• Title/Summary/Keyword: Chloride Ion Diffusion

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Temperature-dependent Diffusion Coefficient of Chloride Ion in UAE Concrete (UAE 콘크리트에 대한 염화물 확산의 온도의존성)

  • Ji-Won Hwang;Seung-Jun Kwon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.28 no.4
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    • pp.48-54
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    • 2024
  • NPP (Nuclear power plant) structures have been constructed near to the sea shore line for cooling water and exposed to steel corrosion due to chloride attack. Regarding NPP structures built in the UAE, chloride transport may be more rapid than those in the other regions since the temperature near to the coast is high. In this study, concrete samples with 5,000psi (35MPa) design strength grade were manufactured with the materials and mix proportions, which were the same as used in the UAE NPP structures, then chloride diffusion coefficients were evaluated considering temperature and curing age. The compressive strength and the diffusion coefficient were evaluated and analyzed for the samples with 28 and 91 curing days. In addition, chloride diffusion tests for 91-day-cured condition were carried out in the range of 20℃ to 50℃. The activation energy was obtained through converting the temperature slope to a logarithmic function and it was compared with the previous studies. The proposed activation energy can be useful for a reasonable durability design by using actual temperature-dependent chloride diffusion coefficient.

Diffusion Characteristics of Chloride ion under Single and Combined Attacks in Concrete Structures (콘크리트 구조물의 단일 및 복합열화 환경하에서의 염소이온 확산특성)

  • 오병환;강의영;인광진;이성규;서정문
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.708-717
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    • 2002
  • Durability is a major concern in the design and construction of concrete structures which are located in the sea environments. In particular, the combined action of chlorides, sulfates, and carbonation nay influence greatly the deterioration behavior of concrete structures. The purpose of the present study is to explore the diffusion characteristics of chloride ions in concrete structures under combined deterioration conditions. The present test results indicate that the chloride penetration into concrete structures is more pronounced under combined attacks of chlorides, sulfates and carbonation. The diffusion coefficients and surface chloride contents were found to increase under combined multiple deterioration conditions. The present study provides quantitatively the penetration and diffusion characteristics of chloride ions in concrete structures under various deterioration conditions. The results of present study may be efficiently used for the realistic design of concrete structures under combined deterioration conditions.

Analysis on Changes in Strength, Chloride Diffusion, and Passed Charges in Normal Concrete Considering Ages and Mix Proportions (재령 및 배합특성을 고려한 보통 콘크리트의 강도, 염화물 확산계수, 통과전하량 변화 분석)

  • Lee, Hack-Soo;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.1-7
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    • 2017
  • Concrete behavior in early-age is changing due to hydration reaction with time, and a resistance to chloride attack and strength development are different characterized. In the present work, changing strength and resistance to chloride attack are evaluated with ages from 28 days to 6 months. For the purpose, strength, diffusion coefficient, and passed charge are evaluated for normal concrete with 3 different mix proportions considering 28-day and 6-month curing conditions. With increasing concrete age, the changing ratio of strength falls on the level of 135.3~138.3%, while diffusion coefficient and passed charge shows 41.8%~51.1% and 53.6%~70.0%, respectively. The results of chloride diffusion coefficient and passed charge show relatively similar changing ratios since they are much dependent on the chloride migration velocity in electrical field. The changing ratios in chloride behaviors are evaluated to be much larger than those in compressive strength since the ion transport mechanism is proportional to not porosity but square of porosity.

The Effect of Chloride on the Corrosion of Reinforced Concrete (염화물이 철근콘크리트의 부식에 미치는 영향)

  • Kim, Jeong-Sup;Shin, Yong-Seok;Lee, Sul;Kim, Kwang-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.2
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    • pp.147-154
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    • 2005
  • It is found that as contents of chloride ion and age increase, area of corrosion also increases. Inare increased to 1035 days from 730 days, slope of increase of corrosion area is greatest. Non-rust inhibitor specimens show corrosion area of 8~35 times more than rust inhibitor specimens and anticorrosive effects by application of rust inhibitor can be confirmed. When chloride ion is not contained, corrosion control effects of steel reinforcing according to increase of thickness are found, but specimens having chloride ion show no regular tend of thickness and corrosion due to complex problems such as reverse diffusion of chloride and test errors.

Influence of Carbonation on the Chloride Diffusion in Concrete (탄산화 현상이 콘크리트 중의 염소이온 확산에 미치는 영향 연구)

  • Oh, Byung-Hwan;Lee, Sung-Kyu;Lee, Myung-Kue;Jung, Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.829-839
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    • 2003
  • Recently, the corrosion of reinforced concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation but the future studies for combined environment will assure the precise assessment.

Development and Application of Unit Table Form using Euro Form for High-rise Building Construction (슬래그 혼입 콘크리트의 염소이온 차단성능)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.136-137
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    • 2018
  • The properties of concrete produced by ready mixed concrete company in Busan were measured. Because the concrete was mixed with blast furnace slag and fly ash etc., the compressive, tensile strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design. FEM analysis was carried out to predict the life time expectancy.

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Chloride Ion Diffusion for Ready Mixed Concrete (설계기준 압축강도별 레미콘의 염소이온 확산 특성평가)

  • Park, Dong-Cheon;Kim, Yong-Ro
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.149-150
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    • 2018
  • The RC buildings which are constructed on the seaside are followed by KBC(2016) to achieve the minimization of durability damage. To control the corrosion of the reinforced steel bar by salt attack, W/C should be under 0.4 and specified concrete strength is more than 35MPa in the concrete/building construction standard specification. Ready mixed concretes which have usually include the admixtures in Busan were tested to certify the salt attack durability. In the same specified concrete strength, remarkable salt attack durability was evaluated in comparison to OPC.

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Numerical study of ITZ contribution on diffusion of chloride and induced rebar corrosion: A discussion of three-dimensional multiscale approach

  • Tu, Xi;Pang, Cunjun;Zhou, Xuhong;Chen, Airong
    • Computers and Concrete
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    • v.23 no.1
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    • pp.69-80
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    • 2019
  • Modeling approach for mesoscopic model of concrete depicting mass transportation and physicochemical reaction is important since there is growing demand for accuracy and computational efficiency of numerical simulation. Mesoscopic numerical simulation considering binder, aggregate and Interfacial Transition Zone (ITZ) generally produces huge number of DOFs, which is inapplicable for full structure. In this paper, a three-dimensional multiscale approach describing three-phase structure of concrete was discussed numerically. An effective approach generating random aggregate in polygon based on checking centroid distance was introduced. Moreover, ITZ elements were built by parallel expanding the surface of aggregates on inner side. By combining mesoscopic model including full-graded aggregate and macroscopic model, cases related to diffusivity and thickness of ITZ, volume fraction and grade of aggregate were studied regarding the consideration of multiscale compensation. Results clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of, rebar diameter, concrete cover and exposure period.

Resistance to Corrosion of Reinforcement of High Volume Fly Ash Concrete

  • Kwon, S.O.;Bae, S.H.;Lee, H.J.;Lee, K.M.;Jung, S.H.
    • Corrosion Science and Technology
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    • v.13 no.6
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    • pp.209-213
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    • 2014
  • Due to the increasing of interest about the eco-friendly concrete, it is increased to use concretes containing by-products of industry such as fly ash(FA), ground granulated blast furnace slag(GGBFS), silica fume(SF), and etc. Especially, these are well known for improving the resistances to reinforcement corrosion in concrete and decreasing chloride ion penetration. The purpose of this experimental research is to evaluate the resistance against corrosion of reinforcement of high volume fly ash(HVFA) concrete which is replaced with high volume fly ash for cement volume. For this purpose, the concrete test specimens were made for various strength level and replacement ratio of FA, and then the compressive strength and diffusion coefficient for chloride ion of them were measured for 28, 91, and 182 days, respectively. Also, corrosion monitoring by half cell potential method was carried out for the made lollypop concrete test specimens to detect the time of corrosion initiation for reinforcement in concrete. As a result, it was observed from the test results that the compressive strength of HVFA concrete was decreased with increasing replacement ratio of FA but long-term resistances against reinforcement corrosion and chloride ion penetration of that were increased.

Chloride Diffusion Coefficients in Cold Joint Concrete with GGBFS (고로슬래그 미분말을 혼입한 콜드조인트 콘크리트의 염화물 확산계수)

  • Oh, Kyeong-Seok;Mun, Jin-Man;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.44-49
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    • 2016
  • Among the deteriorating agents, chloride ion is reported to be one of the most harmful ions due to its rapid diffusion and direct effect on steel corrosion. Cold joint which occurs in mass concrete placing is vulnerable to shear resistance and more severe deterioration. The paper presents an quantitative evaluation of chloride diffusion coefficient in OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag) concrete containing cold joint. GGBFS concrete shows $6.6{\times}10^{-12}m^2/sec$ which is almost 30% level of OPC concrete results and the trend is repeated in the case of cold joint concrete. Compared with OPC concrete, GGBFS concrete is evaluated to have better resistance to chloride penetration, showing 0.30 times of chloride diffusion coefficient in concrete without cold joint 0.39 times with cold joint, respectively.