• Title/Summary/Keyword: Co content

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Effect of TiC Content on Oxidation Behavior of Sintered WC-TiC-TaC Alloys

  • Tanaka, Hiroki;Mouri, Shigeki;Nakahara, Kenji;Sano, Hideaki;Zheng, Guo Bin;Uchiyama, Yasuo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.352-353
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    • 2006
  • The effect of TiC content on oxidation behavior of the sintered WC-TiC-TaC alloys with 2 mass% TaC and different TiC amounts of 3-45 mass% was investigated through oxidation tests in air at 973K. As a result of the tests, it was revealed that with increasing TiC content in the alloys, mass changes caused by oxidation and thickness of the scale decreased. Thus, it is considered that the main component of the scales changed gradually from $WO_3$ to $TiO_2$ with increasing TiC content in the alloys, and oxygen diffusion through the scale to the alloys was inhibited gradually.

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Effect of Ti on Spatter Generation of $CO_2$Welding ($CO_2$용접시 Spatter발생에 미치는 Ti의 영향)

  • 안영호;이종봉;방국수;엄동석
    • Journal of Welding and Joining
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    • v.14 no.5
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    • pp.106-112
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    • 1996
  • The effects of Ti addition in welding wire on the spatter generation and the droplet transfer phenomena were investigated. With increasing Ti content the spattering rate was decreased but the ratio of large size spatter (D $\geq$ 1. 0mm) was increased in both short circuit and globular transfer mode of $CO_2$welding. In short circuit transfer region, the arcing time was increased and the droplet transfer frequency was decreased with increasing Ti content In globular transfer region, the transition current and voltage to globular transfer was lowered and the welding condition region for stable globular transfer was widened with increasing Ti content.

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Bias Field Effect of SmCo Films on Soft Magnetic Properties of CoZrNb Films (SmCo박막의 바이어스자계가 CoZrNb박막의 연자성특성에 미치는 효과)

  • Shin, K.H.;Kim, Y.H.
    • Journal of the Korean Magnetics Society
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    • v.13 no.5
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    • pp.198-203
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    • 2003
  • To investigate whether the use of hard magnetic film is available to generate bias magnetic field for a magnetoimpedance sensor, the magnetic properties of SmCo hard magnetic films were investigated as a function of their compositions. The saturation magnetization decreased with Sm content increasing in SmCo films. And, the coercive force increased in the extent of Sm content of 28 at%, but decreased as Sm content increased moreover. The bias field effect of SmCo film to amorphous CoZrNb film was investigated with the magnetization corves, permeabilities, and magnetic domain structures of SmCo/CoZrNb multilayers. The bias field of about 60 Oe was observed in the film with 3 mm ${\times}$ 0.5 mm, which can be constructed as a MI sensor, and this result strongly indicates that the bias field generated from a hard magnetic film is adequate to enhance the sensitivity of a MI sensor with hard/soft magnetic multilayer structure.

Effects of elevated CO2 on growth of Pinus densiflora seedling and enzyme activities in soil

  • Kim, Sung-Hyun;Jung, Soo-Hyun;Kang, Ho-Jung;Lee, In-Sook
    • Journal of Ecology and Environment
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    • v.33 no.2
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    • pp.133-139
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    • 2010
  • Atmospheric $CO_2$ concentrations have increased exponentially over the last century and, if continued, are expected to have significant effects on plants and soil. In this study, we investigated the effects of elevated $CO_2$ on the growth of Pinus densiflora seedling and microbial activity in soil. Three-year-old pine seedlings were exposed to ambient as well as elevated levels of $CO_2$ (380 and 760 ppmv, respectively). Growth rates and C:N ratios of the pine seedlings were also determined. Dissolved organic carbon content, phenolic compound content, and microbial activity were measured in bulk soil and rhizosphere soil. The results show that elevated $CO_2$ significantly increased the root dry weight of pine seedling. In addition, overall N content decreased, which increased the C:N ratio in pine needles. Elevated $CO_2$ decreased soil moisture, nitrate concentration, and the concentration of soil phenolic compounds. In contrast, soil enzymatic activities were increased in rhizosphere soil, including ${\beta}$-glucosidase, N-acetylglucosaminidase and phosphatase enzyme activities. In conclusion, elevated $CO_2$ concentrations caused distinct changes in soil chemistry and microbiology.

Thermal Stability of Trifunctional Epoxy Resins Modified with Nanosized Calcium Carbonate

  • Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.334-338
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    • 2009
  • Trifunctional epoxy resin triglycidyl paraaminophenol (TGPAP)/$CaCO_3$ nanocomposites were prepared using the melt blending method. The effects of nano-$CaCO_3$ content on the thermal behaviors, such as cure behavior, glass transition temperature ($T_g$), thermal stability, and the coefficient of thermal extension (CTE), were investigated by several techniques. Differential scanning calorimetry (DSC) results indicated that the cure reaction of the TGPAP epoxy resin was accelerated with the addition of nano-$CaCO_3$. When the nano-$CaCO_3$ content was increased, the $T_g$ of the TGPAP/$CaCO_3$ nanocomposites did not obviously change, whereas the crosslinking density was linearly increased. The nanocomposites showed a higher thermal stability than that of the neat epoxy resin. This result could be attributed to the increased surface contact area between the nano-$CaCO_3$ particles and the epoxy matrix, as well as the high crosslinking density in the TGPAP/$CaCO_3$ nanocomposites. The CTE of the nanocomposites in the rubbery region was significantly decreased as the nano-$CaCO_3$ content was increased.

Syntheses and Swelling Behaviors of Poly(n-isopropylacrylamide-co-acrylonitrile) Hydrogels (Poly(N-isopropylacrylamide-co-acrylonitrile) 수화젤의 합성과 팽윤거동)

  • Piao, Zhe Fan;Ham, Myong-Jo;Kim, Young-Ho
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.349-355
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    • 2007
  • Poly(N-isopropylacrylamide-co-acrylonitrile) [P(NIPAAm-co-AN)] copolymers with AN content of up to 10 mol% and their hydrogels were synthesized using water as a reaction medium, and the effects of AN unit incorporation on the critical gel transition temperature(CGTT) and swelling behaviors of the hydrogels were investigated. The CGTT of the copolymer hydrogel was $30{\sim}32\;^{\circ}C$, decreasing with increasing AN content. Below CGTT, swelling rate and equilibrium swelling ratio of the copolymer hydrogel decreased with increasing AN content. On the other hand, it exhibited faster deswelling and lower equilibrium deswelling ratio with increasing AN content above CGTT.

Effect of Perilla Oil on the Fatty Acid Composition, ACAT and HMG-CoA Reductase in Microsomes, or Cholesterol and Protein in Serum of Rabbits (들깨기름이 토끼의 혈청단백질, Cholesterol 과 간장속의 ACAT, HMG-CoA reductase 및 지방산 조성에 미치는 영향)

  • Nam, Hyun-Keun
    • Journal of the Korean Society of Food Culture
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    • v.4 no.2
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    • pp.185-189
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    • 1989
  • Effect of perilla oil on the fatty acid composition, ACAT and HMG-CoA reductase in the liver microsomes, or cholesterol and protein in serum of rabbit were examined. 1. The content of total protein in serum was almost same amount of both groups, but ${\alpha_1}-globulin$ and r-globuline were incresed or ${\beta}-globulin$ was decresed compared with control. 2. The content of high density lipoprotein incresed, and the content of low density lipoprotein decresed in lipoprotein. 3. Total cholesterol and triglyceride were decresed, and the content of phospholipid was incresed. 4. Perilla oil did not effect for changing blood glucose and $Na^+,\;K^+$ electrolytes. 5. Perilla oil did not effect for changing serum GOT and GPT in rabbit. 6. The activity of ACAT decresed and the activity of HMG-CoA reductase incresed. The activity of ACAT and HMG-CoA reductase in liver microsomes were reciprocal. 7. There were arachidonic acid 20:4, eicosapentaenoic acid 20:5, and docosahexaenoic acid 22:6 in the liver microsomes of rabbits. These highly polyunsaturated fatty acids were convented from linolenic acid 18:3 n-3.

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The Effect of Water Content on Hen Egg lysozyme Extraction using Reversed Micelles and Pressurized Carbon Dioxide (가압 이산화탄소와 역미셀을 이용한 난백 lysozyme의 추출에 대한 수분함량의 영향)

  • 박선영;전병수
    • KSBB Journal
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    • v.18 no.3
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    • pp.202-206
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    • 2003
  • A study of hen egg lysozyme extraction using reversed micelles and pressurized CO₂ phase was conducted. The relationship between the lysozyme extraction and water content (W/sub 0/) under the pressurized CO₂ conditions was investigated. The water content of the micellar organic phase was a significant parameter affecting the mass transfer of protein and enzymatic activity in reversed micellar process. It was found that the reversed micelles in the organic phase with pressurized CO₂ were larger than the organic phase without CO₂. Therefore, the extractionrate of lysozyme in the interface of the aqueous phase and the organic phase was increased. W/sub 0/ value was increased at the high surfactant concentration and the extraction rate of lysozyme was enhanced.

Influence of Carbon Content on the Mechanical Properties of the Ni-Co Alloy (Ni-Co 합금강의 기계적 특성에 대한 탄소함량의 영향)

  • Choi, Byung-Ky;Jang, Kyeung-Cheun;Choi, Byung-Hui;Lee, Kee-Ahn
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.5
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    • pp.7-13
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    • 2006
  • This study was to evaluate the effect of carbon content on metallic change and fatigue characteristics with Fe-29%Ni-17%Co, low heat expansion alloy, widely using electronic components, precision machines, and sealing with glass and metal etc. The steels were fabricated with variation of carbon content, 0, 0.03, 0.06, 0.1, and 0.20% with VIM and tensile test and fatigue test were performed to achieve the above purpose. The more carbon content, the higher hardness value and yield strength. But elongation of 0.03%C, 0.06%C, and 0.10%C specimen decreased about 2.2%, 1.5% and 0.8% respectively more than that of the base metal. Especially the strength and elongation of 0.20%C specimen increased simultaneously about 14.4% and 7.5%. Fatigue life of 0.03%C specimen decreased but the more carbon content, the higher fatigue life over 0.06% carbon content more than that of base metal.

Effect Boron and Silicon on Various Properties of Dental Cobalt-Chromium Alloys (치과용 Co-Cr 합금의 제성질에 미치는 Boron과 Silicon의 영향)

  • Jung, Jong-Hyun
    • Journal of Technologic Dentistry
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    • v.14 no.1
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    • pp.119-132
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    • 1992
  • This paper aims to investigate the effect of B and Si upon the mechanical properties, microstructure and corrosion resistance of Co-Cr base alloy. Ten groups of alloy ingot ingot with various contents of B and Si were remelted by high frequency electrical induction furnace and cast into tensile specimen of ADA Specification No. 14 Tensile and hardness test were carried out by Amsler and Rockwell hardness tester(R-30N), respectively. The microstructures of specimen were observed by SEM. The results obtained are summarized as follows : 1. As B content is increased, tensile strength, yield strength and Rockwell hardness number(R-30N) are also increased significantly, while the elongation is decreased significantly. 2. As Si contect os increased, no significant chang in tensile strength is noticed, yield strength is slightly decreased, but Rockwell hardness number(R-30N) is moderately in creased, Elongation marks maxium value with 1% Si content while with more than 1% Si it is decreased. 3. As B content is increased corrosion resistance is decreased and is at best with 1.5% B content. Corrosion resistance is increased with the increase of Si content and the alloys with Si over 3.0% showed corrosion resistance. 4. As B content increased, precipitates are increased in number at grain boundaries. The grain size tends to become coarse with the increase of Si content. 5. Co rich-Cr alloy is present through matrix whereas at the grain boundaries Cr base precipitates are primarily formed.

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