• Clinical and Experimental Pediatrics
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• 제46권3호
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• pp.308-311
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• 2003

저자들은 복부 팽만과 체중감소를 주소로 내원한 신생아에서 복부 팽만이 심하여 기계적 장 폐색을 의심하여 시험적 개복술 시행하였으나, 폐색 소견 발견되지 않았고 이후 대변의 염소 이온 농도를 검사한 결과 CLD로 진단된 1례를 경험하였기에 문헌 고찰과 함께 보고하는 바이다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 추계 학술논문 발표대회
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• pp.148-149
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• 2016

In this paper, the increase in chloride resistance of footing concrete at coastal area was evaluated by replacement of Mineral Admixture. In KBC 2009, the footing concrete's minimum specific concrete strength at coastal area is determined to 35MPa. However, this is criteria only based on the strength aspect. Thus, it is not considered to increase the chloride resistance by replacement of Mineral Admixture. According to the test results of chloride ions penetration resistance, 35MPa class concrete with OPC 100% shown inaccessible state. Low-strength (24~30MPa class) concretes with Mineral Admixture, however, presented better performances. In addition, chloride diffusion coefficient tests showed identical appearance. Therefore, the current KBC's chloride resistance criteria based on only concrete strength has to review for the reason it can cause many problems (ex. cost increases by growing concrete strength and the environmental issues by a lot of cement use).

• Computers and Concrete
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• 제15권1호
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• pp.127-140
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• 2015

The process of chloride ingress in saturated concrete was presented by a previous study that used a mathematical model for the same as that concrete. This model is to be studied chloride ion diffusion which is considered as a chemical phenomenon and is to be represented the chloride diffusion process to be a nonlinear partial differential equation (PDE). In this paper, this nonlinear PDE is solved by the Kirchhoff transformation to render into a linear PDE. This linear PDE associated with initial and boundary conditions is also solved by the Laplace transformation to obtain an analytical solution. To verify the serviceability and reliability of this proposed method, the practical application should be supplied. The input parameters were cited from the previous study. The free chloride concentration profiles obtained by the analytical solution of mathematical model for saturated concretes after 24 and 120 hrs of exposure were compared with the previous study. The predicted results obtained from proposed method have a tendency with experimental results obtained by the previous study and trend toward numerical results approximated by finite difference technique.

• 한국축산식품학회지
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• 제28권3호
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• pp.301-305
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• 2008

조제분유중의 요오드 및 염소를 신속하고 정확하게 분석하기 위해 이온선택성 전극을 이용한 분석을 실시하였다. 전극을 이용한 측정시 영향을 주는 간섭물질을 제거하기 위해 시료를 용해한 후 3% 아세트산 2 mL를 투입하고, 정제는 filter paper(No.541, Whatman, UK)를 이용하여 여과하는 방법을 선택하였다. 요오드 및 염소이온이 pH에 의해 영향을 받는 것을 확인할 수 있었으며, 0.1 N NaOH를 사용하여 pH를 7.0으로 보정하여 농도를 측정함으로써 요오드와 염소의 회수율 각각 $93.7{\pm}2.7%$와 $103.9{\pm}4.9%$의 결과를 얻을 수 있었다. 간단하고 신속한 간섭물질 제거와 정제를 통해 조제분유중의 요오드 및 염소이온의 농도를 이온전극으로 신속하고 정확하게 측정할 수 있었다.

• Corrosion Science and Technology
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• 제8권2호
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• pp.81-88
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• 2009

Chloride induced corrosion of steel reinforcement inside concrete is a major concern for concrete structures exposed to a marine environment. It is well known that transport of chloride ions in concrete occurs mainly through ionic/molecular diffusion, as a gradient of chloride concentration in the concrete pore solution is set. In the process of chloride transport, a portion of chlorides are bound in cement matrix then to be removed in the pore solution, and thus only the rest of chlorides which are not bound (i.e. free chlorides) leads the ingress of chlorides. However, since the measurement of free/bound chloride content is much susceptible to environmental conditions, chloride profiles expressed in total chlorides are evaluated to use in many studies In this study, the capacity of chloride binding in cement matrix was monitored for 150 days and then quantified using the Langmuir isotherm to determine the portions of free chlorides and bound chlorides at given total chlorides and the redistribution of free chlorides. Then, the diffusion of chloride ion in concrete was modeled by considering the binding capacity for the prediction of chloride profiles with the redistribution. The predicted chloride profiles were compared to those obtained from conventional model. It was found that the prediction of chloride profiles obtained by the model has shown slower diffusion than those by the conventional ones. This reflects that the prediction by total chloride may overestimate the ingress of chlorides by neglecting the redistribution of free chlorides caused by the binding capacity of cement matrix. From the evaluation, it is also shown that the service life prediction using the free chloride redistribution model needs different expression for the chloride threshold level which is expressed by the total chlorides in the conventional diffusion model.

• Computers and Concrete
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• 제21권4호
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• pp.471-484
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• 2018

Refined analysis depicting mass transportation and physicochemical reaction and reasonable computing load with acceptable DOFs are the two major challenges of numerical simulation for concrete durability. Mesoscopic numerical simulation for chloride diffusion considering binder, aggregate and interfacial transition zone is unable to be expended to the full structure due to huge number of DOFs. In this paper, a multiscale approach of combining both mesoscopic model including full-graded aggregate and equivalent macroscopic model was introduced. An equivalent conversion of chloride content at the Interfacial Transition Layer (ITL) connecting both models was considered. Feasibility and relative error were discussed by analytical deduction and numerical simulation. Case study clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Difference for single-scale simulation and multiscale approach was observed. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of rebar placement, rebar diameter, concrete cover and exposure period.

• Journal of Chest Surgery
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• 제21권2호
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• pp.240-245
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• 1988

This study was prospectively planned to realize the reduction of calcium ion in serum along with the cardiopulmonary bypass[CPB], to find out the cause of the reduction, and to verify the justification of the classical methods of calcium replacement. Nine patients with various open heart surgeries by CPB in 1987 wee selected at random. Calcium chloride was added as follows:: For each unit of ACD blood transfusion, 600mg of calcium chloride was added. In case of massive transfusion, 600 mg of calcium chloride was injected every 2 or 3 units of transfusion. On occasions such as weaning from CPB, or following defibrillation, or hypotension, weak myocardial contractility of the heart, calcium chloride was needed in an amount of 10 mg / kg. In ICU, calcium chloride was limited to use in low serum level or in emergency use. Total calcium decreased early bypass and progressively increased above the preoperative value during late bypass and three hours thereafter, Ionized calcium increased during late bypass and three hours following. Total and ionized calcium depicted similar patterns of change during open heart surgery. Decrease of the calcium at the early bypass was thought from reduction of total protein and alkalosis during bypass. Meanwhile, increase of both calciums during the end of surgery was presumably attributable to addition of calcium chloride in priming solution, injections of calcium chloride in the process of termination of bypass. We conclude that enough calcium was replaced by the classical methods of calcium supplement.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 추계 학술논문 발표대회
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• pp.127-131
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• 2009

The purpose of this study is to provide fundamental data on chloride diffusion from lightweight aggregate concrete by utilizing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated after experiment based on NT BUILD 492. Diffusion coefficient of SLG and CLG were little bit higher than CG Concrete, but the difference is meaningless. Also, chloride diffusion coefficient indicates that it is highly affected by water-binder ratio, and it decreases with the decrease in water-binder ratio. The admixture substitution indicates decrease only with water-binder ratio of 0.4 for FA15% case, but admixture substitution indicates decrease with all levels of ratio for FA10 + BFS20% which means more appropriate. According to the analysis result of chloride diffusion from lightweight aggregate concrete, crushed stone-powder utilized lightweight aggregate concrete indicates higher chloride diffusion coefficient than CG concrete, which is not a significant difference, and can improve resistance through water-binder ratio and admixture substitution.

• 콘크리트학회논문집
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• 제29권3호
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• pp.307-314
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• 2017

콘크리트는 경제적이고 내구성을 가진 건설재료지만, 염해에 노출될 경우 내부 철근부식으로 인한 성능저하를 나타낸다. 콘크리트로 침투하는 염화물 이온은 수화물의 생성, 공극률 감소 등으로 인해 감소하게 되며, 주로 시간에 따라 감소하는 염화물 확산계수를 통하여 염화물 거동이 구현되고 있다. 본 연구에서는 고로슬래그 미분말(GGBFS: Ground Granulated Blast Furnace Slag)과 보통포틀랜트 시멘트(OPC: Ordinary Portland Cement)를 사용한 고성능 콘크리트를 대상으로 염화물 확산계수, 통과전하, 강도를 재령효과를 고려하여 평가하였다. 이를 위해 물-결합재비를 3가지 수준(0.37, 0.42, 0.47), 치환률을 3가지 수준으로 (0%, 30%, 50%)를 고려한 콘크리트를 제조하였으며, 28일 및 180일 재령에 따라 시험을 수행하였다. OPC를 사용한 콘크리트에서는 물-결합재비가 낮은 배합에서 염화물 확산이 감소하였으며, GGBFS를 50% 혼입한 배합에서는 물-결합재비가 높은 경우 염화물 확산성이 크게 감소하였다. 28일 재령에서 GGBFS 치환률이 50%인 경우 강도의 증가보다 빠르게 염화물 확산계수와 통과전하의 감소가 평가되었으며, 이는 초기재령에서도 효과적으로 염화물 침투에 저항할 수 있음을 나타낸다.

• 한국재난정보학회 논문집
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• 제13권4호
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• pp.562-569
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• 2017

철근콘크리트는 철근과 콘크리트가 재료적으로 일체화되어 경제적이고, 반영구적 이여서 사회 간접자본으로 건설되는 교량 및 대형구조물에 사용되어 지지만 해양노출환경 및 동절기에 사용되는 제설제 등으로 콘크리트 중의 염화물 이온이 철근의 부동태 피막을 파괴하여 철근이 부식함으로써 여러 가지 화학적 및 물리적 작용을 복합적으로 받을 경우에 단기간에 내구성능이 저하되고 구조물의 수명이 단축된다. 본 연구에서는 상기와 같은 철근콘크리트의 염해에 의한 손상부에서 염소이온을 효과적으로 제거하여 초기 구조물의 내구성을 회복할 수 있는 보수 공법에 대한 연구를 수행하였다.