• Title/Summary/Keyword: Chemical test

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An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part4: The Application of the JIS Rapid Test Method to the Several Domestic Reactive Aggregates) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제4보: 국내산 반응성 골재에 JIS 신속법 적용가능성))

  • 차태환;조원기;조일호;노재호;이양수;정재동;윤재환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.447-450
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    • 1994
  • The chemical method and mortar-bar method for identification of the susceptibility to Alkali-Aggregate Reaction (AAR) was established as KS method by referencing the ASTM methods. However, the chemical method requires skilled chemical engineers and aggregates are tested in very severe condition, and on the other hand, the mortar-bar method needs a long time of 3 or 6 months. Judging from this circumstance that the use of crushed stones are increased due to the shortage of natural aggregates, the development and standardization of a new rapid test method is considered essential. The purpose of this paper is to research for the possibility to apply the rapid method, instead of the chemical method and the mortar-bar method with using the several domestic crushed stones.

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Characteristics of TVOCs Emission Factors from Chemical and Natural Coating Materials (화학 및 천연페인트에서 발생되는 TVOCs의 방출강도 특성 연구)

  • Kim Shin Do;Kim Jeong Ho;Park Jin Soo;Lee Jeong Joo
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.487-492
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    • 2004
  • Building materials are composed of very complex chemical compounds, and these indoor building materials discharge very much Volatile Organic Compounds(VOCs). We performed the environmental chamber test to investigate the Total VOCs(TVOCs) emission characteristics and emission factors about chemical and natural coating materials. As the result, we concluded that TVOCs emission are high at initial time and decreased in course of time. Natural paint was low emission level for TVOCs than chemical paint by small chamber test. The TVOCs emission factor-time profile showed a good fit with the results from the measured and predicted value.

Kinetic Theory for Chemical Reactions in Liquids (용액중에서의 화학반응에 관한 동역학적 이론)

  • Kook Joe Shin
    • Journal of the Korean Chemical Society
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    • v.25 no.5
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    • pp.291-299
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    • 1981
  • A test particle kinetic theory for reaction dynamics in liquids is presented at the repeated ring collision level for the hard sphere model. A kinetic equation for the equilibrium time correlation function of the reactive test particle phase space density is derived and the rate kernel expression for the reversible chemical reaction of the type A +B ${\rightleftharpoons$ C + D in the presence of inert solvent S is obtained by the projection operator method.

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Polyol Synthesis of Ruthenium Selenide Catalysts for Oxygen Reduction Reaction

  • Lee, Ki-Rak;Woo, Seong-Ihl
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3145-3150
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    • 2010
  • Ruthenium catalysts modified by selenium have been introduced as alternative materials to Pt in Direct methanol fuel cells (DMFCs). RuSe nano-particles were synthesized on the Vulcan XC72R carbon supports via polyol method. The prepared catalysts were electrochemically and physically characterized by cyclic voltammetry (CV,) linear sweep voltammetry, methanol tolerance test, X-ray diffraction (XRD), Transmission electron microscopy (TEM), Energydispersive Spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). Increasing the Se concentration up to 20 at % increased the electro-catalytic activity for the oxygen reduction. By increasing Se amount, Ru metallic form on the surface was increased. The $Ru_{80}Se_{20}$/C catalysts showed the highest oxygen reduction reaction (ORR) activity and outstanding methanol tolerant property in half cell tests as well as single cell test.

Chemical Compatibility of Solidified Liner Materials (매립장 고화차수재의 화학용액과의 반응특성)

  • 정하익;조진우;임재상;김상길
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.343-346
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    • 2002
  • The chemical compatibility of leachate with the two natural materials was analyzed by performing the hydraulic conductivity test. The selected liner materials were natural marine clay and weathered soil sampled from Kimpo wastefill and Daehwa Dong, Kyonggi Do, respectively. PARAFIX, which is mainly composed of paraffin, cement, stearic acid, PVA etc., was used as solidifying agent. The chemical solutions used in the test were 10% acetic acid, 10% methanol, and real leachate from Kimpo wastefill and the results of tests were compared with that of distilled water. The results of tests show that hydraulic conductivity of solidified clay was increased slightly with permeation of acetic acid, methanol and the increase of hydraulic conductivity was not shown with permeation of leachate, distilled water and in case of weathered soil. Based on the tests, it is ascertained that the tested liner materials can be stable with the solution of low concentration.

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Evaluation of Chemical Resistance of Epoxy Resin Injection Type Leakage Repairing Materials Applied to Underground Concrete Structures (지하 콘크리트 구조물에 적용되는 에폭시 수지계 주입형 누수보수재료의 화학저항성능 평가)

  • Park, So-young;Kim, Soo-Yeon;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.41-42
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    • 2017
  • In this study, an investigation was made to study the chemical resistance performance of epoxy resin injection type leakage repair material used in the Korean construction market in accordance to the test method outlined in "ISO TS 16774, Part 2; Test Method for Chemical Resistance." This is a new standard document used for quality control method of injection type repair material used for leakage cracking of underground concrete structures. The results of this study can be expected to be utilized as reference data that can be used for quality improvement of the maintenance methods for future construction.

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Evaluation of Bifacial Si Solar Module with Different Albedo Conditions (양면수광형 실리콘 태양광 모듈의 바닥면 반사조건 변화에 따른 발전성능 평가)

  • Park, Dohyun;Kim, Minsu;So, Wonshoup;Oh, Soo-Young;Park, Hyeonwook;Jang, Sungho;Park, Sang-Hwan;Kim, Woo Kyoung
    • Current Photovoltaic Research
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    • v.6 no.2
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    • pp.62-67
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    • 2018
  • Multi-wire busbar-type bifacial n-type Si solar cells have been used for the fabrication of monofacial and bifacial photovoltaic (PV) module, where bifacial module was equipped with transparent backsheet while monofacial module was prepared using white backsheet. The comparison of six-day accumulated power production obtained from outdoor test under gray cement ground conditions using 60cell monofacial and bifacial PV modules suggested the bifacial gain of over 20% could be achieved. Furthermore, the outdoor evaluation tests of bifacial modules with different ground conditions such as cement (reference), green paint, white paint and green artificial grass, were performed. It turned out white paint showed the best albedo and thus the highest power production, while green paint and artificial grass showed less power generation than cement ground.

Reducing the Test Time for Chemical Durability of PEMFC Polymer Membrane (PEMFC 고분자막의 화학적 내구성 평가시간 단축)

  • Oh, Sohyeong;Cho, Wonjin;Lim, Daehyeon;Yoo, Donggeun;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.333-338
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    • 2021
  • The durability of the PEMFC stack for large commercial vehicles should be more than 5 times that for passenger vehicles. If the Chemical Accelerated Stress Test (AST) of PEMFC(Proton Exchange Membrane Fuel Cells) membrane for passenger cars is applied as it is for large commercial vehicles, there is a problem that the AST time becomes more than 2,500 hours. In order to shorten the AST time of DOE (Department of Energy), the chemical durability of the polymer membrane was evaluated using oxygen instead of air as a cathode gas. In this study, Nafion XL was used as a polymer membrane to evaluate accelerated durability under OCV, 90?, RH 30%, H2/(air or oxygen) conditions. Among the DOE membrane durability target criteria, the decrease rate of short resistance was the fastest. By using oxygen instead of air, the degradation rate of the polymer membrane was accelerated while being less affected by electrode deterioration, reducing the polymer membrane durability evaluation time to less than half.

Analysis of the Sedimentation Status Test for Type-3 Dry Chemical Powder with Changes in Internal Pressure of the Dry Chemical Extinguisher (분말소화기의 내부압력 변화에 따른 제3종 분말소화약제의 침강도 시험)

  • Ju-Dal Son;Seo-Young Kim;Ha-Sung Kong
    • Journal of the Korea Safety Management & Science
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    • v.25 no.1
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    • pp.67-74
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    • 2023
  • This study aims to measure sedimentation status change with the changes in internal pressure for dry chemical extinguishers of various use periods and analyze the suitability of the fire extinguishers' performance criteria. When the internal pressure of the fire extinguisher is 0%, 2 out of 10 new dry chemical powders for the 5 elapsed years were noted to be suitable, including 3 recycled dry chemical powders with 5 elapsed years that were found eligible. One out of 10 new dry chemical powders for 10 elapsed years was shown as suitable. Also, one new dry chemical powder for 13 elapsed years was suitable. When the internal pressure of the fire extinguisher was 50%, all 10 out of 10 new dry chemical powders for 5 years, recycled one with 5 elapsed years, and a new one with 10 elapsed years were found to be suitable, while 9 new dry chemical powders for 13 years were shown as suitable. When the internal pressure of the fire extinguisher was normal, new ones with 5 elapsed years, recycled ones with 5 elapsed years, new ones with 10 elapsed years, and new ones with 13 elapsed years were all 10 out of 10 samples noted as suitable. In summarizing the experiment results, it was found that the sedimentation status, one of the fire extinguisher's physical properties experiments, affects the fire extinguisher's performance criteria rather than the change with use periods.

A Study on thinner's Physicochemical property and its effect on genital organ of rat (시너(thinner)의 물리화학적 특성과 랫트의 생식기에 미치는 영향 연구)

  • Kim, Hyeon-Yeong;Lee, Sung-Bae;Han, Jeong-Hee;Kim, Tae-Gyun;Lee, Jung-Suk;Kang, Min-Gu;Lee, Chae-Kwan
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.18 no.3
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    • pp.224-238
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    • 2008
  • The aim of this study is to confirm the physicochemical property and hazard of thinner (012), which is a diluent of enamel paint used for floor coating for waterproofing and oil painting for the outer wall. The literatures of physicochemical property and hazard of thinner were surveyed and its physicochemical property were evaluated. And then, the inhalation toxicity of thinner affecting the central nervous system and reproductive organs in rats were examined by subchronic (6 h./day. 5 days/ week for 13 weeks) inhalation test. 1) According to the 13-week subchronic inhalation test, there were no significant changes in clinical test and body weight. However, a significant evidence of toxicity was observed in the hematological test and organ weight such as heart, kidney, liver and brain (p<0.01) in the 200 ppm and 1,000 ppm exposure groups in a dose response manner. In the histopathology analysis, there were no significant evidence of toxicity. Therefore, thinner was not classified as an organ targeted toxic agent. In case of Harmfulness, it could be classified as a chronic toxic agent 3($500 ppm/4hr, rat). 2) The reproductive toxicity such as extension of the period of estrous cycle, reduction of serum estradiol concentration and increase of frequency of the abnormal sperm was observed in the 1,000 ppm exposed animals. 3) The result of the physicochemical property of the test material showed that the specific gravity was 0.793, boiling point $155.8^{\circ}C$, steam pressure 2.1 kPa, ignition point $34.5^{\circ}C$, and spontaneous ignition point $280^{\circ}C$. The endothermic and exothermic values were 371.4 J/g and 159.1 J/g. respectively. The explosion limit was 214 mg/l. These data showed that thinner could be classified as an explosion agent level 1.2 and ignitive liquid agent 3 ($23-60^{\circ}C$) according to the notification No. 2008-1 of the Labor Ministry, "Classifying Standard of Chemical Materials."