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http://dx.doi.org/10.7317/pk.2013.37.2.225

Characterization of Poly(vinyl alcohol) Nanocomposite Films with Various Clays  

Ham, Miran (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Kim, Jeong-Cheol (Energy and Applied Optics Team, Korea Institute of Industrial Technology)
Chang, Jin-Hae (School of Energy and Integrated Materials Engineering, Kumoh National Institute of Technology)
Publication Information
Polymer(Korea) / v.37, no.2, 2013 , pp. 225-231 More about this Journal
Abstract
Poly(vinyl alcohol) (PVA) hybrid films containing 5 wt% pristine clay mineral were synthesized in the water solution. The various PVA hybrid films were synthesized from structurally different pristine clays: saponite (SPT), montmorillonite (MMT), hectorite (SWN), hydrophilic bentonite (PGV), and mica (Mica). The thermo-optical properties and morphologies of the PVA hybrid films were evaluated with various pristine clays. The nanostructure of the hybrid films was observed using transmission electron microscopy, which showed that the clay layers were well dispersed into the matrix polymer, although some clusters or agglomerated particles were also detected. The addition of pristine clay was more effective with regard to improving the thermal properties and gas barrier characteristics, whereas the optical transparency of the PVA hybrid films deteriorated with pristine clay.
Keywords
poly(vinyl alcohol); clay; nanocomposite; film;
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1 R. K. Bharadwaj, Macromolecules, 34, 9189 (2001).   DOI   ScienceOn
2 D. Jarus, A. Hiltner, and E. Baer, Polymer, 43, 2401 (2002).   DOI   ScienceOn
3 D. H. Weinkauf and D. R. Paul, Effect of Structural Order on Barrier Properties, American Chemical Society, Washington, DC, 1990.
4 C. Joly, M. Smaihi, L. Porcar, and R. D. Noble, Chem. Mater., 11, 2331 (1999).   DOI   ScienceOn
5 S. Sinha Ray and M. Okamoto, Prog. Polym. Sci., 28, 1539 (2003).   DOI   ScienceOn
6 J.-H. Chang and K. M. Park, Polym. Eng. Sci., 41, 2226 (2001).   DOI   ScienceOn
7 Y. Fukushima and S. Inagaki, Incl. Phenom., 5, 473 (1987).   DOI
8 E. P. Giannelis, Adv. Mater., 8, 29 (1996).   DOI
9 T. Srikhirin, A. Moet, and J. B. Lando, Polym. Adv. Tech., 9, 491 (1998).   DOI
10 Y. S. Chol and I. J. Chung, Korea Chem. Eng., 46, 23, (2008).
11 P. C. Lebaron, Z. Wang, and T. J. Pinnavaia, Appl. Clay Sci., 15, 11 (1999).   DOI   ScienceOn
12 P. B. Messersmith and E. P. Giannelis, Chem. Mater., 5, 1064 (1993).   DOI   ScienceOn
13 Y. Kojima, A. Usuki, M. Kawasumi, and A. Okada, J. Mater. Res., 8, 1185 (1993).   DOI   ScienceOn
14 J. W. Gilman, Appl. Clay Sci., 15, 31 (1999).   DOI   ScienceOn
15 D. Shi, W. Yu, R. K. Y. Li, Z. Ke, and J. Yin, Eur. Polym. J., 43, 3250 (2007).   DOI   ScienceOn
16 J.-H. Chang, T. G. Jang, K. J. Ihn, W. K. Lee, and G. S. Sur, J. Appl. Polym. Sci., 90, 3208 (2003).   DOI   ScienceOn
17 K. E. Strawhecker and E. Manias, Chem. Mater., 12, 2943 (2000).   DOI   ScienceOn
18 S. Kumar, J. P. Jog, and U. Natarajan, J. Appl. Polym. Sci., 89, 1186 (2003).   DOI   ScienceOn
19 J.-H. Chang, M. K. Mun, and I. C. Lee, J. Appl. Polym. Sci., 98, 2009 (2005).   DOI   ScienceOn
20 T. D. Fornes, P. J. Yoon, D. L. Hunter, H. Keskkula, and D. R. Paul, Polymer, 43, 5915 (2002).   DOI   ScienceOn
21 J. Bernard, A. Favier, T. P. Davis, C. Barner-Kowollik, and M. H. Stenzel, Polymer, 47, 1073 (2006).   DOI   ScienceOn
22 M. Levine, G. Iikka, and P. Weis, J. Polym. Sci. Part B: Polym. Chem., 2, 915 (1964).   DOI
23 S. M. Tadavarthy, J. H. Moller, and K. Amplatz, Am. J. Roentgenol., 125, 609 (1975).   DOI
24 W.-Y. Chiang and C.-M. Hu, J. Appl. Polym. Sci., 30, 4045 (1985).   DOI   ScienceOn
25 J. Wen, V. J. Vasudevan, and G. L. Wilkes, J. Sol-Gel Sci. Technol., 5, 115 (1995).   DOI   ScienceOn
26 R. Y. M. Huang and J. W. Rhim, Polym. Int., 30, 129 (1993).   DOI
27 S. K. Ham, M. H. Jung, and J.-H. Chang, Polymer(Korea), 30, 298 (2006).
28 K. Nakane, T. Yamashita, K. Iwakura, and F. Suzuki, J. Appl. Polym. Sci., 74, 133 (1999).   DOI   ScienceOn
29 I. Sakurada, Poly(vinyl alcohol) Fibers, Marcel Dekker, New York, 1985.
30 W. Y. Chuang, T. H. Yong, W. Y. Chiu, and C. Y. Lin, Polymer, 41, 5633 (2000).   DOI   ScienceOn
31 G. Legaly, Appl. Clay Sci., 15, 1 (1999).   DOI   ScienceOn
32 H. R. Frischer, L. H. Gielgens, and T. P. M. Koster, Acta Polym., 50, 122 (1999).   DOI   ScienceOn
33 J.-H. Chang, "Permeation Properties of Water-Soluble Polymer Nanocomposite Systems", in Barrier Properties of Polymer Clay Nanocomposites, Vikas Mittal, Editor, Nova Science Publishers, Inc., Chapter 6, pp. 117-137 (2009).
34 Y.-H. Yu, C.-Y. Lin, J.-M. Yeh, and W.-H. Lin, Polymer, 44, 3553 (2003).   DOI   ScienceOn
35 F. Suzuki, K. Nakane, and J. S. Piao, J. Mater. Sci., 31, 1335 (1996).   DOI   ScienceOn
36 G. Legaly, Developments in Ionic Polymers, Elsevier, London, Vol 2, p 77 (1986).
37 R. Vendamme, S. Y. Onoue, A. Nakao, and T. Kunitake, Nature Mater., 5, 494 (2006).   DOI   ScienceOn
38 K. Haraguchi, M. Ebato, and T. Takehisa, Adv. Mater., 18, 2250 (2006).   DOI   ScienceOn
39 J.-H. Yeun, G.-S. Bang, B. Y. Park, and J.-H. Chang, J. Appl. Polym. Sci., 101, 591 (2006).   DOI   ScienceOn
40 S. W. Jang and J.-H. Chang, Polymer(Korea), 31, 221 (2007).
41 J. E. Shin, M. R. Ham, J. C. Kim, and J.-H. Chang, Polymer (Korea), 35, 402 (2011).
42 W. F. Jaynes and J. M. Bigham, Clays & Clay Minerals, 35, 440 (1987).   DOI   ScienceOn
43 S.-H. Hsiao, G.-S. Liou, and L.-M. Chang, J. Appl. Polym. Sci., 80, 2067 (2001).   DOI   ScienceOn
44 J.-H. Chang, S. J. Kim, and S. Im, Polymer, 45, 5171 (2004).   DOI   ScienceOn
45 A. B. Morgan and J. W. Gilman, J. Appl. Polym. Sci., 87, 1329 (2003).   DOI   ScienceOn
46 G. Galgali, C. Ramesh, and A. Lele, Macromolecules, 34, 852 (2001).   DOI   ScienceOn
47 T. K. Chen, Y. I. Tien, and K.-H. Wei, Polymer, 41, 1345 (2000).   DOI   ScienceOn