• Title/Summary/Keyword: Chloride Ion Penetration

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Applicability of Colormetric Method for Estimation of Chloride Penetration in Concrete Structures (콘크리트 구조물의 염화물 침투 특성 파악을 위한 변색법의 적용성)

  • Yang Eun-Ik;Kim Myung-Yu;Leem Young-Moon;Park Hae-Geun
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.931-938
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    • 2005
  • When concrete structures are exposed under marine condition for a long time, the steel in concrete is corroded due to the ingression of chlorides in the seawater. Because the damages of corrosion resulting from the chloride ion are very serious, many researches have been performed. Silver nitrate colormetric method that can measure easily penetration depth of chloride ion has been executed, recent)y. However, characteristics of silver nitrate colormetric method were not fully examined. Therefore, the objective of this paper Is to study the applicability of colormetric method. For the purpose of this, effect factors and reaction mechanism of colormetric method were investigated, and the colormetric method is applied for marine concrete structures. According to the results of silver nitrate colored method, two reactions such as white reaction of AgCl and brown reaction of AgOH were shown when $AgNO_3$ was sprayed in splited section. And velocity constant ratio(K) of two reactions appeared that white reaction, AgCl reacts with the fast speed by 3240. When the colormetric method was applied in concrete, it is reasonable that $AgNO_3$ solution more than 0.05N concentration was sprayed. It is confirmed that the colormetric method is useful tool for estimating the chloride of concrete structures in situ. The average chloride amount of colored parts indicates $0.9kg/m^3$ per concrete unit weight.

Effects of Combined Attacks on Chloride Diffusivity in Concrete (콘크리트내의 염소이온 침투특성에 미치는 복합 열화작용의 영향)

  • 오병환;강의영;정상화;장승엽;인광진;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.665-670
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    • 2001
  • The studies on chloride diffusion of concrete have been done so far by many researchers. However, there are few studies that present the effects of other attacks on chloride diffusion properties. Therefore, in this study the experiments are carried out to show the effects of combined attacks, such as carbonation, sulfate attacks, on chloride diffusivity in concrete. The specimens are made by varying cement type and replacement ratio of fly ash. The results show that cement type and replacement of fly ash do not affect greatly chloride diffusion properties. And concrete treated by combined attacks show a little higher chloride content than those treated by chloride solution only. Therefore, the effects of these factors should be taken into account in predicting the penetration of chloride ion in concrete.

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Experimental Study on Deterioration Characteristics under Combined Exposure Conditions of Chlorides and Sulfates (염화물 및 황산염 복합환경 하에서의 열화특성에 관한 실험적 연구)

  • 오병환;인광진;강의영;김지상;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.771-776
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    • 2001
  • Test results on the deterioration process of concrete under single and combined attacks of chloride penetration have been obtained. After test period of 52 weeks, it is found that the internally penetrated chloride ion contents are less in the single attacks of chloride than the combined attacks of chloride and sulfate. Both the diffusion coefficients and surface chloride concentration derived form the chloride profiles showed a time dependence. Also the performance of fly ash-blended cements was observed to be better than plain cements in retarding chloride attack. However it should be needed that improved chloride diffusion model for the combined deterioration process.

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Application of Corrosion Inhibitors to Protect the Corrosion of Reinforcement in Concrete (콘크리트 중의 철근방식을 위한 방청제의 적용)

  • 문한영;김성수;김홍삼;안기용
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.751-754
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    • 1999
  • Corrosion inhibitors are widely used to protect chloride-induced corrosion of reinforcement in concrete. However, the number of researches on the corrosion of reinforcement, when corrosion inhibitor is used, is not enough for actual application in the field. In addition, on corrosion of reinforcement a quantitative standard about corrosion inhibitor does not exist and the data about its influencing concrete are relatively rare. In this study, the effectiveness of rebar corrosion protection, setting time, compressive strength, chloride ion's penetration, and diffusion test were performed using with three different kinds of corrosion inhibitors.

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Effects of Carbonation on Chloride Diffusion Properties of Concrete (중성화가 콘크리트의 염소이온 확산특성에 미치는 영향에 관한 실험연구)

  • 오병환;강의영;정상화;김선우;서정문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.429-432
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    • 2000
  • The studies on chloride diffusion of concrete have been done so far by many researchers. However, there are few studies on the effects of other attacks, like carbonation, on chloride diffusion properties. In this study, the experiments are carried out focusing on this by varying cement type, water to cement ratio and replacement of fly ash of concrete. The results show that carbonation attacks do not affect greatly chloride diffusion properties of plain concrete, while the different tendencies are exhibited for fly ash concrete. Therefore, it is desirable to consider the effects of carbonation attacks on the chloride diffusion model to predict accurately the penetration of chloride ion fly ash is partially replaced for cement.

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Evaluation of Chloride Attack Resistibility of Heavyweight Concrete Using Copper Slag and Magnetite as Aggregate (동슬래그 및 자철석을 골재로 사용한 중량 콘크리트의 회파블록 적용을 위한 염해저항성 평가)

  • Moon, Hoon;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.6
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    • pp.483-492
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    • 2017
  • Recently, the coastal area has become the popular place for infrastructure development. To provide a beautiful scenary of costal area to nearby facilities without any hinderance, and also to protect those facilities from the sea water overflow, it is necessary to develop a new type of wave dissipating block, which is a turning wave block. It is noticeable that the top of the turning wave block is flat and thus can provide spaces for various purposes. However, the unit weight of the block decreases due to the presence of pipeline that is installed for turning the direction of the waves. In order to mitigate such problem, a heavyweight concrete needs to be used to increase the resistance against tidal waves. The copper slag and magnetite were used as a source of fine and coarse aggregate, respectively. The 28 day compressive strength of concrete incorporating ordinary and heavyweight aggregate did not show significant differences. It should be noted that the chloride ion penetration resistance was evaluated using NT-BUILD 492 rather than ASTM C 1202 method because concrete incorporating magnetite as a coarse aggregate showed excessive current flow by ASTM C 1202 method. According to the results from NT Build 492 method, which uses the penetration depth of chlorine ions to obtain chloride ion diffusivity, the heavyweight concrete incorporating the copper slag and the magnetite showed the best resistance against the chloride ion penetration. Therefore, it is reasonable to say that heavyweight concrete made with copper slag and magnetite can be used for production of turning wave block.

Durability characteristics of recycled aggregate concrete

  • Saravanakumar, Palaniraj;Dhinakaran, Govindasamy
    • Structural Engineering and Mechanics
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    • v.47 no.5
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    • pp.701-711
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    • 2013
  • People started to replace natural aggregate with recycled aggregate for a number of years due to disposal problem and certain other potential benefits. Though there are number of drawbacks with use of recycled aggregates like lesser modulus of elasticity, low compressive strength, increase in shrinkage, there are results of earlier studies that use of chemical and mineral admixtures improves the strength and durability of recycled concrete. The use of recycled aggregate from construction and demolition wastes is showing prospective application in construction as alternative to natural aggregates. It conserves lot of natural resources and reduces the space required for the landfill disposal. In the present research work, the effect of recycled aggregate on strength and durability aspects of concrete is studied. Grade of concrete chosen for the present work is M50 (with a characteristic compressive strength of 50 MPa). The recycled aggregates were collected from demolished structure with 20 years of age. Natural Aggregate (NA) was replaced with Recycled Aggregate (RA) in different percentages such as 25, 50 and 100 to understand its effect. The experiments were conducted for different ages of concrete such as 7, 14, 28, 56 days to assess the compressive and tensile strength. Durability characteristics of recycled aggregate concrete were studied with Rapid chloride penetration test (as per ASTMC1202), sorptivity test and acid test to assess resistance against chloride ion penetration, capillary suction and chemical attack respectively. Mix design for 50 MPa gives around 35 MPa after replacing natural aggregate with recycled aggregate in concrete mix and the chloride penetration range also lies in moderate limit. Hence it is understood from the results that replacement of NA with RA is very much possible and will be ecofriendly.

The Evaluation of Resistance of Multi-degregation on Concrete Coated High Performance Penetration Agency (고성능 표면침투제가 도포된 콘크리트의 복합열화저항성 평가)

  • Yoo, Sung-Won;Suh, Jeong-In;Ha, Hyun-Jae;Lee, Sang-Min;Park, Sang-Sun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.241-244
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    • 2004
  • The evaluation of Single or multi-degregation of concrete coated by high performance surface penetration agency was examined through various tests, i.e., carbonation, absorption, carbonation + chloride ion and carbonation + chemical solution according to various high performance surface penetration agencies and various compressive strengths of base concrete. The 2 types of high performance surface penetration agencies were used i.e., inorganic and alcohol soluble. And 2 types of compressive strength of base concrete were used such as 21 30. MPa. The characteristics of concrete coated high performance surface penetration agency was more improved than that of non-coated concrete, and especially, water soluble inorganic agency was most effective. And if compressive strength of base concrete was low, the improved effects would be larger.

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Performance Evaluation of Natural Jute Fiber Reinforced Recycled Coarse Aggregate Concrete Using Response Surface Method (반응표면 분석법을 이용한 천연마섬유보강 순환굵은골재 콘크리트의 성능 평가)

  • Jeon, Ji Hong;Kim, Hwang Hee;Kim, Chun Soo;Yoo, Sung Yeol;Park, Chan Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.4
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    • pp.21-28
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    • 2014
  • In this study, evaluated ware the strength and durability of the vegetated water purification channel concrete to which recycled aggregates, hawang-toh and jute were applied. Box-Behnken method of response surface analysis in statistics was applied to the experimental design. Experimental variables are as follows, recycled coarse aggregates, hawang-toh, blast-furnace slag and jute fiber. In the experiment, conducted were the tests of compressive strength, chloride ion penetration, abrasion resistance and impact resistance the replacement rate effects of the recycled aggregates, blast-furnace slag and hwang-toh on the performance of vegetated water purification channel concrete were analyzed by using the response surface analysis method on the basis of the experimental results. In addition, an optimum mixing ratio of vegetated water purification channel concrete was determined by using the experimental results. The optimum mixing ratio was determined to be in 10.0% recycled coarse aggregates, 60.0% blast-furnace slag, 10.1% hwang-toh and 0.16% jute fiber. The compressive strength, chloride ion penetration, abrasion rate, and impact number of fracture test results of the optimum mixing ratio were 24.1 MPa, 999 coulombs, 10.30 g/mm3, and 20 number, respectively.

Fundamental Study on Optimum Mixing Proportion of Cement Concrete Pavement using Recycled Aggregate (순환골재를 활용한 포장용 시멘트콘크리트의 최적배합 도출을 위한 기초 연구)

  • Kim, Sueng Won;Kim, Yong Jae;Lee, Jang Yong;Lee, Hak Yong;Park, Cheol Woo
    • International Journal of Highway Engineering
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    • v.18 no.6
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    • pp.105-113
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    • 2016
  • OBJECTIVES : This study is to develop the optimum mixing proportions for cement concrete pavement with using recycled aggregates. METHODS : The mixture varied recycled coarse aggregates content from 50 % to 100 % to replace the natural coarse aggregates by weight. Tests for fundamental properties as a cement concrete pavement were conducted before and after hardening of the concrete. RESULTS : It was found that the variation in the amount of the recycled aggregate affected the compressive and flexural strength development, as well as the chloride ion penetration resistance. As the amount of the recycled aggregate content increased the compressive and flexural strength and the resistance to chloride ion penetration decreased. However, the resistance to freeze-thaw reaction was affected significantly. In addition, the gradation of the aggregate became worse and hence so did the coarseness factor as the recycled aggregate amount increased. CONCLUSIONS : The fundamental properties of the concrete with recycled aggregate does not seem to be appropriate when the recycled aggregate quality is not guaranteed up to a some level and its replacement ratio is over 50%. The optimized gradation of the aggregates should also be sought when the recycled aggregate is used for the cement concrete pavement materials.