• 제목/요약/키워드: Closing Department

검색결과 453건 처리시간 0.021초

메조세공 BEA에 고정화된 키랄 Co살렌 착체의 동적분할을 통한 고광학순도의 키랄 모노에스테르 합성 (Synthesis of Optically Active Monoesters via Kinetic Resolution by Chiral Co (Salen) Complex Immobilized on Mesoporous BEA)

  • 최성대;박근우;이경찬;김건중
    • 공업화학
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    • 제26권2호
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    • pp.132-137
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    • 2015
  • BEA형 제올라이트를 알칼리용액으로 처리하여 결정구조 내에 메조세공이 형성되도록 제조하고, 세공 내에 균일계 키랄 Co(III) 살렌을 고정화시켰다. 메조세공 BEA-제올라이트에 고정화된 이핵형 Co-$GaCl_3$ 살렌 촉매는 말단 에폭사이드의 산소고리를 카르복실산으로 여는 키랄 반응에 대하여 높은 활성을 나타내었다. 이 반응을 통하여 라세믹 에폭사이드로부터 다양한 모노 에스테르 유도체를 중간 정도의 광학선택도(47~69 ee%)로 합성할 수 있었다. 키랄(S)-ECH를 반응물로 사용하면, 이들은 키랄 살렌 촉매 존재하에서 카르복시 산에 의하여 에폭사이드의 링이 광학선택적으로 열리며, 생성된 화합물을 염기용액에서 탈염산 처리하면 다시 에폭사이드 링이 형성되면서 광학순도가 매우 높은 모노에스터 에폭사이드 (R)-GB (98 ee% 이상)가 얻어졌다. 고정화촉매는 매우 용이하게 제조될 수 있었으며, 특별한 재생처리 없이 여러번 재사용하여도 촉매의 활성이 유지되었다.

순수 에탄올을 이용한 재발된 좌골부위 압박궤양의 경화요법적 치료 (Treatment of Recurrent Ischial Pressure Sore Using Sclerotherapy with Absolute Ethanol)

  • 송훈;박상근;김종환;홍인표
    • Archives of Plastic Surgery
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    • 제33권5호
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    • pp.627-631
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    • 2006
  • Purpose: Ischial region is common site of pressure sore as well as greater trochanteric area. In general, ischial pressure sore associated with a large subcutaneous bursa often requires radical surgical treatment. The authors performed sclerotherapy using absolute ethanol which was considered as an alternative in treating recurrent ischial pressure sore. Methods: From may 2005 to February 2006, 11 ischial pressure sore patients were treated sclerotherapy using absolute ethanol. The authors performed sclerotherapy using absolute ethanol in 11 patients in whom the ischial sore has recurred despite of multiple radical surgical treatment. The patients' original disorders were spinal cord injury in 9 patients, cerebral palsy in 1 patient and giant cell tumor in thoracic vertebrae 1 patient. Results: Recurrence of pressure sore was not found in any patient during the follow-up period. The swap of the bursa taken before the surgery was germ cultured and compared with the discharge from an end of the inserted drain tube. The germ cultured results after the surgery were tested negative in all patients. Conclusion: This method involves causing the bursa to become scarred and closing it up by sterilizing, fixing, and denaturing by the pharmacologic effect of absolute ethanol instead of surgical excision of the bursa. We felt that aforementioned treatment modality may be considered as an alternative in treating recurrent ischial pressure sore.

내반 요족 변형에서 시행한 제1중족골 및 종골에 대한 절골술 (Combined First Metatarsal and Calcaneal Osteotomy for Fixed Cavovarus Deformity of The Foot)

  • 주인탁;박종민;유종민;정진화
    • 대한족부족관절학회지
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    • 제14권2호
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    • pp.130-134
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    • 2010
  • Purpose: The aim of this study was to evaluate the result of combined first metatarsal and calcaneal osteotomy for static cavovarus deformity of the foot. Materials and Methods: We performed a dorsal closing wedge $1^{st}$ metatarsal osteotomy and a lateral and upward displacement calcaneal osteotomy for 9 patients, 12 feet (6 male and 3 female). The mean age at the time of operation was 37 years and the mean followup period was 27 months. The causes of deformity were 2 poliomyelitis, 1 cerebral palsy, 1 Charcot-Marie-Tooth disease and 5 idiopathic type. Five lateral ligament reconstructions of the ankle and six percutaneous Achilles tendon lengthenings were added. The surgical results in terms of pain, function and alignment of the foot were evaluated by means of AOFAS ankle-hindfoot score and talo-$1^{st}$ metatarsal, calcaneus-$1^{st}$ metatarsal and calcaneal pitch angles were checked with weight bearing radiographs in lateral projection. Results: Talo-$1^{st}$ metatarsal and calcaneal pitch angles were reduced from the mean preoperative values of $21^{\circ}$ and $25^{\circ}$ to $12^{\circ}$ and $19^{\circ}$, respectively, at last followup. Also, calcaneus-$1^{st}$ metatarsal angle was increased from the mean $114^{\circ}$ to $114^{\circ}$. The mean AOFAS score was improved from 44.5 points preoperatively to 89.2 points at followup. There were 1 metatarso-cueiform joint nonunion, 1 sural nerve injury and 3 remaining symptomatic claw toes. Conclusion: Combined first metatarsal and calcaneal osteotomy appears to be an effective procedure for the treatment of adult static cavovarus foot.

수직 밀폐형 심부지열 순환 시뮬레이터의 성능 평가에 관한 연구 (A Study on Performance Evaluation of a Vertically Closed Deep Geothermal Circulation Simulator)

  • 배정형;이동운;윤충만;류연수;정상화
    • 한국기계가공학회지
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    • 제15권5호
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    • pp.8-17
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    • 2016
  • While greenhouses have been utilized as a sustainable alternative to traditional soil farming, they are often powered by diesel boilers that necessitate vast amounts of non-renewable energy and emit toxic fumes. Thus, geothermal heat pumps have been proposed as a more energy-efficient substitution for diesel boilers. Currently, most horticultural facilities in the United States use shallow geothermal systems, and are often equipped with horizontal underground heat exchangers as well as heat pump equipment. These shallow geothermal systems require a large drilling site and heat pump to function, which results in high maintenance costs. The heat pump itself consumes a large amount of power, which degrades system performance. Conversely, high temperatures can be attained within a single borehole in deep geothermal vertical closing systems without using a heat pump. This setup can dramatically reduce the power consumption and improve system performance. In this study, we have modeled a circulation simulator after the circulation systems in deep geothermal facilities to analyze a 2000-meter borehole in Naju-Sanpo-myeon. The simulator is operated by manipulating various putative parameters affecting system performance to analyze the system's coefficient of performance.

정상 성인의 비음도와 비인강 활성도에 관한 연구 (A Study of Normal Nasalance and Velopharyngeal Port Activity in the Speech of Korean Adults)

  • 임대호;신효근;백진아;김현기;권민수
    • 대한구순구개열학회지
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    • 제7권2호
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    • pp.123-132
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    • 2004
  • The purpose of this study was to obtain normative nasalance scores for adult subjects speaking the Korean language. Additional objectives of the study were to determine if speaker sex played a role in differences in nasalance score and there was significantly correlation of nasalance score with nasalance slope score. The subjects include 75 healthy young Korean adults with normal oral and velopharyngeal resource and function. They had no history of speech problem, were judged as having normal speech and resonance at the time of testing, and had no upper respiratory tract infections or allergies at the time of testing. The Nasometer II 6400 was used to obtain nasalance scores and nasalance slope scores for /a/, /i/, /e/, /o/, /u/, /ja/, /je/, /wi/, /p'ap'i/ and /sasi/. The data of nasalance and nasalance slope were analyzed statistically. The mean nasalance score of the female was significantly higher than that of male at /a/, /i/, /wi/, /p'ap'i/ and /sasi/(p <0.10). The mean nasalance score of /i/ was highest and that of /o/ was the lowest. In this study, we could not and the relationship of the nasalance score and the closing slope score. However, there was negative correlation between the mean nasalance score and the opening slope score at ie/ and /;ai, positive to /sasi/. These normative nasalance scores for normal young adults speaking the Korean language provide important reference information for Korean cleft palate teams. In the future study of velopharygneal activity with the Nasometer, the opening slope score will be able to be the important parameter.

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Structural monitoring of movable bridge mechanical components for maintenance decision-making

  • Gul, Mustafa;Dumlupinar, Taha;Hattori, Hiroshi;Catbas, Necati
    • Structural Monitoring and Maintenance
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    • 제1권3호
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    • pp.249-271
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    • 2014
  • This paper presents a unique study of Structural Health Monitoring (SHM) for the maintenance decision making about a real life movable bridge. The mechanical components of movable bridges are maintained on a scheduled basis. However, it is desired to have a condition-based maintenance by taking advantage of SHM. The main objective is to track the operation of a gearbox and a rack-pinion/open gear assembly, which are critical parts of bascule type movable bridges. Maintenance needs that may lead to major damage to these components needs to be identified and diagnosed timely since an early detection of faults may help avoid unexpected bridge closures or costly repairs. The fault prediction of the gearbox and rack-pinion/open gear is carried out using two types of Artificial Neural Networks (ANNs): 1) Multi-Layer Perceptron Neural Networks (MLP-NNs) and 2) Fuzzy Neural Networks (FNNs). Monitoring data is collected during regular opening and closing of the bridge as well as during artificially induced reversible damage conditions. Several statistical parameters are extracted from the time-domain vibration signals as characteristic features to be fed to the ANNs for constructing the MLP-NNs and FNNs independently. The required training and testing sets are obtained by processing the acceleration data for both damaged and undamaged condition of the aforementioned mechanical components. The performances of the developed ANNs are first evaluated using unseen test sets. Second, the selected networks are used for long-term condition evaluation of the rack-pinion/open gear of the movable bridge. It is shown that the vibration monitoring data with selected statistical parameters and particular network architectures give successful results to predict the undamaged and damaged condition of the bridge. It is also observed that the MLP-NNs performed better than the FNNs in the presented case. The successful results indicate that ANNs are promising tools for maintenance monitoring of movable bridge components and it is also shown that the ANN results can be employed in simple approach for day-to-day operation and maintenance of movable bridges.

Manual Muscle Test 중 상지거상저항 검사 시 근력 오류 발생 원인에 대한 고찰 (Study about the Causes of Muscle Force Mistake Occurrence from the Upper Limb Lifting Resistance Test in Manual Muscle Test)

  • 안성훈;양승범;이영준;황성연;김재효;손인철
    • 턱관절균형의학회지
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    • 제1권1호
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    • pp.13-18
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    • 2011
  • Objectives: We investigated muscle force from the upper limb lifting resistance test to conform the objectivity in manual muscle test. Methods: We made standard method in upper limb lifting resistance test to compare with experiment method switching the lower limb position left & right. And resistance forces of upper limb of subject were checked to inspector with closing eyes. Results: 1. The lifting resistance of right upper limb was stronger when the lower limb of right and left were abducted. 2. The lifting resistance of right upper limb was weaken when the lower limb of right and left were adducted. 3. The lifting resistance of right upper limb was weaken when the lower limb of right and left were elevated. Conclusions: As the above results, the deltoid muscle force checked in the upper limb lifting resistance test is affected by the location of lower limbs, it suggested that the muscle force of some part in the body will be affected by the other parts. It will be useful to understand the symmetry principle of body in muscle function.

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하악 전치의 선천적 결손을 동반한 부정 교합의 치험례 (Malocclusion with Congenital Missing of Lower Incisors)

  • 김경호;최광철;정길용;윤희선
    • 대한치과교정학회지
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    • 제28권6호
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    • pp.981-989
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    • 1998
  • 하악 전치의 위치와 각도, 형태와 근원심 폭경 등은 심미성, 전치부의 적절한 교합, 그리고 치료 후 안정성 측면에서 중요한 의미를 갖는다. 하악 전치가 선천적으로 결손된 경우 수평피개 및 수직피개의 증가, 인접치의 이동, 공극 및 치아 크기 부조화 등 교정적으로 복잡한 문제를 야기할 수 있으므로 하악 전치 결손시 이에 대한 충분한 고려가 필요하다. 하악 전치 결손의 치료계획 수립시 전치의 위치와 각도, 입술 모양, crowding양, 견치와 대구치 관계, 수평 및 수직피개, 전후방적 골격 관계 및 치아크기 비율 등이 고려되어야 하며, 전치부 치아 크기 부조화에 대한 정확한 평가를 위해 diagnostic model set-up을 시행하는 것이 많은 도움이 된다. 본 증례의 두 환자는 모두 하악 전치 2개가 결손되었지만 crowding양, 골격 관계 및 입술 모양, 구치 관계 등이 달랐으며 이에 따른 치료 계획 역시 발치 및 비발치로 상이하였다. 앞으로 두 환자의 치료후 안정 및 유지에 대한 장기간의 관찰이 필요하리라 사료된다.

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사질토지반에서 터널굴착시 막장안정을 위한 폐합비에 관한 연구 (A Study on the Closure Ratio for Tunnel Face Stabilization during Tunnel Excavation in Sand Soil)

  • 김상환;김지태;임채호;이인근
    • 한국지반공학회논문집
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    • 제28권4호
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    • pp.79-89
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    • 2012
  • 본 논문은 터널 굴착시 막장면 안정성 확보를 위한 막장폐합비에 따른 막장면 응력 및 지반거동을 분석하기 위해 실내모형실험 및 수치해석적 분석을 실시하였다. 실내모형실험에서는 터널막장면의 폐합비와 토피고에 따른 막장면 응력 및 지반의 거동을 실험하였다. 실내모형실험 결과를 검증하기 위하여 2차원 수치해석을 실시하였으며 이들 서로의 결과들을 비교 분석하였다. 그 결과 막장 폐합비가 증가할수록 터널 막장면 안정성 확보가 가능할 것으로 판단되며 막장 폐합비가 80% 이상일 경우에는 막장 안정성에 큰 문제가 없는 것으로 나타났다. 이러한 연구결과는 향후 경제적인 터널 막장폐합시스템을 개발하는데 매우 유용할 것으로 기대된다.

비생리적인 최대교두감합위의 교합재구성을 통한 수정 (Prosthetic rehabilitation for a patient with CO-MI discrepancy)

  • 추승식;허윤혁;조리라;박찬진
    • 구강회복응용과학지
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    • 제31권3호
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    • pp.273-282
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    • 2015
  • 중심위에서 벗어나 있는 최대교두감합위는 상하악 치아의 조기접촉 및 사면활주의 직접적인 원인이며, 악관절 내장증, 치아마모, 치주질환 등을 일으킬 수 있다. 그러므로 광범위한 보철수복이 필요한 환자에서 중심위와 최대교두감합위의 불일치가 존재하는 경우 반드시 이를 제거하여 생리적인 교합양식을 회복해야 한다. 본 증례의 환자는 초진 시 약 3.5 mm의 사면활주와 다수의 우식 및 중등도의 치주질환을 앓고 있었다. 보철수복을 통해 기능 및 심미성을 회복하는 동시에 중심위와 최대교두감합위를 일치시켜 사면활주를 제거하였으며, ARCUSdigma II와 경두개 방사선 사진을 이용하여 생리적인 위치로 수정된 하악위와 변화된 개폐구 경로를 관찰하였다.