• Bulletin of the Korean Chemical Society
• /
• v.32 no.spc8
• /
• pp.2891-2892
• /
• 2011

• 한국전기화학회:학술대회논문집
• /
• 2002.04a
• /
• pp.27-27
• /
• 2002

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.11 no.1
• /
• pp.32-52
• /
• 1985

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 1998.05a
• /
• pp.86-86
• /
• 1998

• Bulletin of the Korean Chemical Society
• /
• v.17 no.10
• /
• pp.949-951
• /
• 1996

• Journal of Environmental Science International
• /
• v.14 no.10
• /
• pp.919-928
• /
• 2005

This study introduces the development of new supercritical water oxidation(SCW)(multiple step oxidation) to destruct recalcitrant organic substances totally and safely by using sodium nitrate as an oxidant. This method has solved the problems of conventional SCW, such as precipitation of salt due to lowered permittivity, pressure increase following rapid rise of reaction temperature, and corrosion of reactor due to the generation of strong acid. Destruction condition and rate in the supercritical water were examined using Polyvinyl Chloride(PVC) and ion exchange resins as organic substances. The experiment was carried out at $450^{\circ}C$ for 30min, which is relatively lower than the temperature for supercritical water oxidation $(600-650^{\circ}C)$. The decomposition rates of various incombustible organic substances were very high [PVC$(87.5\%)$, Anion exchange resin$(98.6\%)$, Cationexchange resin$(98.0\%)$]. It was observed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium (salt formation). However, relatively large amount of sodium nitrate (4 equivalent) was required to raise the decomposition ratio. For complete oxidation of PCB was intended, the amount of oxidizer was an important parameter.

• YAKHAK HOEJI
• /
• v.34 no.3
• /
• pp.215-218
• /
• 1990

An ion chromatographic method based on indirect photometric detection of UV transparent anions was developed. Separation of anion was accomplished on strong anion exchange column (Waters SAX) using UV detector at 254 nm. Among examined UV-active additives (Dns-H, Dns-glu, Dnsser, Dns-val), Dns-glu showed the highest sensitivity. Studies on the effects of the pH and ionic strength of eluent revealed that the increase of pH and ionic strength of the eluent decreased capacity factor. The best eluent for the separation of acetate, fluoride, chloride, nitrate and bromide was $1\;{\times}\;10^{-4}M$ Dns-glu in 5 mM phosphate buffer (pH 6.30). The detection limit of chloride ion was 2.1 ng in this condition.

• Bulletin of the Korean Chemical Society
• /
• v.26 no.1
• /
• pp.51-56
• /
• 2005

A PVC membrane electrode for lead ion based on 1-phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone (PQDBP) as ionophore was demonstrated. The optimum composition of the membrane was 30 wt% poly(vinyl chloride), 60 wt% dibutyl phthalate as a plasticizer, 4 wt% ionophore and 6 wt% sodium tetraphenylborate as additive. The electrode exhibits a Nernstian response (28.7 mV decade$^{-1}$) for Pb$^{2+}$ over a wide concentration range (1.0 ${\times}$ 10$^{-1}$ to 1 ${\times}$ 10$^{-6}$ M) with a detection limit of 6.0 ${\times}$ 10$^{-7}$ M. This sensor has a short response time and can be used for at least 2 months without any divergence in potentials. The proposed electrode could be used in a pH range of 3.0-6.0 and revealed good selectivities for Pb$^{+2}$ over a wide variety of other metal ions. It was successfully applied as an indicator electrode for the potentiometric titration of lead ion with potassium chromate and for the direct determination of lead in mine.

• Korean Journal of Food Science and Technology
• /
• v.48 no.4
• /
• pp.341-346
• /
• 2016

The AMY2B gene, encoding human pancreatic ${\alpha}$-amylase isozyme (HPA II), was expressed in Pichia pastoris, and the effects of chloride ions on HPA II activity toward starch substrates were investigated. As seen with chloride ion-dependent ${\alpha}$-amylases-including HPA I, the isozyme of HPA II-chloride ions increased enzyme activity and shifted the optimal pH to an alkaline pH. The activity enhancement by chloride was more significant at pH 8 than that at pH 6, suggesting that the protonation state of the general acid/base catalyst of HPA II was important for the hydrolysis of starches at an alkaline pH because of the increase in its $pK_a$ by chloride ions. The turnover values for cereal starches as the substrates markedly increased in the presence of chloride by up to 7.2-fold, whereas that for soluble starch increased by only 1.7-fold. Chloride inhibited substrate hydrolysis at high substrate concentrations, with $K_i$ values ranging from 6 to 15 mg/mL.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.10a
• /
• pp.751-754
• /
• 1999

Corrosion inhibitors are widely used to protect chloride-induced corrosion of reinforcement in concrete. However, the number of researches on the corrosion of reinforcement, when corrosion inhibitor is used, is not enough for actual application in the field. In addition, on corrosion of reinforcement a quantitative standard about corrosion inhibitor does not exist and the data about its influencing concrete are relatively rare. In this study, the effectiveness of rebar corrosion protection, setting time, compressive strength, chloride ion's penetration, and diffusion test were performed using with three different kinds of corrosion inhibitors.