• Title/Summary/Keyword: Clay materials

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A Characteristic Analysis on Clay Pigments of Mural Paintings in Sri Lanka

  • Yoo, Seon-Young;Seneviratne, Buddakoralelage Janani Namal;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.327-333
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    • 2022
  • Sri Lanka has four types of mural painting styles; Classic, Late Classic, Kandyan, and Southern styles, but there is little research on scientific analysis for mural paintings. In this study, we analyze white, yellow, and red clay pigments which were collected from ancient producing sites. Analyzing pigment samples shows that samples are containing aluminum oxide(Al2O3) and silicon dioxide(SiO2) which are connected to the soil. And a degree of iron oxidation determines yellow or red colors. To understand the characteristics of clay pigment samples, we go over previous pigment analyses of mural paintings in Sri Lanka. Kaolin is identified after the 17th century, yellow and red ochre are applied in early periods, Classic and Late Classic styles. The change in raw materials of pigments occurred in the 17th century.

Characteristics of adsorption-desorption of herbicide paraquat in soils (제초제 paraquat의 토양중 흡.탈착 특성)

  • Lee, Seog-June;Kim, Byung-Ha;Kim, Jang-Eok
    • The Korean Journal of Pesticide Science
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    • v.2 no.1
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    • pp.70-78
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    • 1998
  • This study was conducted to investigate the adsorption-desorption characteristics of herbicide paraquat on clay minerals, humic materials, and soils under the laboratory conditions. Adsorption time of paraquat on clay minerals was faster than organic materials and soils. Adsorption amount on montmorillonite, 2:1 expanding-lattice clay mineral, was largest among the adsorbents tested. The adsorption capacity of paraquat was approximately 21 % of cation exchange capacity in soils, 45.1 % in kaolinite, and 80.6% in montmorillonite. Humic materials, humic acid and fulvic acid isolated from soil II, adsorbed larger amount of paraquat than kaolinite and soils. Distribution of tightly bound type of paraquat was larger in clay mineral and soils but loosely bound type was larger in humic acid and fulvic acid. In oxidized soil, the adsorption amount of paraquat was decreased to 85.1-95.5% of original soils. Distribution of unbound and loosely bound type of paraquat was decreased in oxidized soil but tightly bound type was increased. The competition cations decreased paraquat adsorption on humic materials and soils but not affected on montmorillonite. No difference was observed as the kinds of cations. In cation-saturated adsorbents, the adsorption amount was decreased largely in humic materials and soils but decreased a little in montmorillonite. The tightly bound type of paraquat in all adsorbents was not desorbed by pH variation, sonication, and cation application but loosely bound type was desorbed. However, the desorption amount was different as a kinds of adsorbents and desorption methods.

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Study on the Characteristics of Materials and Production Techniques of Clay Seated Vairocana Buddha Triad of Seonunsa Temple, Gochang (보물 제1752호 고창 선운사 소조비로자나삼불좌상 재질특성 및 제작기법 연구(1): 소조불상 주요 구성재료 분석)

  • Lee, Hwa Soo;Lee, Han Hyoung;Han, Gyu-Seong
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.562-577
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    • 2020
  • In this study, to conserve the clay seated Vairocana Buddha triad in Seonunsa temple, Gochang (Treasure 1752), the primary materials employed for creating the clay Buddha statues were scientifically analyzed. By analyzing the soil layer constituting the Buddha statues, it is observed that the said layer comprises sand having particle size greater than that of medium sand and soil having particle size smaller than that of fine sand, which were used in a ratio of 7:3, along with the bast fibers of paper mulberry (Broussonetia kazinoki). Hence, the aforementioned soil layer is composed of a mixture of sand and weathered soil, along with bast fibers to prevent scattering. By analyzing the tree species, it is found that the wooden materials constituting the bottom board and the interior of Buddha's sleeves of the Amitabha Buddha statue, Vairocana Buddha statue, and Medicine Buddha statue are hard pines (Pinus spp.). Additionally, three layers are found in the cross section of the gold layer. Furthermore, each of the hair sections of the Buddha statues is composed of earthy materials such as quartz, albite, microcline, mica, and magnetite, and the hair surface was painted by incorporating black materials containing magnetite.

Characterization and Fatigue Life Evaluation of Rubber/Clay Nanocomposites (고무-점토 나노복합체 물성 및 피로내구성 평가)

  • Woo, Chang-Su;Park, Hyun-Sung;Joe, Deug-Hwan;Jun, Young-Sig
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1199-1203
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    • 2011
  • Nanocomposites were prepared through the compounding of rubber and clay. Measurements of the static and dynamic mechanical properties of different compositions over a temperature range $70-100^{\circ}C$ showed that the mechanical properties of these rubber/clay nanocomposites are superior to those of existing rubber materials. In this study, by using the parameter of the maximum Green.Lagrange strain appearing at certain locations, the relationship between fatigue life and maximum Green.Lagrange strain, and the correlations between test-piece tests and bench tests of actual rubber components are proved. In order to predict the fatigue life of rubber components at the design stage, a simple procedure of life prediction is suggested. The predicted fatigue lives of the rubber engine mounts agree fairly well with the fatigue lives determined experimentally.

A Study of Iron Pot Casting and Bellows Technology (토제 거푸집 무쇠솥 주조와 불미기술 연구)

  • Yun, Yonghyun;Doh, Jungmann;Jeong, Yeongsang
    • Korean Journal of Heritage: History & Science
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    • v.53 no.2
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    • pp.4-23
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    • 2020
  • The purpose of this study was to explore the diversity of Korea's iron casting technology and to examine various casting methods. The study involved a literature review, analysis of artifacts, local investigation of production tools and technology, and scientific analysis of casting and cast materials. Bellows technology, or Bulmi technology, is a form of iron casting technology that uses bellows to melt cast iron before the molten iron is poured into a clay cast. This technology, handed down only in Jeju Island, relies on use of a clay cast instead of the sand cast that is more common in mainland Korea. Casting methods for cast iron pots can be broadly divided into two: sand mold casting and porcelain casting. The former uses a sand cast made from mixing seokbire (clay mixed with soft stones), sand and clay, while the latter uses a clay cast, formed by mixing clay with rice straw and reed. The five steps in the sand mold casting method for iron pot are cast making, filling, melting iron into molten iron, pouring the molten iron into the cast mold, and refining the final product. The six steps in the porcelain clay casting method are cast making, cast firing, spreading jilmeok, melting iron into molten iron, pouring the molten iron, and refining the final product. The two casting methods differ in terms of materials, cast firing, and spreading of jilmeok. This study provided insight into Korea's unique iron casting technology by examining the scientific principles behind the materials and tools used in each stage of iron pot casting: collecting and kneading mud, producing a cast, biscuit firing, hwajeokmosal (building sand on the heated cast) and spreading jilmeok, drying and biyaljil (spreading jilmeok evenly on the cast), hapjang (combining two half-sized casts to make one complete cast), producing a smelting furnace, roasting twice, smelting, pouring molten iron into a cast, and refining the final product. Scientific analysis of the final product and materials involved in porcelain clay casting showed that the main components were mud and sand (SiO2, Al2O3, and Fe2O3). The release agent was found to be graphite, containing SiO2, Al2O3, Fe2O3, and K2O. The completed cast iron pot had the structure of white cast iron, comprised of cementite (Fe3C) and pearlite (a layered structure of ferrite and cementite).

A Study on the Optimal Mixture Ratio for Stabilization of Surface Layer on Ultra-soft Marine Clay (초연약 해성점토의 표층고화처리를 위한 최적배합에 관한 연구)

  • 천병식;고경환;김진춘
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.33-43
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    • 2002
  • Recently, as large constructions on the coast increase, an application of a surface layer stabilization method which is one of the improvement methods for dredged soft clay has increased. However, there are few studies about this. The purpose of this study is clarifying characteristics of ultra-soft marine clay and hardening agent. Also, it is verifying an optimal mixture ratio of hardening agent through the laboratory tests according to designed experiments and proving by statistical analysis and pilot tests. Laboratory tests were performed with proper hardening agent and test soil in accordance with the design of experiments. Regression equations between hardening agents materials and unconfined compressive strength were derived from the tests. The applicability of regression equations were also verified by pilot tests. From the test results, it was found that hardening agent materials(cement, slag, fly-ash, inorganic salts, arwin, gypsum etc.) have some effect upon compressive strength. The optimal mixture ratio which satisfies the required compressive strength was derived from the statistical analysis. The effect of ground improvement by cements and hardening agents was confirmed through the pilot tests. This study will suggest data for design or construction criteria of stabilization of surface layer on ultra-soft marine clay.

Characterization of Poly(vinyl alcohol) Nanocomposite Films with Various Clays (다양한 점토를 이용한 폴리(비닐 알코올) 나노 복합체 필름의 특성 연구)

  • Ham, Miran;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.225-231
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    • 2013
  • Poly(vinyl alcohol) (PVA) hybrid films containing 5 wt% pristine clay mineral were synthesized in the water solution. The various PVA hybrid films were synthesized from structurally different pristine clays: saponite (SPT), montmorillonite (MMT), hectorite (SWN), hydrophilic bentonite (PGV), and mica (Mica). The thermo-optical properties and morphologies of the PVA hybrid films were evaluated with various pristine clays. The nanostructure of the hybrid films was observed using transmission electron microscopy, which showed that the clay layers were well dispersed into the matrix polymer, although some clusters or agglomerated particles were also detected. The addition of pristine clay was more effective with regard to improving the thermal properties and gas barrier characteristics, whereas the optical transparency of the PVA hybrid films deteriorated with pristine clay.

Membrane Application of Polymer/Layered Silicate Nanocomposite (고분자/층상실리케이트 나노복합체의 분리막에의 응용)

  • Park, Ji-Soon;Rhim, Ji-Won;Goo, Hyung-Seo;Kim, In-Ho;Nam, Sang-Yong
    • Membrane Journal
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    • v.15 no.4
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    • pp.255-271
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    • 2005
  • polymer/layered silicate nanocomposite (PLSNs) is new type of materials, based on clays usually rendered hydrophobic through ionic exchange of the sodium interlayer cation with an onium cation. It could be prepared via various synthetic routes comprising exfoliation adsorption, in situ intercalative polymerization and melt intercalation. The whole range of polymer is used, i.e. thermoplastics, thermosets and elastomers as a matrix. Two types of structure may be obtained, namely intercalated nanocomposites where the polymer chains are sandwiched in between silicate layers and exfolicate nanocomposites where the separated, individual silicate layers are more or less uniformly dispersed in the polymer matrix. This new family of materials exhibits enhanced properties at very low filer level, usually inferior to 5wt$\%$, such as increased mechanical properties, increase in thermal stability and gas barrier properties and good flame retardancy. Gas permeability through the PLSNs films decreased due to increased tortuosity made by intercalation or exfoliation of clay in polymer.