• Title/Summary/Keyword: Co and Na addition

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Characteristics of Hydrogen Production by Catalytic Pyrolysis of Plastics and Biomass (플라스틱 및 바이오매스의 촉매 열분해에 의한 수소 생성 특성)

  • Choi, Sun-Yong;Lee, Moon-Won;Hwang, Hoon;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.19 no.4
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    • pp.221-227
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    • 2010
  • In this study, we consider gas generation characteristics on pyrolysis of eco-fuel which were made by mixing of Pitch Pine and Lauan sawdust as biomass and polyethylene, polypropylene, polystyrene as municipal plastic wastes with catalyst in fixed bed reactor. From the result of higher heating value(HHV) measurement and of ultimate analysis, the heating value of plastic wastes and a hydrogen content in plastic sample are higher than biomass. An activation energy was reduced by a catalyst addition. However the catalyst content influence over 5 wt% was insignificant. The yield of hydrogen from gasification of biomass containing plastic wastes such as polyethylene, polypropylene and polystyrene were obtained higher than that of sole biomass. The high temperature and mixture ratio of catalyst conditions induced to high hydrogen yield in most of the samples. As the influence of catalyst, the hydrogen yield by catalytic reaction was higher than non-catalytic reaction. We confirmed that Ni-$ZrO_2$ catalyst is more active in increasing the hydrogen yield in comparison with that of carbonate catalyst. The maximum hydrogen yield was 65.9 vol.%(Pitch Pine / polypropylene / 20 wt.% Ni-$ZrO_2$(1:9) at $900^{\circ}C$).

Characteristics of Strong Alkaline Electrolyzed Water Produced in All-in-one Electrolytic Cell (일체형 전해조에서 생산된 강알카리성 전해수의 특성)

  • Lee, Ho Il;Rhee, Young Woo;Kang, Kyung Seok
    • Clean Technology
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    • v.18 no.4
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    • pp.446-450
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    • 2012
  • Strong alkaline electrolyzed water which is produced in cathode by electrolyzing the solution where electrolytes (NaCl, $K_2CO_3$ etc.) are added in diaphragm electrolytic cell, is eco-friendly and has cleaning effects. So, it is viewed as a substitution of chemical cleaner. In addition, strong alkaline electrolyzed water is being used by some Japanese automobile and precision parts manufacturing industries. When strong alkaline electrolyzed water is produced by using diaphragm electrolytic cell, it is necessarily produced at the anode side. Since strong acidic electrolyzed water produced is discarded when its utilization cannot be found, production efficiency of electrolyzed water is consequently decreased. Also, there is a weakness electrolytic efficiency is decreasing due to the pollution of diaphragm. In order to overcome this, non-diaphragm all-in-one electrolytic cell integrated with electrode reaction chamber and dilution chamber was applied. Strong alkaline electrolyzed water was produced for different composition of electrolytes, and their properties and characteristics were identified. In comparing the properties between strong alkaline electrolyzed water produced in diaphragm electrolytic cell and that produced in all-in-one electrolytic cell, the differences in ORP and chlorine concentration were found. In emulsification test to confirm surface-active capability, similar results were obtained and strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell was identified to be useable as a cleaner like strong alkaline electrolyzed water produced in diaphragm electrolytic cell. Strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell is thought to have sterilizing power because it has active chlorine which is different from strong alkaline electrolyzed water produced in diaphragm electrolytic cell.

Application of Ceramic MF Membrane at the Slow Sand Filtration Process (완속모래여과 공정에서 세라믹 MF 막의 적용)

  • Choi, Kwang-Hun;Park, Jong-Yul;Kim, Su-Han;Kim, Jeong-Sook;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.12
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    • pp.877-882
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    • 2013
  • The application of ultrafiltration (UF) and microfiltration (MF) membranes has been increased for drinking water purification. The advantages of UF/MF membrane process compared to conventional treatment processes are stable operation under varying feed water quality, smaller construction area, and automatic operation. Most membrane treatment plants are designed with polymeric membranes. Recently, some studies suggested that the process of treating surface water with ceramic membranes is competitive to the application of polymeric membranes. Higher water flux, less frequent cleaning, and much longer lifetime are the advantages of ceramic membrane comparing to polymeric membrane. Therefore, this research focused on the application of ceramic MF membrane pilot plant at the slow sand filtration plant. The ceramic membrane pilot plant has three trains that used raw water and sand filtered water as a feed water, respectively. For optimizing the pilot plant process, the coagulation with PACl coagulant was used as a pretreatment of ceramic membrane process. In addition, CEB (Chemical Enhanced Backwash) process using $H_2SO_4$ and NaOCl was used for 1.5 days, respectively. The experimental results showed that applying the optimum coagulant dose before membrane filtration showed enhancing membrane fluxes for both raw water and sand filtered water. Also, when using raw water as a feed of membrane, minimum fouling rate was 2.173 kPa/cycle with 25 mg/L of PACl and when using sand filtered water, the minimum fouling rate was 0.301 kPa/cycle with 5 mg/L of PACl.

Isolation of Cysteine Proteinase Gene (PgCysP1) from Panax ginseng and Response of This Gene to Abiotic Stresses (인삼으로부터 Cysteine Proteinase 유전자의 분리 및 환경 스트레스에 대한 반응)

  • Jeong, Dae-Young;Kim, Yu-Jin;Shim, Ju-Sun;Lee, Jung-Hye;In, Jun-Gyo;Lee, Bum-Soo;Yang, Deok-Chun
    • Journal of Ginseng Research
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    • v.32 no.4
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    • pp.300-304
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    • 2008
  • Cysteine proteinases play an essential role in plant growth and development but also in senescence and programmed cell death. They participate in both anabolic and catabolic processes. In addition, they are involved in signalling pathways and in the response to biotic and abiotic stresses. A cDNA clone encoding cysteine proteinase (CP) gene, designated PgCysP1, was isolated from Panax ginseng C. A. Meyer. Reverse transcriptase (RT)-PCR results showed that PgCysP1 expressed at different level in P. ginseng hairy root. Different stresses such as biotic as well as abiotic stresses triggered a significant induction of PgCysP1. The positive responses of PgCysP1 to the various stimuli suggested that PgCysP1 may help to protect the plant against reactive environmental stresses.

Characteristics of Groundwater Contamination Caused by Seawater Intrusion and Agricultural Activity in Sacheon and Hadong Areas, Republic of Korea (해수침투와 농업활동에 의한 사천-하동 해안지역 지하수의 오염 특성)

  • Kim, Hyun-Ji;Hamm, Se-Yeong;Kim, Nam-Hoon;Cheong, Jae-Yeol;Lee, Jeong-Hwan;Jang, Sung
    • Economic and Environmental Geology
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    • v.42 no.6
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    • pp.575-589
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    • 2009
  • Groundwater has been extracted for irrigation in Sacheon-Hadong area, which is close to the South Sea. We analyzed chemical components of groundwater to examine the effects of seawater intrusion and agricultural activities in the study area. Most groundwater samples displayed the Na/Cl concentration ratios similar to that of seawater (0.55) with an increasing tendency of electrical conductivity ($227-7,910\;{\mu}S/cm$) towards the coast. In addition, statistical interpretation of the cumulative frequency curves of Cl and $HCO_3$ showed that 30.1% of the groundwater samples were highly affected by seawater intrusion. Groundwaters in the study area mostly belonged to the Ca-Cl and Na-Cl type, demonstrating that they were highly influenced by seawater intrusion and cation exchange. The result of oxygen-hydrogen isotope analysis demonstrated slightly higher $\delta^{18}O$ ((-8.53)-(-6.13)‰) and ${\delta}D$ ((-58.7)-(-43.7)‰) comparing to mean oxygen-hydrogen isotope ratios in Korea. As a result of nitrogen isotope analysis, the $\delta^{15}N-NO_3$ values ((-0.5)-(19.1)‰) indicate two major sources of nitrate pollution (organic nitrogen in soil and animal and human wastes) and mixed source of the two. However, denitrification may partly contribute as a source of nitrogen. According to factor analysis, four factors were identified among which factor 1 with an eigenvalue of 6.21 reflected the influence of seawater intrusion. Cluster analysis indicated the classification of groundwater into fresh, saline, and mixed ones.

Effect of Solvents on Phase Behavior and Flux Removal Efficiency in Alkyl Ethoxylates Nonionic Surfactant Based Cleaners (Alkyl Ethoxylates계 비이온 계면활성제를 주체로 한 세정제에서 용제에 따른 상거동과 플럭스 제거 효능)

  • Lee, Jong-Gi;Bae, Sang-Soo;Cho, In-Sik;Park, So-Jin;Park, Byeong-Deog;Park, Sang-Kwon;Lim, Jong-Choo
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.677-683
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    • 2005
  • In this work, the effect of additives such as solvent, sodium dodecyl sulfate and NaCl on microemulsion phase behavior and flux removal efficiency in systems containing commercial alkyl ethoxylates nonionic surfactant was investigated. The addition of a n-hydrocarbon as a solvent produced on O/W (Oil/Water) microemulsion phase over a wider range of temperature and cosurfactant to surfactant ratios. Especially, the addition of n-hexadecane to the surfactant system, which was the most hydrophobic solvent among the solvents used in this study, produced a microemulsion phase over a wide range of temperatures and promoted formation of a microemulsion phase at lower temperatures. The candidate for cleaner samples, prepared from phase behavior experiments, showed excellent removal efficiency for abietic acid at $40^{\circ}C$. These data suggested the potential applicability of hydrocarbons to actual cleaner formulations.

The Effect of Phosphorus Supplementation to $40\%$ Soybean Meal Substituted Diet for Common Carp ($40\%$ 대두박분 대체 잉어 사료에 대한 인의 첨가효과)

  • KIM In-Bae;On Jae-Kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.18 no.5
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    • pp.491-495
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    • 1985
  • A series of growth experiment on the effect of phosphate addition to a common carp feed contatining a large amount of soybean meal were conducted at the Fish Culture Experiment Station of the National Fisheries University of Pusan from November 2, 1984 to February 3, 1985. Carp feed containing $40\%$ soybean meal performs very poorly but when supplemented with $2\%$ dibasic sodium phosphate the feed gave a very good performance almost similar to one of the best carp feed commercially available. In this 94 day experiment, phosphate added feed resulted in 1.431 in food coefficient, and 1.619 in daily growth rate for common carp of 73.3g in initial weight, and 1.558 and $1.589\%$ for those of 26.7g, respectively, compared to the performance of the feed without phosphate addition, which resulted in 1.863 in food coefficient and $1.365\%$ in daily growth rate for the large ones, and 1.820 and $1.438\%$ for the small ones, respectively, thus indicating that carp feeds containing a large amount of soybean meal could effectively be used if a proper amount of phosphorus is supplemented.

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Gel and Texture Properties of Fish-meat Gel Prepared with Pagrus major in Comparison to Different Grades of Alaska Pollock (도미를 활용하여 제조한 연제품의 겔 및 texture 특성)

  • Gao, Ya;Oh, Jung Hwan;Karadeniz, Fatih;Lee, Seul-Gi;Kim, Hyung Kwang;Kim, Se Jong;Jung, Jun Mo;Cheon, Ji Hyeon;Kong, Chang-Suk
    • Journal of Life Science
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    • v.26 no.8
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    • pp.955-962
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    • 2016
  • Fish-meat gel is an intermediate product used in a variety of surimi-based seafood. One of the most-used raw materials of fish-meat gel is Alaska Pollock due to its high-quality meat in terms of gel strength and texture. However, increasing demand for fish-meat gel, along with overexploitation of the wild catch Alaska Pollock, has put the industry in need of low-cost sustainable alternative sources for fish-meat gel. Pagrus major (PM) is a widely aquacultured fish known for having white meat that is low in fat. The current study compares the quality of fish-meat gel prepared from aquacultured PM to that of high and mid-grade Alaska Pollock fish-meat gel. Gels were compared in terms of gel strength, texture, color, and protein pattern. Results indicated that fish-meat gels prepared from PM were superior to Alaska Pollock fish-meat gels with regard to gel strength, hardness, springiness, chewiness, cutting strength, and breaking force. In addition, although not matching in quality, PM exhibited a cohesiveness, whiteness, and expressible moisture content comparable to Alaska Pollock of both grades. Protein pattern analysis also showed that PM and Alaska Pollock fish-meat gels had similar protein profiles before and after gel preparation. Therefore, P. major is suggested as a potential substitute for Alaska Pollock in fish-meat gel production.

Purification of Vibrio anguillarum Growth Inhibition Factor Produced by Bacillus amyloliquefaciens H41. (Bacillus amyloliquefaciens H41이 생산하는 Vibrio anguillarum 생육 저해인자의 정제)

  • Shin, Hyun-Chul;Chung, Kyung-Tae;Kim, Kwang-Hyun;Kim, Byung-Woo;Kwon, Hyun-Ju;Lee, Eun-Woo;Yum, Jong-Hwa;Rhu, Eun-Ju;Jeong, Yu-Jeong;Kim, Young-Hee
    • Journal of Life Science
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    • v.18 no.6
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    • pp.789-795
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    • 2008
  • To study the possible use of probiotics in fish farming, we evaluated antagonism of antibacterial strain Bacillus amyloliquefaciens H41 against the fish pathogenic bacterium Vibrio anguillarum NCMB1. The purification of growth inhibition factor produced by B. amyloliquefaciens H41 was achieved by obtaining supernatant of this bacterium. The growth inhibition factor was purified to homogeneity by 70% ammonium sulfate precipitation, DEAE-sephadex A-50 ion exchange chromatography, sephadex G-200 gel filtration column chromatography, and sephadex G-50 gel filtration column chromatography with 40.8 fold of purification and 2.9% yield. The molecular weight of the purified growth inhibition factor was 48 kDa as determined by sodium dodecyl sulfate polyacrylamide gel electrophoresis. The optimum pH and temperature for the growth inhibition factor were pH 7.5 and $30^{\circ}C$, respectively. The activity of growth inhibition factor was enhanced slightly by some metal ions, such as $Mg^{+2}$, $Mn^{+2}$, but was inhibited by the addition of $Co^{+2}$, $Hg^{+2}$, $Zn^{+2}$ and $Ag^{+2}$. NaCl stability of the growth inhibition factor was observed with 50% residual activity at 3% NaCl concentration. Toxicity test showed that the purified B. amyloliquefaciens H41 growth inhibition factor did not affect the live of Japanese flounder (Paralichthys olivaceus) and the effectiveness was 78% of residual lethality compared to commercial antibacterial agents.

Effect of Supplementation of Fermented Milk Containing Active Peptides(IPP, VPP) in Accordance with Medical Nutrition Therapy in Pre- and Hypertension Subjects (고혈압 전단계 및 고혈압 환자에서 의학영양치료와 병행한 생리활성 펩티드 함유 유산균 발효유 섭취가 혈압에 미치는 영향)

  • Kim, Ji-Young;Kim, Yun-Young;Kim, Hye-Rang;Yun, Sung-Seob;Kim, Wan-Sik;Yea, Hyun-Soo;Chung, Jin-Young;Lee, In-Hoe;Choue, Ryo-Won
    • Journal of the East Asian Society of Dietary Life
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    • v.18 no.6
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    • pp.918-926
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    • 2008
  • It is well known non-drug therapy for hypertension patients can reduce blood pressure. These types of therapy include maintaining ones ideal body weight, quitting smoking, consuming large amounts of fruits and vegetables consuming low levels of saturated fat and salt and regular exercise. Fermented milk protein derived biologically active peptides such as isoleucine-proline-proline_(IPP) or valine-proline-proline_(VPP) have been shown to lower blood pressure in hypertensive subjects. This study was conducted to investigate the antihypertensive effects of medical nutritional therapy _(MNT) in accordance with the consumption of fermented milk enriched with IPP and VPP. To accomplish this, we conducted a randomized case-controlled study of 43 subjects who had blood pressure levels greater than 120/80 mmHg. The subjects in the study group were randomly allocated into two groups, an MNT + fermented milk (100mL/day) group (n=21) and an MNT+L. helveticus fermented milk with tripeptides (IPP=2.2mg, VPP=2.6mg/100mL) group (n=22). The MNT included weight management, reduction of sodium, total fat and saturated fat intake, increased intake of fruits and vegetables, and increased intake of low fat dairy products. The treatments were administered for 12 weeks during which time no drug interventions were conducted. The daily intakes of total calories, fats, cholesterol and Na decreased significantly after 12 weeks of MNT in the control and the experimental groups. In addition, the systolic blood pressure de creased significantly in the control and experimental groups; however, the diastolic blood pressure only decreased significantly in the experimental group. Overall, the results of this study indicate that the intake of fermented milk containing IPP and VPP in conjunction with MNT exerted positive effects on the blood pressure of pre- and hypertensive subjects.

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