• Title/Summary/Keyword: Chemistry laboratory class

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GLOBAL WEAK MORREY ESTIMATES FOR SOME ULTRAPARABOLIC OPERATORS OF KOLMOGOROV-FOKKER-PLANCK TYPE

  • Feng, Xiaojing;Niu, Pengcheng;Zhu, Maochun
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.5
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    • pp.1241-1257
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    • 2014
  • We consider a class of hypoelliptic operators of the following type $$L=\sum_{i,j=1}^{p_0}a_{ij}{\partial}^2_{x_ix_j}+\sum_{i,j=1}^{N}b_{ij}x_i{\partial}_{x_j}-{\partial}_t$$, where ($a_{ij}$), ($b_{ij}$) are constant matrices and ($a_{ij}$) is symmetric positive definite on $\mathbb{R}^{p_0}$ ($p_0{\leqslant}N$). By establishing global Morrey estimates of singular integral on the homogenous space and the relation between Morrey space and weak Morrey space, we obtain the global weak Morrey estimates of the operator L on the whole space $\mathbb{R}^{N+1}$.

A Status on the Chemical Waste in Elementary School Science Laboratory (초등학교 과학실에서 발생하는 화학폐기물에 대한 실태)

  • Kim, Seong Gyu;Heo, Seung Hyeon
    • Journal of Environmental Science International
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    • v.13 no.3
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    • pp.301-311
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    • 2004
  • The purpose of this study was to examine teachers’ awareness of chemical waste produced in elementary school laboratory experimentation and how this awareness relates to collection and disposal of chemical waste. More specifically, the study looked at the correlation between the handling of chemical waste and factors such as years of teachers’ educational career, class size and amount of waste produced. The target population were 250 elementary school teachers in Gyeongnam area and 237 subjects were responded. Among the 237 responses, 37 cases that did not complete the questionnaire were eliminated. Therefore, 200 responses were analyzed in this study. The survey questionnaire consisted of 15 questions. The categories of the questionnaire were their skills of management and treatment of the chemical waste. The data collected were analyzed by SPSS 10.0, and the relations among variables such as class sizes and years of teaching experience were also analyzed by $x^2-test.$ The results in this study were as follows: First, there were no significant differences between the years of teaching and class sizes in the training experience of chemical waste disposal. Second, there was a significant difference between the science laboratory size and class sizes in the laboratory actual condition. In addition, in the relations between the number of times of experimentation and the years of teaching experience, there was a significant difference. Third, in terms of the discharge amount of chemical waste, there was a significant difference between the years of teaching and class sizes. Fourth, in the simple chemistry waste disposal process in the science laboratory, there also was a significant difference between the kinds of experimental equipments that used in the experimentation and the years of teaching. Based on this study, it was found that great amount of the chemical wastes produced in the science laboratory dumped into the drain and the treatment process of chemical waste was also inattentive. Even the importance of environmental education is emphasized in the elementary education, the basic problems occurred in the science laboratory is disregarded. Therefore, not only students but teachers have to pay attention to the disposal process of chemical waste in the laboratory in order to prevent environment pollution. Furthermore, the efforts of preventing environment pollution are needed such as opening the teacher training course about environment education, minimal use of chemicals, treatment of chemical waste, and so forth.

Functional Identification of Ginkgo biloba 1-Deoxy-D-xylulose 5-Phosphate Synthase (DXS) Gene by Using Escherichia coli Disruptants Defective in DXS Gene

  • Kim, Sang-Min;Kuzuyama, Tomohisa;Chang, Yung-Jin;Kim, Soo-Un
    • Journal of Applied Biological Chemistry
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    • v.48 no.2
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    • pp.101-104
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    • 2005
  • DXS catalyzes the first step of MEP pathway. Escherichia coli disruptants defective in dxs were constructed by insertional mutation and characterized. Selected disruptant, DXM3, was auxotrophic for DX or ME. Putative class 1 DXS ORF from Ginkgo biloba was shown to rescue DXM3 grown without DX or ME supplementation. The putative ORF was thus confirmed as DXS1. The disruptant was demonstrated to be useful for DSX screening.

Photoluminescence and Electroluminescence of Carbazole-based Conjugated Dendritic Molecules

  • Cho, Min-Ju;Kim, Young-Min;Ju, Byeong-Kwon;Choi, Dong-Hoon
    • Journal of Information Display
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    • v.9 no.3
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    • pp.16-22
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    • 2008
  • A novel class of conjugated dendritic molecules bearing N-hexyl-substituted carbazoles as peripheral groups and various conjugative aromatic cores was synthesized through Heck coupling and the Horner-Emmons reaction. A multilayered structure of ITO/PEDOT:PSS (30 nm)/emitting material (50 nm)/BCP (10 nm)/$Alq_3$ (10 nm)/LiF (1 nm)/Al (100 nm) was employed to evaluate the synthesized dendritic materials. The electroluminescence spectrum of the multilayered device made of 3Cz predominantly exhibited blue emissions. Similar emissions were observed in the PL spectra of it's the device's thin film. The multilayered devices made of 3Cz, 3BCz, and 4BCz showed luminance values of 6,250 cd $m^{-2}$ at 24 V, 3,000 cd $m^{-2}$ at 25 V, and 1,970 cd $m^{-2}$ at 36 V, respectively. The smallest molecule, 3Cz, which bore three carbazole peripheral groups, exhibited a blue-like emission with CIE 1931 chromaticity coordinates of x = 0.17 and y = 0.21.

Accelerated SCC Testing of Stainless Steels According to Corrosion Resistance Classes

  • Borchert, M.;Mori, G.;Bischof, M.;Tomandl, A.
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.280-287
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    • 2015
  • The German Guidelines for stainless steel in buildings (Z.30.3-6) issued by the German Institute for Building Technology (DIBt) categorizevarious stainless steel grades into five corrosion resistance classes (CRCs). Only 21 frequently used grades are approved and assigned to these CRCs. To assign new or less commonly used materials, a large program of outdoor exposure tests and laboratory tests is required. The present paper shows theresults of stress corrosion cracking (SCC) tests that can distinguish between different CRCs. Slow strain rate tests (SSRT) were performedin various media and at different temperatures. CRC IV could be distinguished from CRC II and CRC III with a 31.3 % $Cl^-$ as $MgCl_2$ solutionat $140^{\circ}C$. CRC II and CRC III could be differentiated by testing in a 30% $Cl^-$ as $MgCl_2$ solutionat $100^{\circ}C$.

Efficient Protection of Alcohols with Carboxylic Acids Using a Variety of Heteropolyoxometallates as Catalysts, Studying Effective Reaction Parameters

  • Tayebee, Reza;Cheravi, Fatemeh
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2899-2904
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    • 2009
  • Esterification is an important class of reactions in the preparation of perfumery and flavor chemicals, wherein homogeneous, solid acidic, and superacidic catalysts are normally used. Now, an efficient and selective protocol for protection of various functionalized alcohols employing carboxylic acids as protecting agents is realized through the catalytic mediation of simple heteropolyoxometallates. In this methodology, water is the only by-product and notably the aspect of effluent treatments does not arise. The advantages include the operational simplicity, recycle ability of the catalyst and mild reaction conditions. The present catalytic system may be a potential candidate not only for laboratory practice but also for commercial applications and offers an environmentally safer alternative to the existing processes.

The Development and Validation of Instructional Strategies Using the Advanced Laboratory Equipment(ALE) in Science High School Chemistry Classrooms: A Focus of UV-Visible and IR Spectrophotometer (과학고등학교 화학수업에서 첨단과학 실험기기 활용 수업 전략의 개발 및 타당화: 자외선-가시광선 및 적외선 분광기를 중심으로)

  • Jeon, Kyunghee;Park, Dahye;Jang, Nakhan;Park, Jongwook;Park, Jongseok
    • Journal of the Korean Chemical Society
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    • v.60 no.1
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    • pp.69-81
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    • 2016
  • The purpose of this study was to find out the validation of instructional strategies using the Advanced Laboratory Equipment (ALE class) by investigating science high school students’ perception on ALE in chemistry classrooms and to consider the need for development of teaching materials on ALE class. 7 sessions of ALE including experiments with innovative equipment were developed and applied to 21 students in D Science High School. At the end of the sessions, questionnaire was given to the students. We also collected qualitative data by interviewing 9 students who participated in the questionnaire. We analyzed the data collected by In-depth interviews and students’ experimental reports. The result showed that ALE class was effective to enhance students’ understanding of learning concepts because the experimental time was shortened in real time data processing. Some students showed creative performance on solving scientific problems by using everyday materials in experimental process and developed perceptions of practical inquiry. Through this process, students’ positive attitudes and interests in science and heuristic inquiry skills were also enhanced. Developing ALE lesson materials will be helpful for students to understand science and technology and the domain of science in broader contexts.

A Stidy on the Real Management of Experimental-practice and Spot-practice at Department of Food and Nutrition of Junior College in Korea (전문대학 식품영양과의 실험실습 및 현장실습 운영실태에 관한 연구)

  • Yun, Seong-Sik;So, Myeong-Hwan;Nam, Gung-Seok
    • The Korean Journal of Food And Nutrition
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    • v.2 no.1
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    • pp.61-72
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    • 1989
  • This study was conducted to gather the baseline data on realities of experimental-practice and opinions toward spot-practice, and to examine how to cope with the problems raised at the Department of Food and Nutrition of Junior Technical College in Korea. Questionnaires were gathered from 42 chairmans of the Department of Food and Nutrition and 140 Present dieticians worked in Seoul, Bucheon am Seongnam area. The results are as follows, First, as a whole, each college had 2~3 experimental laboratory (Lab), in which Cooking Science Lab. Chemistry Lab and Microbiology Lab were occurred at higher frequency as Lab's name. Second, the numbers per experimental-practice class were more than 40 at most colleges. 85% of Present dieticians have answered to feel too much numbers per the class during their college days, whereas professors' opinions toward the numbers per class were suitable at 20~30 persons per class. Third, professors' opinion toward the adquate ratio of the theory subject classes to experimental subject classes was suitable at 60 : 40. Dieticians answered to take the theory subject classes partly or mostly on behalf of the experimental-practice classes. Fourth, the main reasons which inhibited normal experimental-practice class were the class for emphasis on examination, the shortage of experiment budget, the excess of class members, the shortage of experimental Lab Also, this results showed same propensity to present dieticians' opinion toward the same question above. Fifth, among the experimenta1-practice subjects established at the Department of Food and Nutrition, Diet Therapy Lab was highest frequency class emphasized on theory followed by Nutrition Counselling Lab, Food Processing and Storage Lab, Food Hygiene Lab and Food Microbiology Lab in that order. Here, Basic Chemistry Lab, Biochemistry Lab, Food Microbiology Lab were pointed as subjects far from the present task of dieticians. Sixth, Department of Food and Nutrition, as a whole, has conferred with spot-practice arrangement About 50% (all who want to join spot-practice) of second year students took part in spot-practice. In the other way, all colleges except for 2 colleges didn't give the credit for the spot-practice system. Seventh, according to the on analysis on spot-practice places, manufacturing company was at highest frequcney followed by hospitals, elementary school having group feeding system in that order. Especially, 16.7% (5 colleges) of the total colleges sent the students to the research institute related to food industry for spot-practice experience. Eighth, Professors' opinions toward the spot-practice time and period were preferable on summer vacation of second year and for 1~2 weeks, respectively. On the contrary, 74 dieticians answered to the adquate period as for 4 weeks. Ninth, 86 dieticians of the total 140 answered to complete the spot-practice during their college days, which helps the present task of them. Lacks of spot-practice program, Lacks of comprehension of upper personals and lacks of group feeding equipments ranks higher as difficulties in spot-practice management.

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Advances in the chemistry, pharmacological diversity, and metabolism of 20(R)-ginseng saponins

  • Wang, Chaoming;Liu, Juan;Deng, Jianqiang;Wang, Jiazhen;Weng, Weizhao;Chu, Hongxia;Meng, Qingguo
    • Journal of Ginseng Research
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    • v.44 no.1
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    • pp.14-23
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    • 2020
  • Ginseng has been used as a popular herbal medicine in East Asia for at least two millennia. However, 20(R)-ginseng saponins, one class of important rare ginsenosides, are rare in natural products. 20(R)-ginseng saponins are generally prepared by chemical epimerization and microbial transformation from 20(S)-isomers. The C20 configuration of 20(R)-ginseng saponins are usually determined by 13C NMR and X-ray single-crystal diffraction. 20(R)-ginseng saponins have antitumor, antioxidative, antifatigue, neuroprotective, and osteoclastogenesis inhibitory effects, among others. Owing to the chemical structure and pharmacological and stereoselective properties, 20(R)-ginseng saponins have attracted a great deal of attention in recent years. In this study, the discovery, identification, chemical epimerization, microbial transformation, pharmacological activities, and metabolism of 20(R)-ginseng saponins are summarized.

Validity of MAST-CLA for diagnosis of arthropod allergy using receiver operating characteristic (ROC) analysis

  • Park, Joon-Soo;Nam, Hae-Seon;Kim, Yong-Bae;Choi, Young-Jin;Lee, Sang-Han;Kim, Sung-Ho
    • Parasites, Hosts and Diseases
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    • v.45 no.3
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    • pp.239-243
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    • 2007
  • Many allergists are currently focusing on the development of new diagnostic tools, and are attempting to improve both the sensitivity and specificity. A multiple allergen simultaneous test-chemiluminescent assay (MAST-CLA) is one of the most popular diagnostic tools used in the Republic of Korea. However, there remains controversy among allergists with regard to the cut-off point for a positive result. The present study was conducted in order to determine the validity of MAST-CLA as compared with that of the skin prick test, with particular emphasis on arthropod allergens, on the basis of percentage agreement rates and k-values, and also to suggest the optimal positive cutoff points using receiver operating characteristic (ROC) curves. The study was conducted with 97 subjects (54 men, 43 women). Optimal individual cut-off points were calculated as follows; class II for Dermatophagoides farinae, class I for Dermatophagoides pteronyssinus, and trace for a cockroach mix. These findings suggest that attempting to apply optimal individual cut-off points will be a good way of improving diagnostic tests, particularly MAST-CLA.