• Title/Summary/Keyword: Clay Minerals

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Fundamental Studies on Stabilization of Shallow Slope Failure Using Lime Pile - Changes of Clayey Properties with Lime Addition - (생석회 파일을 이용한 얕은 사면 파괴의 안정화에 대한 기초 연구 - 생석회 첨가에 따른 점성토의 특성 변화 중심으로 -)

  • Kwon, Moonam;Goo, Jeungmin
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.5
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    • pp.49-55
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    • 2006
  • Quick lime made from limestone that are deposited abundantly in Korea has excellent potentials for stabilization of clayey soils. If Korea is able to take advantage of its abundant supply, economical efficiency could be achieved through mass production as well as being able to take advantage of utilization of natural resources. For stabilizing of clayey soil with lime, it is necessary to determine the required quantities of lime firstly and to evaluate the degree of stabilization with lime content. In this test, the quantity of lime required for 2 clayey soils which located in Seunggok and Bugok province respectively, and for 2 clay minerals-kaolinite and montmorillonite-were determined by ASTM C 977-92 and were evaluated for solidification of each samples with changing lime contents by Atterberg limit test and pH test. It was also evaluated for the improvement of each sample with lime content and curing time. The sample which added lime content determined by ASTM C 977-92 increased plastic limit, unconfined compression strength, and decreased pH in increasing trend.

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Removal of Pb(II) from Aqueous Solution Using Hybrid Adsorbent of Sericite and Spent Coffee Grounds (견운모와 커피찌꺼기 복합 흡착제를 이용한 수용액의 Pb(II) 제거)

  • Choi, Hee-Jeong
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.571-580
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    • 2018
  • In this study, hybrid adsorbents (SS) were prepared by mixing spent coffee grounds (SCG) and sericite, a kind of clay minerals, to adsorb Pb(II) from an aqueous solution. In FT-IR analyses, the main functional groups of SS adsorbents were O-H, C=O and C-N groups. The specific surface area, cation exchange capacity and the pore diameter of SS were larger than those of using SCG and sericite. Formation conditions of the SS adsorbent were the optimum pyrolysis temperature of $300^{\circ}C$, SCG : sericite ratio of 8 : 2, and particle size of 0.3 mm. Langmuir adsorption isotherm was more suitable than Freundlich one, and the maximum adsorption capacity was reached 44.42 mg/g. As a result of the adsorption thermodynamic analysis, the adsorption of Pb(II) onto SS was the physical adsorption and exothermic process in nature. The regeneration of SS adsorbent using distilled water showed 88~92% recovery and the active site of SS adsorbent decreased with increasing the reuse cycle time. As a result, SS adsorbent showed that it can be used to remove Pb(II) easily, inexpensively and efficiently without any pre-treatment from aqueous solutions.

Petrogeochemistry of Shales in Cretaceous Gyeongsang Supergroup from the Euiseong Basin, Korea (의성분지(義城盆地)에 분포(分布)하는 백악기(白堊紀) 경상누층군(慶尙累層群)의 셰일에 관(關)한 암석지구화학(岩石地球化學))

  • Lee, Hyun Koo;Lee, Chan Hee;Kim, Sang Jung
    • Economic and Environmental Geology
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    • v.30 no.1
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    • pp.1-14
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    • 1997
  • The shales from the Euiseong area are interbedded along the bedding in Cretaceous Gyeongsang Supergroup, which are composed mainly of quartz, plagioclase, K-feldspar and associated with trace amount of biotite, muscovite, chlorite, pyrite, hematite, carbonate and clay minerals. The ratio of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shales from the Shindong Group are ranged from 9.16 to 24.32 and from 1.70 to 5.97, and the Hayang Group ranged from 2.76 to 8.89 and from 0.42 to 2.74, which are negative correlated between $K_2O/Na_2O$ and $Al_2O_3/Na_2O$ against $SiO_2/Al_2O_3$ respectively. Those are suggested that controlled of mineral compositions in shales due to substitution and migration of elements by sedimentation and diagenesis. These shale formation were deposited in basin of terrestrial environments originated from the igneous rocks, and the REE of these rocks are not influenced with diagenesis and hydrothermal alterations on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.43 to 0.62) and Th/U (1.11 to 10.71). The narrow range in trace and REE element characteristics as Co/Th (0.63 to 1.92), La/Sc (1.98 to 5.90), Sc/Th (0.58 to 1.30), V/Ni (0.90 to 3.25), Cr/V (0.45 to 1.78), Ni/Co (1.88 to 6.67) and Zr/Hf (30.04~60.87) of these shales argues for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (6.90 to 17.02), Th/Yb (4.17 to 13.68) and La/Th (1.98 to 5.90), and their origin is explained by derivation from a mixture of intermediate to acidic igneous rocks.

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An Analysis of the Behavior of Rock Slope with Excavation-Induced Tension Cracks Located in DongHae Highway Construction Site (개착과정에서 인장균열이 발생된 동해고속도로 건설현장 암반사면의 거동 해석)

  • 조태진;이창영;고기성
    • Journal of the Korean Geotechnical Society
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    • v.20 no.8
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    • pp.15-27
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    • 2004
  • Sliding aspects of rock slope, where large-scaled tension cracks are induced during preliminary excavation, have been analyzed. Structure of rock mass is investigated by performing the electrical resistivity survey and the orientations and positions of discontinuities are measured from DOM-drilled core log. Geological evidence far primary failure movement has been detected and clay minerals which possess swelling properties are identified through XRD analysis. Slope stability is examined by considering the orientations of discontinuities and their trace distributions on the cut-face and neighboring natural slope surface. Both orientations and positions of failure-invoking discontinuity planes, traces of which are exposed within the anticipated sliding region, are concerned fur analyzing the preferred sliding directions. Regional sliding vectors are assessed based on the relative positions of potential sliding planes in the boreholes and the general trend of anticipated failure movement of rock slope is also investigated.

Origin of Banded $B_t$ Horizons in Sandy Deposits ($B_t$ Band의 형성 과정)

  • 오경섭
    • The Korean Journal of Quaternary Research
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    • v.3 no.1
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    • pp.35-45
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    • 1989
  • In Korean peninsula as well as in Western European Countries, we can find, reddish bands in sandy deposits of various origin. These bands (called "$B_t$ Band"), composed of fine material, are regularly intervalled and parallel to topography. This study is tring to elucidate their origin and associated milieux, with a group of methods and techniques (field survey, micromorphological analysis, granulometry, X-ray diffractometry of clay minerals...). $B_t$ Bands are not sedimentological origin. They were formed by superposition of two type accumulations in the sandy profile, triggered by different mechanisms: 1) accumulation in banded form, concerning silty heterometric material and micas, oweing to cryophoretic forces operating in course of deep freezing of sandy deposits: 2) illuviation of ferrugineous clays in the precedants bands, migrated in chelate state by soil water. The first processes are associated with very cold and humid climate in which freeze soil more than 3m in depth. The second, cold and humid climate in which podzolizattion is generalized. In case of South Korea and Western Europe, these two types of climates are not present circumstance, but Recent Quaternary (probably since the Wurm).the Wurm).

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Development of several methods to remove Cadmium from soil contaminated with Cadmium (Cadmium 오염토양(汚染土壤)에서 Cadmium 제거방법(除去方法)의 개발(開發))

  • Choi, Jyung;Lee, Jyung-Jae;Hur, Nam-Ho
    • Korean Journal of Environmental Agriculture
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    • v.10 no.2
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    • pp.128-132
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    • 1991
  • This study was carried out to find a method to remove cadmium from soil and/or attenuate in Cd saturated Soil The chemical form of Cd was influenced by the physico-chemical properties of soil and the adsorption of Cd by soil conformed to the Langmuir isotherm. The order of Cd contents in chemical fractions extracted by several reagents was EDTA > NaOH > $HNO_3$. Flooding, liming and the addition of chelating agents and clay minerals to the contaminated soil seems to desirable in alleviating the harmful effects of Cd on plant growth by reducing Cd content in the $KNO_3$ fraction.

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Analysis for the Behavior of Ridge-Cut Rock Slope (능선부 개착에 의해 형성된 암반사면 거동해석)

  • Cho, Tae-Chin;Hwang, Taik-Jean;Shin, Sun-Mi;Lee, Guen-Ho
    • Tunnel and Underground Space
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    • v.22 no.6
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    • pp.393-402
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    • 2012
  • A behavior of ridge-cut rock slope had been monitored by installing inclinometers and regional slope movement toward rear side of cut face was detected. To delineate the governing factors of slope behavior, especially backward slip of ridge-cut slope, petrographic characteristics of rock cores obtained from four drilled boreholes had been examined. BIPS images inside boreholes had been acquired and structural characteristics of slope rock had been studied. Mechanical properties of discontinuity planes distributed in the drilled core had been measured and the shear strength of coal seam imbedded-discontinuity planes also had been obtained by performing the direct shear test. Monitoring results of slope behavior had been analyzed by comprehensibly considering both the mechanical and structural characteristics of slope rock and coal seam-imbedded discontinuity planes, and the potential governance of coal seam and clay minerals embedded in the joint plane on the regional slope behavior has been also identified.

Advance of geophysical exploration techniques for investigation of seawater intrusion (해수침투 평가를 위한 물리탐사기술의 진전)

  • 이상규;황학수;황세호;박인화;성낙훈
    • The Journal of Engineering Geology
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    • v.10 no.2
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    • pp.172-188
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    • 2000
  • This paper presents the state of art and the role of geophysical exploration techniques with evaluating the trend of domestic and worldwide seawater intrusion research, and illustrates advanced techniques obtained through the project of 'Development of the techniques for estimation, prediction, and prevention of seawater intrusion' funded by the Ministry of Science and Technology of Korea. The advanced geophysical interpretation was achieved by adding the digital geophysical logging data. DC resistivity and TEM monitorings were applied to determine whether or not the seawater intrusion was in progress. Induced Polarization technique using electric current monitoring channel was introduced to discriminate seawater contaminated zone from highly conductive layer caused by clay minerals. A conceptual model was suggested with spatial visualization of the study area to predict the diffusion of seawater contamination. Finally, the future work of the development of geophysical techniques was suggested with the base of the present level of them.

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Spatial Interpretation of Monsoon Turbid-water Environment in a Reservoir (Yongdam) Discharging Surface Water, Korea (표층수를 방류하는 저수지(용담호)에서 몬순 탁수환경의 공간적 해석)

  • Shin, Jae-Ki;Hur, Jin;Lee, Heung-Soo;Park, Jae-Chung;Hwang, Soon-Jin
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.933-942
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    • 2006
  • In this study, temperature, turbidity, suspended paniculate matter (SPM) distribution and mineral characteristics were investigated to explain spatial distribution of the turbid-water environment of Yongdam reservoir in July, 2005. Six stations were selected along a longitudinal axis of the reservoir and sampling was conducted in four depths of each station. Water temperature was showed the typical stratified structure by the effects of irradiance and inflow. Content of inorganic matter in suspended particles increased with the concentration of suspended particulate matter (SPM) due to the reduction of ash-free dry matter (AFDM). Turbidity ranged from 0.6 to 95.1 NTU and the maximum turbidity value of each station sharply increased toward downstream from upstream. The high turbidity layers were located at the depth between 12~16 m. Particle size ranged from 0.435 to $482.9{\mu}m$. day and silt-sized particles corresponded 91.9~98.9% and 1.1~8.0% in total numbers of SPM, respectively. Turbidity showed high correlations with clay (r=0.763, p<0.05) and silt content (r=0.870, p<0.05).Inorganic matter content (r=0.960, p<0.01) was more correlated with turbidity than organic matter (r=0.823, p<0.05). Mineral characterization using x-ray diffraction and electron probe microanalyzer demonstrated that the major minerals contained in the SPM were kaolinite, illite, vermiculite and smectite. As results of this study, surface water discharge as well as small size of the SPM were suggested as long-term interfering factors in settling down the turbid water in the reservoir.

Utilization of Natural Zeolite for $NH_4^\;^+-N$ Adsorbent (($NH_4^\;^+-N$ 흡착제(吸着劑)로서의 천연(天然) Zeolite의 이용(利用))

  • Kim, Sang-Su;Hur, Nam-Ho;Choi, Jyung
    • Korean Journal of Environmental Agriculture
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    • v.10 no.1
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    • pp.27-31
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    • 1991
  • This study was conducted to examine the adsorption capacity of $NH_4\;^+-N$ by natural zeolite for the purpose of investigating the possibility for $NH_4\;^+-N$ eliminator of Korean natural zeolite. The dominant clay minerals of zeolite were clinoptilolite and mordenite. The reaction of $NH_4\;^+-N$ adsorption by zeolite reached equilibrium after 4hrs. The amount of $NH_4\;^+-N$ adsoption by zeolite was not significantly affected by the particle size of zeolite. The order of $NH_4\;^+-N$ adsorption by zeolite according to exchangeable cations was Na-> Ca> K-saturated zeolite. The amount of $NH_4\;^+-N$ adsorption by zeolite was increased with increasing pH of solution and the ratio of zeolite to the volume of solution. The isothermal curvel of $NH_4\;^+-N$ adsorption by zeolite was conformed to Langmuir equation.

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