• Journal of the Mineralogical Society of Korea
• /
• v.18 no.1
• /
• pp.1-9
• /
• 2005

The electrocatalytic reduction of O₂ was investigated with methyl viologen and methylene blue incorporated clay-modified electrodes. Clay suspensions were prepared with Na-montmorillonite, Ca-montmorillonite, and kaolinite. The methyl viologen-clay modified electrodes were made by coating clay suspensions adsorbing methyl viologen on a glassy carbon electrode. Cyclic voltammetry were performed in aqueous media to investigate the electrocatalytic property of the modified electrode in reducing O₂. A Na-montmorillonite modified electrode showed the greatest adsorption capacity for methyl viologen. The modified electrode made of Na-montmorillonite suspension of 0.87 g/10 mL and a 2.5 mM of methyl viologen solution showed the most effective electrocatalytic property, where the catalytic reduction potential was shifted by 242.6 mV toward the positive potential. The electrocatalytic ability was more significant in acidic (pH=3.7) and alkaline (pH=12.7) media than the neutral pH range (6.3∼8.3). The methyl viologen-Na-montmorillonite modified electrode had the good reproducibility and maintain the electrocatalytic property over 20 times reuse.

• Journal of the Korean GEO-environmental Society
• /
• v.14 no.8
• /
• pp.29-35
• /
• 2013

The objective of this research was to investigate the effect of various clay materials on the growth and change in mineral composition of soybean sprout. Further effect of sericite concentration on growth of soybean sprout was optimized. The experiments were carried by using three different viz., loess supernatant, tap water and sericite supernatant. From the obtained results it was found that a significant growth in soybean sprouts was observed while using sericite supernatant this growth was 14.71% and 50% more total growth than that of loess supernatant and tap water. In addition, using sericite supernatant the length of root of soybean sprouts was reached 17.30% and 36.50% longer than that of tap water and loess supernatant. The plausible reason for this growth using sericite supernatant may be due to the presence of various mineral($K^+$, $Ca^+$) in sericite. Further the mineral contents of sericite supernatant were 11.56% and 13.48% more than that for loess supernatant and tap water. Among the various sericite concentration used it was found that 100g/L sericite supernatant showed significant growth rate compared with other fractions. From the obtained results comparing with all materials 100g/L sericite concentration was economic for the cultivation of soybean sprout.

• The Journal of Engineering Geology
• /
• v.19 no.3
• /
• pp.287-294
• /
• 2009

To be design the slope, the area distributed the mica schist which was metamorphosed by shale or mudstone must carefully consider the stability. Mica schist is another unstable rock for slope by schistosity, cleavage, axial plane of a fold etc. In general mica schist contains the swelling clay minerals such as smectite, vermiculite and montmorillonite. These minerals make the slope unstable. At OO tunnel construction area for the rail way of the Kyungbu high speed train, the slope of mica schist is very unstable by the distribution phenomena of the discontinuous plane such as joints which are 1-5 cm spacing and thrust and strike-slip fault. By the drilling core of this area, most RQD have 0-20%.

• Journal of the Mineralogical Society of Korea
• /
• v.5 no.2
• /
• pp.93-101
• /
• 1992

Several "Napseok" mines are distribute in the Miryang area where the volcanic rocks are hydrothermally altered. The "Napseok" are pyrophyllite and dickite, with a small amount of silicates such as quartz, illite, tosudite and dumortierite. Other associated minerals are oxides, hydroxides, sulfides, sulfates and phosphates. Pyrophyllite which occurs as 2M polytype exhibits that the basal spacing increases due to dehydroxylation at 750${\circ}C$. Halloysite shows tubular forms. Wavellite is precipitated in fissures during the latest stage of the hydrothermal alteration process. Five mineral zones, that is pyrophyllite-deckite, illite, halloysite, silica, and albite-chlorite zones, are recognized with decreasing alteration degree. Clay minerals were formed by leaching of Si and alkali ions fron the country rocks, considering mineral assemblages, pyrophyllite polytype and thermodynamical data reported in the literature, temperatures of formation of main clay deposits are assumed to be 270 to 350${\circ}C$.

• Korean Journal of Environmental Agriculture
• /
• v.35 no.2
• /
• pp.97-103
• /
• 2016

BACKGROUND: Clay mineral is well known to improve physico-chemical of soil. The objective of this study was to investigate the growth characteristics and inorganic nutrient contents of crops with application levels of phyllite.METHODS AND RESULTS: Both young radish and lettuce were selected as target crops for this study. The experiment was conducted in a wagner pot(1/5000a) in glass house at Sunchon National University. Treatment conditions were divided P0NPK(No phyllite + NPK), P5NPK(phyllite 5 Mg/ha + NPK), P10NPK(phyllite 10 Mg/ha + NPK) and P15NPK(phyllite 15 Mg/ha + NPK) by crops, respectively. Bulk density and porosity of soil in control without treatment conditions were ranged from 1.02 ∼1.04 g/cm³ and 56.5∼57.0%, respectively, and those for treatments with phyllite were in the ranged from 0.94∼1.00 g/cm³ and 58.4∼63.5%, respectively. Dry weights of young radish and lettuce were higher in P15NPK treatment than those in other treatments. The amounts of T-N, T-P and K uptake in young radish with phyllite application treatments were increased 36∼115, 18∼67 and 20∼76% than without phyllite application treatment, respectively. In lettuce treatments, amounts of T-N, T-P and K uptake were intended to all tested treatments similar with result of young radish treatment.CONCLUSION: Therefore, these results confirm that phyllite application to the soil improves physico-chemical of soil in addition to improving growth of young radish and lettuce.

• Journal of the Mineralogical Society of Korea
• /
• v.17 no.1
• /
• pp.23-35
• /
• 2004

The weathering characteristics of periodically submerged sedimentary rocks in the Sayeon dam, Ulsan was examined by field work, electron probe micro-analysis, X-ray diffraction, and X-ray fluorescence spectrometry. Analysis of fracture zone and exfoliation showed the submerged sedimentary rocks have undergone severe mechanical weathering. Mechanical weathering in the water-rock interface accelerated chemical weathering, such as dissolution and alteration of the most of minerals except for quartz in the weathering zone. The dissolution of carbonates specially calcite, is remarkable creating the cavities, whereas formation of minerals including clay minerals is not active. The sedimentary rocks have been periodically submerged for a certain period of time, and have repeated freezing and thawing. This mechanical weathering favored infiltration, which accelerated mineral dissolution. The high content of easily soluble carbonate of the sedimentary rocks is likely the major cause of intense chemical weathering. The dissolved elements within the infiltrated water interrupted the occurrence of clay and weathering minerals, and expend fractures by infiltrated water accelerated weathering process.

• Economic and Environmental Geology
• /
• v.47 no.1
• /
• pp.29-38
• /
• 2014

Recently developed illite-age-analysis (IAA) approach has been applied to determine the multiple events for the Singal and Wangsukcheon faults in the Chugaryeong fault belt, Korea. Fault reactivated events during Late Cretaceous to Paleogene events($69.2{\pm}0.3$ Ma and $27.2{\pm}0.5$ Ma) for the Singal fault and of $75.4{\pm}0.8$ Ma for the Wangsukcheon fault were determined by combined approach of the optimized illite-polytype quantification and the K-Ar age-dating of clay fractions separated from the fault clays. These absolute geochronological determinations of the multiple tectonic events recorded in the Chugaryeong fault belt are crucial to establish the tectonic evolution of the Korean Peninsula since Late Cretaceous.

• Journal of the Korean Geosynthetics Society
• /
• v.9 no.1
• /
• pp.1-11
• /
• 2010

The soil mechanical characteristics according to geologic conditions were investigated in the study area. The geology of study area was consisted of Ingok Tuff, Yuchi Conglomerate and Dado Tuff. Yuchi Tuff covered about 80% of the study area. The disturbed and undisturbed soils were sampled from the conglomerate area, Tuff area and Shale area, and then a series of the laboratory soil tests was performed. The soils sampled from the conglomerate area have a large dry unit weight and a low permeability relatively, while the soils sampled from tuff and shale areas have a small dry unit weight and a high permeability. It is proven that the soil permeability is highly affected by the effective grain size and the silt and clay content. That is, the soil permeability is increased with increasing the effective grain size, and the soil permeability is decreased with increasing the silt and clay content.

• Korean Journal of Mineralogy and Petrology
• /
• v.35 no.4
• /
• pp.397-407
• /
• 2022

Mineralogical analysis of the bedrock of the Gobi Desert in southern Mongolia, the source of Asian dust, was conducted to trace the geological origin of the constituent minerals of Asian dust. The bedrock of the source of Asian dust consists of Paleozoic volcanics and volcaniclastic sedimentary rocks, Paleozoic granitic rocks, and Mesozoic sedimentary rocks. Paleozoic volcanics and volcaniclastic sediments lithified compactly, underwent greenschist metamorphism, and deformed to form mountain ranges. Mesozoic sedimentary rocks fill the basin between the mountain ranges of Paleozoic strata. In comparison to Paleozoic volcanic and sedimentary rocks, Mesozoic sedimentary rocks have lower contents of chlorite and plagioclase, but high contents of clay minerals including interstratified illite-smectite, smectite, and kaolinite. Paleozoic granites characteristically contain amphibole and biotite. Compared with the mineral composition of bedrock in source, Asian dust is a mixture of detrital particles originating from Paleozoic and Mesozoic bedrocks. However, the mineral composition of Mesozoic sedimentary rocks is closer to that of Asian dust. Less lithified Mesozoic sedimentary rocks easily disintegrated to form silty soils which are deflated to form Asian dust.

• The Journal of Engineering Geology
• /
• v.33 no.1
• /
• pp.121-136
• /
• 2023

Microstructural characterization, identification of mineral assemblages, and K-Ar age dating of fault gouges from five Quaternary fault sites segmented along the northern Yangsan Fault, SE Korea were performed to understand formation condition and multiple activity of faults. The mean and median sizes of particles of bulk gouges vary among the studied faults: 1.75 ㎛ and 1.43 ㎛ for the Danguri Fault, 1.94 ㎛ and 1.79 ㎛ for the Yukjae Fault, 5.57 ㎛ and 4.16 ㎛ for the Yugye Fault, and 5.55 ㎛ and 2.31 ㎛ for the Bogyeongsa Fault. Fault gouges contain abundant secondary minerals, including smectite, chlorite, illite, kaolinite, laumontite, and mordenite, which are found in association with quartz and feldspar. K-Ar dating of the fault gouges (both bulk samples and separate size fractions) yields ages ranging from 59.1 to 18.8 Ma, with bulk ages of 47.6 Ma for the Yukjae Fault, 59.1 Ma for the Ansim Fault, 39.4 Ma for the Yugye Fault, and 22.6 Ma for the Bogyeongsa Fault. The finer fractions generally have younger K-Ar ages compared with the coarser fractions, and the finest fraction (<0.2 ㎛) is the youngest for each fault. Hydrothermal alteration of the gouges is considered to have occurred under low-temperature (100~200℃) conditions during faulting. Microstructural features and clay mineral assemblages of fault gouges and brecciated rocks should be considered when interpreting fault events and reactivation, in addition to age dating of faulting.