of our proposed scheme.

Relationship Between AC and DC Magnetic Properties of an Iron-Based Amorphous Alloy for High Frequency Applications

  • Choi, Y.S.;Noh, T.H.;Lim, S.H.
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.24-30
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    • 1996
  • The relationship between effective permeability and the remanence ratio of an Fe-based amorphous alloy (Metglas 2605S3A) is investigated over a wide frequency range, in an effort to understand magnetization behavior of the alloy. In the frequency range from 1 to 200 kHz, the permeability is maximum at the remanence ratio of 0.4-0.5 and, at frequencies over 500 kHz, the correlation with negative coefficients emerges indicating that the permeability decreases with the remanent ratio, except for the ribbon coated with an insulating layer of MgO which exhibits both high values of the effective permeability and remanence ratio. It is considered from the correlation results that the boundary at which the dominant magnetization mechanism changes from domain wall motion to spin rotation is near 500 kHz. The core loss is also investigated as a function of annealing time when the samples are annealed at a fixed temperature of $435^{\circ}C$. The core loss in most cases decreases with the annealing time, the degree of the loss may consist of the hysteresis loss and anomalous eddy current loss. The two loss components are considered to be of similar magnitudes at low frequencies while, at high frequencies, the dominant contribution to the total loss is the anomalous loss.

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Investigation of Oxidation Behavior of Alloy 617 under Air/Helium Environments at 950℃ (니켈기 합금 Alloy 617의 950℃ 대기/헬륨 분위기에서 산화거동 고찰)

  • Jung, Sujin;Lee, Gyeong-Geun;Kim, Dong-Jin
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.218-224
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    • 2018
  • Alloy 617 is a candidate Ni-based superalloy for intermediate heat exchanger (IHX) of a high-temperature gas reactor (VHTR), because of its good creep strength and corrosion resistance at high temperature. Small amount of impurities such as $H_2O$, $H_2$, CO and $CH_4$ are introduced inevitably in helium, as a coolant during operation of a VHTR. Reactions of material and impurities are accelerated with increase of temperature to $950^{\circ}C$ of operating temperature of a VHTR, leading to material corrosion aggravation. In this circumstance, high-temperature corrosion tests were performed at $950^{\circ}C$ in air and impure helium environments, up to 250 hours in this study. Oxidation rate of $950^{\circ}C$ in an air environment was higher than that of impure helium, explained by difference in outer oxide morphology and microstructure as a function of oxygen partial pressure. An equiaxed Cr-rich surface oxide layer was formed in an air environment, and a columnar Cr-rich oxide was formed in an impure helium environment.

Microstructural evolution of rheocast Al-6.2wt.%Si alloy with isothermal stirring (Al-6.2wt.%Si 합금의 등온교반시간에 따른 미세조직변화)

  • Lee, Jung-Ill;Park, Ji-Ho;Kim, Gyeung-Ho;Lee, Ho-In
    • Journal of Korea Foundry Society
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    • v.15 no.5
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    • pp.514-522
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    • 1995
  • The microstructural evolution with isothermal stirring during semi-solid state processing of hypoeutectic Al-6.2wt%Si alloy was studied. Substructure of the individual primary solid particle in the slurry was investigated through transmission electron microscopy(TEM). Formation of subgrain boundaries on the rheocast Al-6.2wt%Si alloy is observed and the misorientation between the grains is shown typically under 2 degrees by analyzing selected area diffraction (SAD) and convergent beam electron diffraction (CBED) patterns. The existence of high angle grain boundaries are also observed in the alloy. Based upon these observations, mechanisms for the primary particles fragmentation are considered. With isothermal stirring, the dislocation density increases, and the evolution of dislocation cell structure takes place, which is interpreted as a process of achieving uniform deformation by dynamic recovery under applied shear stress.

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Enhanced mechanical properties and interface structure characterization of W-La2O3 alloy designed by an innovative combustion-based approach

  • Chen, Pengqi;Xu, Xian;Wei, Bangzheng;Chen, Jiayu;Qin, Yongqiang;Cheng, Jigui
    • Nuclear Engineering and Technology
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    • v.53 no.5
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    • pp.1593-1601
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    • 2021
  • Oxide dispersion strengthening (ODS) tungsten alloys are highly desirable in irradiation applications. However, how to improve the properties of ODS-tungsten alloys efficiently has been worth studying for a long time. Here we report a nanostructuring approach that achieves W-La2O3 alloy with a high level of flexural strength and Vickers hardness at room temperature, which have the maximum value of 581 MPa and 703 Hv, respectively. This method named solution combustion synthesis (SCS) can generate 30 nm coating structures W-La2O3 composite powders by using Keggin-type structural polyoxometalates as raw materials in a fast and low-cost process. The composite powder can be fabricated to W-La2O3 alloy with an optimal microstructure of submicrometric W grains coexisting with nanometric oxide particles in the grain interior, and a stability interface structure of grain boundaries (GBs) by forming transition zones. The method can be used to prepare new ODS alloys with excellent properties in the future.

Non-isothermal Stamping Analysis of Automotive Seat Cushion Panel Using Mg Alloy Sheet (마그네슘을 적용한 자동차 시트 쿠션 패널 비등온 성형해석)

  • Seo, Oh Suk;Lee, Chung An;Park, Chang Su;Kim, Hwa Jin;Lee, Kyoung Teak
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.5
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    • pp.605-611
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    • 2016
  • Mg alloy sheet exhibits significant differences in tensile and compressive yield stress depending on the temperature, as well as variations in its hardening behavior. Such unusual behavior makes it difficult to simulate the forming process of Mg alloy sheets. Results of analysis tend to deviate significantly from the experimental data because commercial software do not completely implement the unusual hardening behavior, yield asymmetry and temperature dependent changes in the Mg alloy's material properties. In the previous study, an in-plane tension-compression cyclic tester was developed to predict the cyclic behavior of Mg alloy sheets at an elevated temperature of up to $250^{\circ}C$. A new constitutive equation was suggested to analyze the unusual behavior, and was implemented in the commercial software in the form of user subroutine. In this paper, a stamping process of Mg seat cushion panel for automotive parts was simulated using the experimental data and user subroutine. Based on the analysis, an optimal temperature condition was determined and a stamping die shape at each step was suggested in the non-isothermal stamping of Mg alloy sheets.

Effects of Post Weld Heat Treatment on Microstructures of Alloy 617 and 263 Welds for Turbines of HSC Power Plants (HSC발전소 터빈용 초내열합금 Alloy 617 및 263 용접부의 미세조직에 미치는 후열처리의 영향)

  • Kim, Jeong Kil;Shim, Deog Nam;Park, Hae Ji
    • Journal of Welding and Joining
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    • v.34 no.3
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    • pp.52-60
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    • 2016
  • Recently nickel based superalloys are extensively being regarded as the materials for the steam turbine parts for hyper super critical (HSC) power plants working at the temperature over $700^{\circ}C$, since the materials have excellent strength and corrosion resistance in high temperature. In this paper, alloy 617 of solution strengthened material and alloy 263 of ${\gamma}^{\prime}$-precipitation strengthened material were prepared as the testing materials for HSC plants each other. Post weld heat treatment (PWHT) was conducted with the gas tungsten arc (GTA) welded specimens. The microstructure of the base metals and weld metals were investigated with Electron Probe Micro-Analysis (EPMA) and Scanning Transmission Electron Microscope (STEM). The experimental results revealed that Ti-Mo carbides were formed in both of the base metals and segregation of Co and Mo in both of the weld metals before PWHT and PWHT leaded to precipitation of various carbides such as Mo carbides in the specimens. Furthermore, fine ${\gamma}^{\prime}$ particles, that were not precipitated in the specimens before PWHT, were observed in base metal as well as in the weld metal of alloy 263 after PWHT.