• 제목/요약/키워드: Chemical test

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쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제4보: 국내산 반응성 골재에 JIS 신속법 적용가능성) (An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part4: The Application of the JIS Rapid Test Method to the Several Domestic Reactive Aggregates))

  • 차태환;조원기;조일호;노재호;이양수;정재동;윤재환
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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    • pp.447-450
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    • 1994
  • The chemical method and mortar-bar method for identification of the susceptibility to Alkali-Aggregate Reaction (AAR) was established as KS method by referencing the ASTM methods. However, the chemical method requires skilled chemical engineers and aggregates are tested in very severe condition, and on the other hand, the mortar-bar method needs a long time of 3 or 6 months. Judging from this circumstance that the use of crushed stones are increased due to the shortage of natural aggregates, the development and standardization of a new rapid test method is considered essential. The purpose of this paper is to research for the possibility to apply the rapid method, instead of the chemical method and the mortar-bar method with using the several domestic crushed stones.

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화학 및 천연페인트에서 발생되는 TVOCs의 방출강도 특성 연구 (Characteristics of TVOCs Emission Factors from Chemical and Natural Coating Materials)

  • 김신도;김정호;박진수;이정주
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.487-492
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    • 2004
  • Building materials are composed of very complex chemical compounds, and these indoor building materials discharge very much Volatile Organic Compounds(VOCs). We performed the environmental chamber test to investigate the Total VOCs(TVOCs) emission characteristics and emission factors about chemical and natural coating materials. As the result, we concluded that TVOCs emission are high at initial time and decreased in course of time. Natural paint was low emission level for TVOCs than chemical paint by small chamber test. The TVOCs emission factor-time profile showed a good fit with the results from the measured and predicted value.

용액중에서의 화학반응에 관한 동역학적 이론 (Kinetic Theory for Chemical Reactions in Liquids)

  • 신국조
    • 대한화학회지
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    • 제25권5호
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    • pp.291-299
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    • 1981
  • 용액중에서 화학반응을 설명하기 위하여 한개의 대표적인 입자의 반복적 충돌현상까지 고려한 동역학적인 이론을 경구모델을 사용하여 연구하였다. 반응성을 지닌 대표적인 입자의 상공간 밀도의 시간상관함수가 만족시키는 동역학방정식을 유도하였고 이로부터 비활성 용매 S중에서 일어나는 A + B ${\rightleftharpoons$ C + D 형태의 가역반응에 관계되는 반응속도 계수의 인자를 투영연산자방법으로 구하였다.

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Polyol Synthesis of Ruthenium Selenide Catalysts for Oxygen Reduction Reaction

  • Lee, Ki-Rak;Woo, Seong-Ihl
    • Bulletin of the Korean Chemical Society
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    • 제31권11호
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    • pp.3145-3150
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    • 2010
  • Ruthenium catalysts modified by selenium have been introduced as alternative materials to Pt in Direct methanol fuel cells (DMFCs). RuSe nano-particles were synthesized on the Vulcan XC72R carbon supports via polyol method. The prepared catalysts were electrochemically and physically characterized by cyclic voltammetry (CV,) linear sweep voltammetry, methanol tolerance test, X-ray diffraction (XRD), Transmission electron microscopy (TEM), Energydispersive Spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). Increasing the Se concentration up to 20 at % increased the electro-catalytic activity for the oxygen reduction. By increasing Se amount, Ru metallic form on the surface was increased. The $Ru_{80}Se_{20}$/C catalysts showed the highest oxygen reduction reaction (ORR) activity and outstanding methanol tolerant property in half cell tests as well as single cell test.

매립장 고화차수재의 화학용액과의 반응특성 (Chemical Compatibility of Solidified Liner Materials)

  • 정하익;조진우;임재상;김상길
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 봄 학술발표회 논문집
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    • pp.343-346
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    • 2002
  • The chemical compatibility of leachate with the two natural materials was analyzed by performing the hydraulic conductivity test. The selected liner materials were natural marine clay and weathered soil sampled from Kimpo wastefill and Daehwa Dong, Kyonggi Do, respectively. PARAFIX, which is mainly composed of paraffin, cement, stearic acid, PVA etc., was used as solidifying agent. The chemical solutions used in the test were 10% acetic acid, 10% methanol, and real leachate from Kimpo wastefill and the results of tests were compared with that of distilled water. The results of tests show that hydraulic conductivity of solidified clay was increased slightly with permeation of acetic acid, methanol and the increase of hydraulic conductivity was not shown with permeation of leachate, distilled water and in case of weathered soil. Based on the tests, it is ascertained that the tested liner materials can be stable with the solution of low concentration.

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지하 콘크리트 구조물에 적용되는 에폭시 수지계 주입형 누수보수재료의 화학저항성능 평가 (Evaluation of Chemical Resistance of Epoxy Resin Injection Type Leakage Repairing Materials Applied to Underground Concrete Structures)

  • 박소영;김수연;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.41-42
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    • 2017
  • In this study, an investigation was made to study the chemical resistance performance of epoxy resin injection type leakage repair material used in the Korean construction market in accordance to the test method outlined in "ISO TS 16774, Part 2; Test Method for Chemical Resistance." This is a new standard document used for quality control method of injection type repair material used for leakage cracking of underground concrete structures. The results of this study can be expected to be utilized as reference data that can be used for quality improvement of the maintenance methods for future construction.

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양면수광형 실리콘 태양광 모듈의 바닥면 반사조건 변화에 따른 발전성능 평가 (Evaluation of Bifacial Si Solar Module with Different Albedo Conditions)

  • 박도현;김민수;소원섭;오수영;박현욱;장성호;박상환;김우경
    • Current Photovoltaic Research
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    • 제6권2호
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    • pp.62-67
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    • 2018
  • Multi-wire busbar-type bifacial n-type Si solar cells have been used for the fabrication of monofacial and bifacial photovoltaic (PV) module, where bifacial module was equipped with transparent backsheet while monofacial module was prepared using white backsheet. The comparison of six-day accumulated power production obtained from outdoor test under gray cement ground conditions using 60cell monofacial and bifacial PV modules suggested the bifacial gain of over 20% could be achieved. Furthermore, the outdoor evaluation tests of bifacial modules with different ground conditions such as cement (reference), green paint, white paint and green artificial grass, were performed. It turned out white paint showed the best albedo and thus the highest power production, while green paint and artificial grass showed less power generation than cement ground.

PEMFC 고분자막의 화학적 내구성 평가시간 단축 (Reducing the Test Time for Chemical Durability of PEMFC Polymer Membrane)

  • 오소형;조원진;임대현;유동근;박권필
    • Korean Chemical Engineering Research
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    • 제59권3호
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    • pp.333-338
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    • 2021
  • 대형 상용차용 PEMFC 스택 내구성은 승용차용보다 5배 이상 되어야 한다. 승용차용 PEMFC 고분자막의 화학적 가속 내구성 평가(AST)를 대형 상용차용에 그대로 적용하면 AST 시간이 2,500시간 이상이 되는 문제점이 있다. DOE(Department of Energy)의 AST 시간을 단축시키기 위해 Cathode 가스로 공기대신 산소를 사용하여 고분자막의 화학적 내구성을 평가하였다. 본 연구에서는 Nafion XL을 고분자막으로 사용해 OCV, 90 ℃, RH 30%, H2 (Anode), 공기 또는 산소조건으로 가속 내구성을 평가하였다. DOE 내구 목표 기준 중 Short 저항 감소가 제일 빨리 나타났다. 공기대신 산소를 사용함으로써 전극 열화의 영향을 적게 받으면서, 고분자막의 열화 속도를 가속화시켜 고분자막 내구성 평가시간을 절반 이하로 단축시켰다.

분말소화기의 내부압력 변화에 따른 제3종 분말소화약제의 침강도 시험 (Analysis of the Sedimentation Status Test for Type-3 Dry Chemical Powder with Changes in Internal Pressure of the Dry Chemical Extinguisher)

  • 손주달;김서영;공하성
    • 대한안전경영과학회지
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    • 제25권1호
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    • pp.67-74
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    • 2023
  • This study aims to measure sedimentation status change with the changes in internal pressure for dry chemical extinguishers of various use periods and analyze the suitability of the fire extinguishers' performance criteria. When the internal pressure of the fire extinguisher is 0%, 2 out of 10 new dry chemical powders for the 5 elapsed years were noted to be suitable, including 3 recycled dry chemical powders with 5 elapsed years that were found eligible. One out of 10 new dry chemical powders for 10 elapsed years was shown as suitable. Also, one new dry chemical powder for 13 elapsed years was suitable. When the internal pressure of the fire extinguisher was 50%, all 10 out of 10 new dry chemical powders for 5 years, recycled one with 5 elapsed years, and a new one with 10 elapsed years were found to be suitable, while 9 new dry chemical powders for 13 years were shown as suitable. When the internal pressure of the fire extinguisher was normal, new ones with 5 elapsed years, recycled ones with 5 elapsed years, new ones with 10 elapsed years, and new ones with 13 elapsed years were all 10 out of 10 samples noted as suitable. In summarizing the experiment results, it was found that the sedimentation status, one of the fire extinguisher's physical properties experiments, affects the fire extinguisher's performance criteria rather than the change with use periods.

시너(thinner)의 물리화학적 특성과 랫트의 생식기에 미치는 영향 연구 (A Study on thinner's Physicochemical property and its effect on genital organ of rat)

  • 김현영;이성배;한정희;김태균;이정석;강민구;이채관
    • 한국산업보건학회지
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    • 제18권3호
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    • pp.224-238
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    • 2008
  • The aim of this study is to confirm the physicochemical property and hazard of thinner (012), which is a diluent of enamel paint used for floor coating for waterproofing and oil painting for the outer wall. The literatures of physicochemical property and hazard of thinner were surveyed and its physicochemical property were evaluated. And then, the inhalation toxicity of thinner affecting the central nervous system and reproductive organs in rats were examined by subchronic (6 h./day. 5 days/ week for 13 weeks) inhalation test. 1) According to the 13-week subchronic inhalation test, there were no significant changes in clinical test and body weight. However, a significant evidence of toxicity was observed in the hematological test and organ weight such as heart, kidney, liver and brain (p<0.01) in the 200 ppm and 1,000 ppm exposure groups in a dose response manner. In the histopathology analysis, there were no significant evidence of toxicity. Therefore, thinner was not classified as an organ targeted toxic agent. In case of Harmfulness, it could be classified as a chronic toxic agent 3($500 ppm/4hr, rat). 2) The reproductive toxicity such as extension of the period of estrous cycle, reduction of serum estradiol concentration and increase of frequency of the abnormal sperm was observed in the 1,000 ppm exposed animals. 3) The result of the physicochemical property of the test material showed that the specific gravity was 0.793, boiling point $155.8^{\circ}C$, steam pressure 2.1 kPa, ignition point $34.5^{\circ}C$, and spontaneous ignition point $280^{\circ}C$. The endothermic and exothermic values were 371.4 J/g and 159.1 J/g. respectively. The explosion limit was 214 mg/l. These data showed that thinner could be classified as an explosion agent level 1.2 and ignitive liquid agent 3 ($23-60^{\circ}C$) according to the notification No. 2008-1 of the Labor Ministry, "Classifying Standard of Chemical Materials."