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http://dx.doi.org/10.14478/ace.2018.1056

Removal of Pb(II) from Aqueous Solution Using Hybrid Adsorbent of Sericite and Spent Coffee Grounds  

Choi, Hee-Jeong (Department of Health and Environment, Catholic Kwandong University)
Publication Information
Applied Chemistry for Engineering / v.29, no.5, 2018 , pp. 571-580 More about this Journal
Abstract
In this study, hybrid adsorbents (SS) were prepared by mixing spent coffee grounds (SCG) and sericite, a kind of clay minerals, to adsorb Pb(II) from an aqueous solution. In FT-IR analyses, the main functional groups of SS adsorbents were O-H, C=O and C-N groups. The specific surface area, cation exchange capacity and the pore diameter of SS were larger than those of using SCG and sericite. Formation conditions of the SS adsorbent were the optimum pyrolysis temperature of $300^{\circ}C$, SCG : sericite ratio of 8 : 2, and particle size of 0.3 mm. Langmuir adsorption isotherm was more suitable than Freundlich one, and the maximum adsorption capacity was reached 44.42 mg/g. As a result of the adsorption thermodynamic analysis, the adsorption of Pb(II) onto SS was the physical adsorption and exothermic process in nature. The regeneration of SS adsorbent using distilled water showed 88~92% recovery and the active site of SS adsorbent decreased with increasing the reuse cycle time. As a result, SS adsorbent showed that it can be used to remove Pb(II) easily, inexpensively and efficiently without any pre-treatment from aqueous solutions.
Keywords
adsorption; heavy metal removal; hybrid materials; spent coffee grounds; sericite;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 H. J. Choi, Biosorption of heavy metals from acid mine drainage by modified sericite and microalgae hybrid system, Water Air Soil Pollut., 226(6), 1-8 (2015).
2 C. H. Wu, C. Y. Kuo, and S. S. Guan, Adsorption kinetics of lead and zinc ions by coffee residues, Pol. J. Environ. Stud., 24, 761-767 (2015).
3 M. Ghasemi, M. Naushad, N. Ghasemi, and Y. Khosravi-fard, Adsorption of Pb(II) from aqueous solution using new adsorbents prepared from agricultural waste: Adsorption isotherm and kinetic studies, J. Ind. Eng. Chem., 20(4), 2193-2199 (2014).   DOI
4 J. Anwar, U. Shafique, W. Zaman, M. Salman, A. Dar, and A. Shafique, Removal of Pb(II) and Cd(II) from water by adsorption on peels of banana, Bioresour. Technol., 101, 1752-1755 (2010).   DOI
5 A. A. Alghamdi, An investigation on the use of date palm fibers and coir pith as adsorbents for Pb(II) iones from its aqueous solution, Desalination Water Treat., 57(25), 12216-12226 (2015).
6 S. Gupta, D. Kumar, and J. P. Gaur, Kinetic and isotherm modeling of Pb(II) sorption onto some waste plant materials, Chem. Eng. J., 148, 226-233 (2009).   DOI
7 H. D. Utomo, Lead adsorption onto various solid surfaces, Nat. Resour., 6, 152 (2015).
8 R. Lafi, A. B. Fradj, A. Hafiane, and B. H. Hameed, Coffee waste as potential adsorbent for the removal of basic dyes from aqueous solution, Korean J. Chem. Eng., 31, 2198-2206 (2014).   DOI
9 F. J. Cerino-Cordova, P. E. Diaz-Flores, R. B. Garcia-Reyes, E. Soto-Regalado, R. Gomez-Gonzalez, M. T. Garza-Gonzalez, and E. Bustamante-Alcantara, Biosorption of Cu(II) and Pb(II) from aqueous solutions by chemically modified spent coffee grains, Int. J. Environ. Sci. Technol., 10, 611-622 (2013).   DOI
10 H. G. Alemayehu, A. K. Burkute, and A. G. Ede, Adsorptive removal of Pb(II) and Cr(VI) from wastewater using acid untreated coffee husk, Interlink Cont. J. Environ. Sci. Toxicol., 1, 9-16 (2014).
11 S. Berhe, D. Ayele, A. Tadesse, and A. Mulu, Adsorption efficiency of coffee husk for removal of lead(II) from industrial effluents: equilibrium and kinetic study, Int. J. Sci. Res. Publ., 5, 1-8 (2015).
12 F. R. Oliveira, A. K. Patel, D. P. Jaisi, S. Adhikari, H. Lu, and S. K. Khanal, Environmental application of biochar: Current status and perspectives, Bioresour. Technol., 246, 110-122 (2017).   DOI
13 R. Gomez-Gonzalez, F. J. Cerino-Cordova, A. M. Garcia-Leon, E. Soto-Regalado, N. E. Davila-Guzman, and J. J. Salazar-Rabago, Lead biosorption onto coffee grounds: Comparative analysis of several optimization techniques using equilibrium adsorption models and ANN, J. Taiwan Inst. Chem. Eng., 68, 201-210 (2016).   DOI
14 C. Jeon, Adsorption and recovery of immobilized coffee ground beads for silver ions from industrial wastewater, J. Ind. Eng. Chem., 53, 261-267 (2017).   DOI
15 H. J. Choi, Behavior of Pb(II) and Cd(II) Removal from aqueous solution by adsorption onto methyl-esterified sericite, KSWST J. Water Treat., 24(4), 87-100 (2016).
16 H. J. Choi and K. H. Kim, Parametric study a dyeing wastewater treatment by modified sericite, Environm. Technol., 37(20), 2572-2579 (2016).
17 I. Anastopoulos, M. Karamesouti, A. C. Mitropoulos, and G. Z. Kyzas, A review for coffee adsorbents, J. Mol. Liq., 229, 555-565 (2017).   DOI
18 F. Fu and Q. Wang, Removal of heavy metal ions from wastewaters: A review, J. Environ. Manag., 92(3), 407-418 (2011).   DOI
19 S. W. Yu and H. J. Choi, Use of hybrid bead, tannin and chitosan, for treatment of Pb(II) from aqueous solution, KSWST J. Water Treat., 26(2), 53-64 (2018).   DOI
20 H. J. Choi, S. W. Yu, and K. H. Kim, Efficient use of Mg-modified zeolite in the treatment of aqueous solution contaminated with heavy metal toxic ions, J. Taiwan Inst. Chem. Eng., 63, 482-489 (2016).   DOI
21 G. Z. Kyzas, Commercial coffee wastes as materials for adsorption of heavy metals from aqueous solutions, Materials, 5, 1826-1840 (2012).   DOI
22 H. J. Choi and S. M. Lee, Heavy metal removal in the acid mine drainage using calcined eggshells and microalgae hybrid system, Environ. Sci. Pollut. Res., 22(17), 13404-13411 (2015).   DOI
23 J. Goel, K. Kadirvelu, C. Rajagopal, Kumar, and V. Garg, Removal of lead(II) by adsorption using treated granular activated carbon: batch and column studies, J. Hazard. Mater., 125(1), 211-220 (2005).   DOI
24 Z. Guo, J. Zhang, Y. Kang, and H. Liu, Rapid and efficient removal of Pb(II) from aqueous solutions using biomass-derived activated carbon with humic acid in-situ modification, Ecotoxicol. Environ. Saf., 145, 442-448 (2017).   DOI
25 B. G. Alhogbi, Potential of coffee husk biomass waste for the adsorption of Pb(II) ion from aqueous solutions, Sustain Chem. Pharm., 6, 21-25 (2017).   DOI
26 S. Y. Lee and H. J. Choi, Persimmon leaf bio-waste for adsorptive removal of heavy metals from aqueous solution, J. Environ. Manag., 209, 382-392 (2018).   DOI
27 A. S. Franca, L. S. Oliveira, and M. E. Ferreira, Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds, Desalination, 249(1), 267-272 (2009).   DOI
28 V. Boonamnuayvitaya, C. Chaiya, W. Tanthapanichakoon, and S. Jarudilokkul, Removal of heavy metals by adsorbent prepared from pyrolyzed coffee residues and clay, Sep. Purif. Technol., 35, 11-22 (2004).   DOI
29 N. Azouaou, Z. Sadaoui, A. Djaafri, and H. Mokaddem, Adsorption of cadmium from aqueous solution onto untreated coffee grounds: Equilibrium, kinetics and thermodynamics, J. Hazard. Mater., 184(1-3), 126-134 (2010).   DOI