• Journal of the Korean Society of Food Science and Nutrition
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• v.42 no.11
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• pp.1886-1891
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• 2013

To inactivate the microorganisms on the surface of blueberries after harvest and to secure microbial safety, a bubble-aqueous chlorine dioxide washing system was developed. After treating the freshly prepared blueberries with the bubble-aqueous chlorine dioxide washing system, the changes in the microbial populations and quality of the blueberries were determined during storage $4{\pm}1^{\circ}C$. Microbiological data indicated that the populations of total aerobic bacteria, yeast and mold decreased by 1.4 and 1.3 log CFU/g at the treatment of 20 ppm aqueous chlorine dioxide with the system, respectively. There was no significant difference in color change and weight loss during storage among treatments. In addition, this washing system could handle approximately 60 kg of blueberry per hour, resulting in labor-saving. Therefore, these results clearly suggest that the bubble-aqueous chlorine dioxide washing system could be useful in improving the microbiological safety of fresh blueberries after harvest.

• Journal of Bio-Environment Control
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• v.28 no.3
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• pp.197-203
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• 2019

This study was carried out to investigate the effect of chlorine water and plasma gas treatment on the quality and microbial control of Latuca indica L. baby Leaf during storage. Latuca indica L. baby leaves were harvested from a plant height of 10cm. They were sterilized with $100{\mu}L{\cdot}L^{-1}$ chlorine water and plasma-gas (1, 3, and 6hours), and packaged with $1,300cc{\cdot}m^{-2}{\cdot}day^{-1}{\cdot}atm^{-1}$ films and then stored at $8{\pm}1^{\circ}C$ and RH $85{\pm}5%$ for 25days. During storage, the fresh weight loss of all treatments were less than 1.0%, and the carbon dioxide and oxygen concentrations in packages were 6-8% and 16-17%, respectively for all treatments in the final storage day. The concentration of ethylene in the packages fluctuated between $1-3{\mu}L{\cdot}L^{-1}$ during the storage and the highest concentration of ethylene was observed at 6 hours plasma treatment in the final storage day. The off-odor of all treatments were almost odorless, the treatments of chlorine water and 1 hour plasma maintained the marketable visual quality until the end of storage. Chlorophyll content and Hue angle value measured at the final storage day were similar to those measured before storage in chlorine water and 1 hour of plasma treatments. E. coli was not detected immediately after sterilization in all sterilization treatments. After 6 hours of plasma treatment, the total bacteria fungus counts were lower than the domestic microbial standard for agricultural product in all sterilization treatments. The total aerobic counts in the end storage day increased compared to before storage, whereas E. coli was not detected in all sterilization treatments. The sterilization effect against bacteria and fungi was the best in chlorine water treatment. Plasma treatment showed sterilization effects, but within a prolonged period of time. In addition, the sterilization effect decreased gradually. These results suggest that chlorine water and plasma treatment were effective in maintaining Latuca indica L. baby Leaf commerciality and controlling microorganisms during postharvest storage.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2524-2527
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• 2007

Solid propellant gas generators (SPGG) play a role as a turbopump starter in liquid propellant propulsion systems by supplying pressurized gas to power turbines for engine start. For such a purpose, the propellants should burn with a relative low flame temperature and the combustion gas should not contain corrosive constituents such as chlorine compounds. In accordance with these requirements, stabilized AN-based propellants have been usually used as the most appropriate oxidizer for propellant compositions. However, the burning area of the propellant intends to increase to satisfy the required mass flux because of its low burning rate. Consequently the burning area incensement brings on the SPGG size augmentation. A flow restriction such as filters is applied to decrease the SPGG size by rising up the combustion pressure resulting in increasing the burning rate. The feasibility of the size reduction of SPGG by the employment of filters have been studied. The preliminary results of this study show that the considerable reduction of SPGG size would be achievable just by installing a filter with relatively high pressure loss coefficient.

• Asian Journal of Atmospheric Environment
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• v.3 no.1
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• pp.27-41
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• 2009

Internally mixed states of submicron particles during transport from the Asian continent to the Pacific Ocean were analyzed using a single-particle time-offlight mass spectrometer. The observation was conducted at Tsukuba in Japan in the spring of 2005 in order to investigate springtime transport of particles from the continent. The sum of ion intensities of sulfate (${HSO_4}^-$) detected in particles originating from the continental air masses counted for 75% of that in all particles during the observation. By analyzing correlations among compounds, origins and internally mixed states of compounds were estimated. It was found that nitrate was mixed with sulfate-rich particles as the air mass approached Japan. It was confirmed that Asian mineral dust particles played significant roles for transport of continental sulfate to Japan. As a result of analysis on internal mixing of chlorine and nitrate, it was implied that the chlorine loss in fine sea salt particles had already proceeded at Tsukuba. It was characteristic that fluoride ions were significantly detected, coal combustion in the Asian Continent can be an important source of fluorides detected in Japan through the westward transportation of fine particles including fluorides.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.8
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• pp.4713-4716
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• 2014

Several methods that have been used to manage a degasing process in recent years, such as an injection method that uses aluminum molten metal powder and chemicals, and the input method that supplies argon and nitrogen, or chlorine gas using a gas blow-tube. On the other hand, these methods have some problems, and it is a difficult process to handle pollution due to the production of considerable toxic gases, such as chlorine and fluoride gas, irregular effects, and lowering work efficiency due to the excessive processing time. The problems that are most fatal are the production of considerable sludge due to a reaction of aluminum molten metal with chemicals, loss of metals, and the decreasing life of refractory materials. To solve these problems, this study developed a technology that is related to continuous casting of molten aluminum metal and monolithic degasing apparatus.

• Journal of Power System Engineering
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• v.22 no.1
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• pp.79-86
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• 2018

Many countries have conducted extensive studies for biomass co-firing to enhance the durability of reactor on high-temperature corrosion. However, due to the complicated mechanisms of biomass co-firing, there have been limitations in accurately determining the current state of corrosion and predicting the potential risk of corrosion of power plant. In order to solve this issue, this study introduced Lab-scale corrosion system to analyze the corrosion characteristics of the A213 T91 material under the biomass co-firing conditions. The corrosion status of the samples was characterized using SEM/EDS analysis and mass loss measurement according to various biomass co-firing conditions such as corrosion temperature, $SO_2$ concentration, and corrosion time. As a result, the corrosion severity of A213 T91 material was gradually increased with the increase of $SO_2$ concentration in the reactor. When $SO_2$ concentration was changed from 0 ppm to 500 ppm, both corrosion severity and oxide layer thickness were proportionally increased by 15% and 130%, respectively. The minimum corrosion was observed when the corrosion temperature was $450^{\circ}C$. As the temperature was increased up to $650^{\circ}C$, the faster corrosion behavior of A213 T91 was observed. A213 T91 was observed to be more severely corroded by the effect of chlorine, resulting in faster corrosion rate and thicker oxide layer. Interestingly, corrosion resistance of A213 T91 tended to gradually decrease rather than increases as the oxide layer was formed. The results of this study is expected to provide necessary research data on boiler corrosion in biomass co-firing power plants.

• Korean Journal of Agricultural Science
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• v.47 no.3
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• pp.415-424
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• 2020

This study investigated the effects of an ethylene scrubber (ES) with a micro-perforated polypropylene (MP-PP, 30 ㎛) or a high density polyethylene (MP-HDPE, 30 ㎛) film liner for the export carton packaging box in 'Campbell Early' grapes. Rachis browning was highest in the untreated group, followed by MP-PP and MP-HDPE for 14 days of simulated marketing at 20℃. The combination treatment of ES with the film liners showed a partial inhibition of the rachis browning regardless of the film liners. The effects of an alcohol releaser (AR) sachet or chlorine dioxide (CD) diffuser co-packaging were also investigated in the 'Campbell Early' grapes packed with the MP-HDPE (40 × 99 pin hole·m^-2) film liner. The CD 1 g treatment showed a very limited weight loss of 1.1%, which was significantly lower than the 4.7% of the untreated control after 14 days of simulation marketing at 20℃. The berry shatter was 0.7% for the MP-HDPE + CD 1 g treatment and 1.8% for the MP-HDPE + CD 5 g treatment on the 10th day of the simulated marketing, which was significantly lower than the 8.9% of the control. The stem browning was significant suppressed until the 10th day of the simulated marketing. In particular, the CD 1 g treatment in combination with the MP-HDPE showed a low rachis and pedicel browning index of 2.0, which is 50% and 40% lower than that of the untreated control and the MP-HDPE single treatment, respectively. In addition, the CD 1 g treatment group showed a higher decay reduction effect than the CD 5 g treatment group, which caused high concentration damage.

• The Korean Journal of Food And Nutrition
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• v.35 no.4
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• pp.247-252
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• 2022

To improve the shelf-life of Centella asiatica, Centella asiatica was treated with gel packs containing slow-released chlorine dioxide (ClO₂) gas at 3-5 ppm for 20 days at 4℃. The weight loss rate, as well as the changes in pH, color, and texture of the treated samples, were investigated. The weight of the control and ClO₂ gas-treated samples was decreased during the storage period. The change in weight of the control was slightly faster than that of the samples treated with 3 and 4 ppm ClO₂ gas. The pH of the control and the ClO₂ gas treated samples were decreased during the storage period and there was no significant difference between the control and ClO₂ gas treated samples. Concerning color (lightness, redness, and yellowness) changes of Centella asiatica during the storage period, there was no significant difference between the control and ClO₂ gas treated samples. The change in shear force in the leaf and stem of Centella asiatica during the storage period was slightly lower in the 4 ppm ClO₂ gas treated samples (in the leaf) compared to the control and 3 and 4 ppm ClO₂ gas treated samples (in the stem) compared to the control and 5 ppm ClO₂ gas treated sample.

• Macromolecular Research
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• v.8 no.3
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• pp.142-146
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• 2000

Hyperbranched poly(ether sulfone) analogs with the 1,3,5-s-triazine moiety were prepared by the direct polymerization of AB$_2$type monomer, 2,4-bis(4-hydroxyphenyl)-6-(4-(4-(4-fluorobenzenesulfonyl)phenoxy)phenyl)-1,3,5-s-triazine (3). The selective reactivity of three chlorine atoms on cyanuric chloride toward nucleophiles provides an efficient route for the systematic synthesis of AB$_2$type triazine monomers and their hyperbranched polymers. The triazine rings influenced the structural and material characteristics of these hyperbranched polymers. The hyperbranched poly(ether sulfone) analog4 showed a glass transition at 295$^{\circ}C$. and was soluble in THF, 1,4-dioxane, and DMSO. An excellent thermal stability of polymer 4 was exhibited by a TGA analysis, which showed that 5% weight loss occurred at 480$^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• v.13 no.1
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• pp.83-87
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• 1992

The ring expansion of 1,3-thiazolidines 4 derived from ${\beta}$-ketoacid derivatives to the corresponding dihydro-1,4-thiazines 1 by using the action of chlorine on 4 has been achieved. In the chlorinolysis unisolable sulfenyl chlorides 5 may be formed from chlorosulfonium ions 11 by ${\beta}$-elimination involving carbonyl activated methylene hydrogens. Addition of sulfenyl chloride to the internal double bond appears to form probable thiiranium ions 14, which in turn gave 1 with loss of acidic proton. Imminium ions 15 could be hydrolyzed easily to give enol 8. As a side reaction, dihydrothiazine that was formed was further chlorinated to produce dichlorides 16 which were rearranged readily to the chloromethyl compounds 10.