• Title/Summary/Keyword: Chloride migration

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Characteristic of Chloride Ion Diffusion in Concrete Containing GGBF (고로슬래그미분말 혼합 콘크리트의 염소이온 확산특성)

  • 문한영;김홍삼;김진철;최두선
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.793-796
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    • 2001
  • Physical properties of concrete, Such as, compressive strength, permeable pore and penetration depth of chloride ion were investigated. And to investigate the effect of containing GGBF in concrete, the diffusion coefficient of chloride was measured through an electro- migration test. The diffusion coefficient of chloride was decreased with increase of replacement ratios of GGBF when compared to OPC. Relation coefficients between physical properties of concrete and diffusion coefficient of chloride were more than 0.9.

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Effect of Micro-Cracks on Chloride Ions Penetration of Concrete II: Examination of Critical Crack Width (미세균열이 콘크리트의 염소이온 침투에 미치는영향 II: 임계 균열폭의 고찰)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.6
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    • pp.707-715
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    • 2007
  • The vulnerability of concrete to its environment is significantly dependent on the fact that concrete is a porous material. For well-consolidated and well-cured concrete, its service life is a very long and an entrance of aggressive substance might be only pores. However, for cracked concrete, cracks should be preferential channel for the penetration of aggressive substance such as chloride ions. The effect of crack on chloride penetration depends on its size for example, crack width and crack depth. The purpose of this study is examining the effect of crack width and crack depth on chloride penetration. In order to visualize chloride penetration via cracks, RCM (rapid chloride migration) testing is accomplished. Crack width is examined using an optical microscope and CMOD value is used to estimate average crack width. From the examination on the trend of chloride diffusion coefficients of concrete specimens with various crack widths, a critical crack width and a critical crack depth are found out.

An Experimental Study on the Chloride Attack Resistibility of Alkali-Activated Ternary Blended Cement Concrete (알칼리 활성화 3성분계 혼합시멘트의 염해 저항성에 관한 실험적 연구)

  • Yang, Wan-Hee;Hwang, Ji-Soon;Jeon, Chan-Soo;Lee, Sea-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.321-329
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    • 2016
  • The use of ternary blended cement consisting of Portland cement, granulated blast-furnace slag (GGBFS) and fly ash has been on the rise to improve marine concrete structure's resistance to chloride attack. Therefore, this study attempted to investigate changes in chloride attack resistibility of concrete through NT Build 492-based chloride migration experiments and test of concrete's ability to resist chloride ion penetration under ASTM C 1202(KS F 2271) when 1.5-2.0% of alkali-sulfate activator (modified alkali sulfate type) was added to the ternary blended cement mixtures (40% ordinary Portland cement + 40% GGBFS + 20% fly ash). Then, the results found the followings: Even though the slump for the plain concrete slightly declined depending on the use of the alkali-sulfate activator, compressive strength from day 2 to day 7 improved by 17-42%. In addition, the coefficient from non-steady-state migration experiments for the plain concrete measured at day 28 decreased by 36-56% depending on the use of alkali-sulfate. Furthermore, total charge passed according to the test for electrical indication of concrete's ability to resist chloride ion penetration decreased by 33-62% at day 7 and by 31-48% at day 28. As confirmed in previous studies, reactivity in the GGBFS and fly ash improved because of alkali activation. As a result, concrete strength increased due to reduced total porosity.

A Study for the Accelerated Chloride Diffusion Test of Concrete (콘크리트의 촉진염소이온 확산 시험법에 관한 연구)

  • 이용은;김진철;이찬영
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.427-432
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    • 1999
  • An electrci method for the rapid determination of chloride diffusion coefficient in concrete is proposed considering the electrical migration term in the Nernst-Plank equation. The experimental set-up for this method is basically that for PD index by Dhir, excluding some change in the experimental parameter values in consideration of reliability, simplicity and rapidity of the accelerated test method. Experimental results show that 30mm of specimen thickness, 10 volt of supplied potential, and 5M of chloride ion concentration are optimal

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Research on chloride ion diffusivity of concrete subjected to CO2 environment

  • Zhang, Shiping;Zhao, Binghua
    • Computers and Concrete
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    • v.10 no.3
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    • pp.219-229
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    • 2012
  • Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

Material Characteristics of High-Strength Concrete Incorporating High Replacement Level of Blast-Furnace Slag (고로슬래그를 다량 함유한 고강도 콘크리트의 재료적 특성)

  • Lee, Hoi-Keun;Jung, Jae-Hong;Kim, Han-Joon;Lee, Seung-Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.291-292
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    • 2010
  • In this study, high-strength concrete mixtures were made with blast-furnace slag of 50% and 70% replacement level to evaluate material properties including compressive strength development, adiabatic temperature rise, autogenous shrinkage and chloride-ion migration coefficient. Test results showed that the use of high percentage blast-furnace slag in high-strength concrete can reduce heat of hydration and chloride-ion migration coefficient, result in control thermal cracking and improve durability performance especially under high corrosive environment.

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Evaluation of Fiber and Blast Furnace Slag Concrete Chloride Penetration through Computer Simulation

  • Kim, Dong-Hun;Petia, Staneva;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.4
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    • pp.379-386
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    • 2011
  • Durability of concrete is an important issue, and one of the most critical aspects affecting durability is chloride diffusivity. Factors such as water.cement ratio, degree of hydration, volume of the aggregates and their particle size distribution have a significant effect on chloride diffusivity in concrete. The use of polypropylene fibers(particularly very fine and well dispersed micro fibers) or mineral additives has been shown to cause a reduction in concrete's permeability. The main objective of this study is to evaluate the manner in which the inclusion of fiber(in terms of volume and size) and blast furnace slag(BFS) (in terms of volume replacement of cement) influence the chloride diffusivity in concrete by applying 3D computer modeling for the composite structure and performing a simulation of the chloride penetration. The modeled parameters, i.e. chloride diffusivity in concrete, are compared to the experimental data obtained in a parallel chloride migration test experiment with the same concrete mixtures. A good agreement of the same order is found between multi.scale microstructure model, and through this chloride diffusivity in concrete was predicted with results similar to those experimentally measured.

Studies on the Analysis of DOA in PVC Wrap Film and its Migration into Foodstuffs (염화비닐 랩 필름의 DOA 분석 및 식품에의 이행에 관한 연구)

  • Lee, Keun-Taik;Gyoung, Young-Soo;Park, Tae-Kyu
    • Korean Journal of Food Science and Technology
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    • v.22 no.2
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    • pp.145-149
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    • 1990
  • Extraction and analysis conditions of di-(2-ethylhexyl) adipate (DOA) and its migration contents into foods wrapped with plasticized polyvinyl chloride (PVC) film during storage and cooking with microwave were examined using gas chromatography. Experiments on the extraction solvent and method showed that the method of reflux using carbon tetrachloride for longer than one hour allowed the highest extraction of DOA. Analysis of four PVC wrap films from different factories in domestic market showed the DOA contents of 18.9% for home-use and 24.6% for retail-use on the average. The highest migration during storage was observed in pork belly, which were 21% and 26% after one and three days respectively. During microwave cooking; smaller than 5.5% of DOA were migrated into foods when the film was not contacted with foods, whereas about 49% migration was observed in pork belly contacted with film directly.

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Comparision of Test Methods for Estimating Chloride Ion Diffusion Coefficient in Concrete (콘크리트중의 염소이온 확산계수 추정 실험법의 비교)

  • 문한영;김홍삼;문재흠;한아름
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.787-790
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    • 1999
  • To estimate durability of reinforced concrete structures located in or nearby seawater, many different kinds of accelerated tests for evaluation of chloride ion permeation in concrete were proposed. At present the only standardized test is the ASTM C 1202(RCP test). This test method is used to estimate the concrete's resistivity of the chloride penetration in concrete by using the total charges passed and sometimes used to calculate the chloride diffusion coefficients. However, this test may lead to an erroneous chloride diffusion coefficient. So this test method was compared with the modified Dhir's test and the traditional concentration diffusion test. Experimental results showed that the diffusion coefficients determined the RCP test and the PD Index gave wrongous values, but the diffusion coefficient acquired by considering a migration term was nearly the same to the CD Test.

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