• Title/Summary/Keyword: Chi3l1

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Synthesis of Surface Active Properties of Destructible Surfactants with 1,3-Dioxane (1,3-디옥산을 함유한 분해성 계면활성제의 합성의 및 계면 특성)

  • Kim, Chi-Hoi;Roh, Yun-Chan;Kim, Yu-Ok;Nam, Kie-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.61-71
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    • 1996
  • In acid-catalyzed acetal cyclization of long aliphatic aldehydes($R=n-C_7H_{15}$ ; $n-C_9H_{19}$ ; $n-C_{11}H_{23}$) with 1,1,1-tris(hydroxymethyl)propane, 2-alkyl-5-hydroxymethyl-5-ethyl-1,3-dioxanes were obtained. The final products, sodium 2-alkyl-5-(sulfonatedpropylethermethyl)-5-ethyl-1,3-propanesultion in the presence of sodium hydride. These compounds were a new group of destructible surfactants which were readily hydrolyzed and oxidized in natural water reservoirs. Physical properties of these new compounds involved some surface properties such as Krafft point(Kp), critical micelle concentration(cmc), surface tension of aqueous solutions near cmc(${\gamma}_{min}$), foaming power, emulsion power and hydrolysis properties were determined. The destructible surfactants containing 1,3-dioxane ring were synthesized to about $85{\pm}5.5%$ yield. The cmc values of the compounds by ring method were assumed to $0.5{\sim}5.0{\times}10^{-3}mol/L$ range and surface tensions at cmc were $29.5{\sim}33.0dyne/cm$ respectively at $25^{\circ}C$. The foaming power and foam stability were $170{\sim}230mm$ and $52{\sim}135mm$ respectively at $1{\times}10^{-2}mol/L$, foam was occurred rarely below $1{\times}10^{-3}mol/L$. The emulsion property of liquid paraffin was better than that of soybean oil. For hydrolysis property with ph and time, these compounds were decomposed within about 200minutes at $ph1{\sim}2$. Hopefully these compounds are expected to be a good O/W emulsifier that have decomposability in acid and may be used in the process which do not need foaming.

Effects of Melatonin and Fluid Shear Stress on 3T3-L1 Preadipocytes (3T3-L1 지방전구세포에서 멜라토닌과 유체전단응력의 영향)

  • Lee, Jeongkun;Lee, Yeong Hun;Park, Chae Lim;Kim, Chi Hyun
    • Journal of Biomedical Engineering Research
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    • v.39 no.3
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    • pp.109-115
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    • 2018
  • Obesity is a worldwide disease caused by the excessive proliferation of adipocytes. Multiple factors, including melatonin and physical loading, are involved in the control of obesity. Melatonin has been shown to induce apoptosis on preadipocytes while physical loading such as fluid shear stress (FSS) affects the proliferation and differentiation of adipocytes. Here, we studied the combined effects of melatonin and FSS on 3T3-L1 preadipocytes. For physical loading, preadipocytes were stimulated with a maximum dynamic fluid shear stress of 1 Pa at 1 Hz for 2 hours with/without melatonin. The experiment conditions were divided into four groups: (1) control, (2) 1 mM melatonin treatment, (3) FSS, and (4) combined 1 mM melatonin and FSS. All groups had a fixed duration time of 2 hours. ERK, p-ERK, COX-2, $C/EBP{\beta}$, $PPAR{\gamma}$, osteopontin, Bax, caspase-3 and caspase-8 proteins were assessed by Western blot analysis. GAPDH was used as a control. Results showed that combined melatonin and FSS treatment activated the ERK/MAPK pathway but not COX-2. Furthermore, combined melatonin and FSS treatment significantly decreased $C/EBP{\beta}$ and $PPAR{\gamma}$ compared to other groups. However, caspase-3 and caspase-8 did not result in significant changes. In summary, combined melatonin and FSS appears to have the potential to inhibit adipogenesis and treat obesity.

A Study on the Off-Line Parameter Estimation for Sensorless 3-Phase Induction Motor using the D-Axis Model in Stationary Frame (정지좌표계 d축 모델을 이용한 위치센서 없는 3상 유도전동기의 오프라인 제정수 추정에 관한 연구)

  • Mun, Tae-Yang;In, Chi-Gak;Kim, Joohn-Sheok
    • The Transactions of the Korean Institute of Power Electronics
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    • v.25 no.1
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    • pp.13-20
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    • 2020
  • Accurate parameters based on equivalent circuit are required for high-performance field-oriented control in a three-phase induction motor. In a normal case, stator resistance can be accurately measured using a measuring equipment. Except for stator resistance, all machine parameters on the equivalent circuit should be estimated with particular algorithms. In the viewpoint of traditional regions, the parameters of an induction motor can be identified through the no-load and standstill test. This study proposes an identification method that uses the d-axis model of the induction motor in a stationary frame with the predefined information on stator resistance. Mutual inductance is estimated on the rotational dq coordination similar to that in the traditional no-load experiment test. The leakage inductance and rotor resistance can be estimated simply by applying different voltages and frequencies in the d-axis model of the induction motor. The proposed method is verified through simulation and experimental results.

The Influence of Rice Black-Streaked Dwarf Virus on the Rice Yield and Its Components (벼 검은줄무늬오갈병이 수량과 수량구성요소에 미치는 영향)

  • Kim D.K.;Park R.K.;Jung Y.T.;Jin Y.D.
    • Korean journal of applied entomology
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    • v.22 no.3 s.56
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    • pp.193-197
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    • 1983
  • In 1981 Rice Black-Streaked Dwarf Virus (RBSDV) was severely occurred in Yeongnam area of Korea. The influence of RBSDV to rice plant was studied with two susceptible cultivars, Nagdongbyeo and Cheongcheongbyeo. The stunting rate was determined by the percentage of plant height of infected plants vs. healthy plants. When the rice plants were severely stunted by RBSDV, the yield components and yield were greatly reduced. The stunting of rice plants infected with RBSDV was caused mostly by the shortening of internodes in upper parts of the culm. The relationship between stunting rate of rice plants and yield was shown to have a negative exponential correlation. The regression equations of the relationship are experssed as follows: In Cheongcheongbyeo $Y=46.6lxe^{-0.0624_\chi}$, and in Nagdongbyeo $Y=54.82xe^{-0.067_\chi}$.

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Classifications of the Skin Colors on Korean women and their Preference Colors of Apparel (한국 여성의 피부색 분류와 의상선호색에 관한 연구)

  • 이민아;김구자
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.1
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    • pp.133-143
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    • 2002
  • The textile industry is petting increased effort to manufacture the value-added products that gives the differentiated characters at every level of fiber and fabric production. The color is an important element to be used strategically in order to push up the value-added design. The colors of apparel products have a close relationship with the skin colors of consumers and their preference colors. This study was carried out to cluster the skin colors of the Korean women into several similar skin colors and to analyze their preference colors by the classified groups. We measured the skin colors of 354 Korean women. With color spectrometer, JX-777, we measured 4 points of the body; cheek with removing cosmetics off, forehead, rear neck and arm on the interior part near elbow. All subjects had been shown with 40 color chips and answered the preference colors and preference colors of apparel. Data were analysed to classify skin colors using K-means Cluster Analysis and Duncan test, Frequency and Chi square test on the preference colors about the clustered 3 groups. In doing so, we used in SPSS Win 10 statistical package. Findings were as fellows: 1) The skin colors of the Korean women were clustered into YR, R, and Y skin colors. The majority of the subjects, 324 observations had YR skin colors and the subjects were classified into 3 kinds of skin color groups who had YR skin colors. 2) The average skin colors of total 324 subjects was 5.23YR 6.49/4.09 in Munsell Color System(MCS), 66.56 in L value, 10.53 in a value, and 20.67 in b value. 3) The average skin color of Type 1 was 7.98YR 6.24/4.14 in MCS, 64.10 in L value, 15.05 in a value, and 24.0 in b value. For Type 2 was 7.30 YR 6.56/3.28 in MCS, 67.24 in L value, 6.89 in a value, and 18.4 in b value, and Type 3 was 7.01 YR 7.20/4.38 in MCS, 73.53 in L value, L 16.04 in a value, and 24.87 in b value. 4) The average face color of total 324 subjects was 7.31YR 6.65/3.56 in MCS, 68.13 in L value, 9.53 in a value, and 20.18 in b value. 5) The average face color of Type 1 was 4.19 YR 6.92/5.05 in MCS, 70.78 in L value, 13.2 in a value, and 25.32 in b value. For Type 2 was 5.24YR 6.33/3.79 in MCS, 64.94 in L value, 9.84 in a value, and 19.08 in b value. Type 3 was 5.4YR 6.85/4.68 in MCS, 70.1 in L value, 11.73 in a value, and 23.92 in b value. 6) The difference of mean values between the clustered 3 skin color groups showed significantly different except the a value of neck and H value of cheeks and H value of foreheads. 7) All 3 groups showed that the most preference colors and the most preference colors of apparel was 5R 4/14. and their preference colors were much more than the preference colors of apparel.

The Health Symptoms Assessment and Urinary Hippuric Acid Excretions of Workers Exposed to Toluene in Shoes Workshops (신발 작업장에서 Toluene폭로 근로자들의 자각증상에 의한 건강상태평가 및 요중 Hippuric acid 배설량)

  • Ok, Chi-Sang;Kim, Young-Mi
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.131-131
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    • 1995
  • The health symptoms assessment and urinary hippuric acid excretions of workers exposed to toluene occupationally in shoes workshops were investigated by the Questionnaire and the field monitoring. Based on the results, the acute health symptoms of workers exposed to toluene by questionnaire were fatigue(58.7%), irritation of the eyes, nose and throat(57.2%), and skin dryness(43.3%). And the complaints about workshop environment are odor, dust and noise. The mean values of urinary hippuric acid excretions in m식e and female were 1.08 $pm$ 0.50 g/l, 1.59 ± 1.27 g/l in total workers, espectively.

The Design of Miniature Microstrip Fractal Patch Antenna Using L-shaped Feeding Structure. (L-형급전구조를 이용한 소형 마이크로스트립 Fractal 패치 안테나 설계)

  • Park, Chang-Hyun;Yoon, Chi-Mu;Kim, Kab-Ki
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.10a
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    • pp.863-867
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    • 2007
  • In this paper, We have designed miniature microstrip patch antenna based on fractal structure using L-shaped feeding structure for 4G mobile communication applications. Miniature antenna has achieved by the presence of unusual fundamental resonant mode which we call "crossed-diagonal"(CD)current. Using CST Microwave Studio 5.0, patch antenna was designed. The simulated input return loss showed the bandwidth of 1.2647[GHz]($2.944{\sim}4.209GHz$), 35.4% below -10dB. The gain of E, H-plane was achieved 8.3dBi and 8.4dBi respectively. And beamwidth of 3dB in the E, H-plane was $40.6^{\circ}$ and $81.6^{\circ}$, respectively.

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In vitro and in vivo antibacterial activities of root extract of tissue cultured Pluchea indica (L.) Less.

  • Pramanik, Kartick Chandra;Chatterjee, Tapan Kumar
    • Advances in Traditional Medicine
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    • v.8 no.3
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    • pp.295-301
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    • 2008
  • The methanolic root extract of tissue cultured Pluchea indica (L.) Less. was tested for its antibacterial potentiality against 102 different strains of bacteria belonging to both Gram positive and Gram negative groups. The bacteria could be arranged according to their decreasing order of sensitivity as follows: Staphylococcus aureus, Vibrio cholerae, Bacillus spp. Vibrio parahaemolyticus, shigellae, Salmonella spp., and Escherichia coli. The extract was found to be bacteriostatic in nature against Salmonella typhimurium NCTC 74. When administered to Swiss strain of white mice at the doses of 0.5 and 1.0 mg/kg body weight, the extract could significantly protect the animals challenged with 50 MLD of S. typhimurium NCTC 74. According to the chi-square test, the in vivo data is highly significant (P < 0.001).

New Thiazolo[3,2-b][1,2,4]triazole Derivatives : Useful Compounds for the Preparation of 7-Substituted Cephalosporins

  • Nam, Ghil-Soo;Lee, Jae-Chul;Chi, Dae-Yoon;Kim, Joong-Hyup
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.383-386
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    • 1990
  • We have synthesized several bicyclic heteroaromatic compounds with bridgehead nitrogen from N-amine salts of heteroaromatic amines. 2-Amino and 2-unsubstituted thiazolo[3,2-b][l,2,4]triazole derivatives 2a-b were prepared by the cyclization reaction from N-amine salts of aminothiazole-5-yl(N-methoxyimino)acetate with cyanogen bromide and formamidine acetic acid salt, respectively. 2-Methylthiazolo[3,2-b][1,2,4]triazole 2c was obtained from N-acetylated N-amine salt of aminothiazole-5-yl(N-methoxyimino)acetate by the cyclization reaction in the presence of polyphosphoric acid (PPA). 2-Substituted and 2-unsubstituted thiazole[3,2-b][1,2,4]triazole derivatives 2a-c were coupled with 7-aminocephalosporanic acid (7-ACA). Coupled cephalosporin derivatives 1a-c did not have good antibacterial activities in vitro.

Synthesis and Degradability of Aliphatic Copolyester and Aliphatic Copolyesteramide(2) (지방족 copolyester 및 copolyesteramide의 합성과 분해성(2))

  • Kim, Woo-Sik;Hyun, Seok-Hee;Jeon, Il-Ryon;Kang, Hye-Jung;Lee, Chi-Giu;Kim, Sung-Hwan
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.481-489
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    • 1996
  • D,L-lactide (2-LA) was copolymerized with ${\beta}$-methyl-${\delta}$-valerolactone (MVL) using tetraphenyltin as a catalyst and the properties of the copolymers were investigated. The composition of the repeating unit of lactic acid in the copolymers was higher than that in the monomer feeds. The composition of the lactic acid unit in the copolymers decreased with increasing copolymerization time. The yield and the molecular weight of the copolymer increased with increasing 2-LA in the feed composition. These results suggest that the reactivity of 2-LA is larger than that of MVL. The number average molecular weight was in the range of 54,000 to 63,000 and the polydispersity index was in the range of 1.7 to 2.1. The copolymers did not show melting point, but glass transition temperature. The degradable tendency of the copolymers with lipase was almost equal to that of L-lactide-MVL copolymer.

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