• Title/Summary/Keyword: Chemical surface treatment

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Experimental study on improving bamboo concrete bond strength

  • Mali, Pankaj R.;Datta, Debarati
    • Advances in concrete construction
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    • v.7 no.3
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    • pp.191-201
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    • 2019
  • Bamboo concrete bond behaviour is investigated through pullout test in this work. The bamboo strip to be used as reinforcement inside concrete is first treated with chemical adhesive to make the bamboo surface impermeable. Various surface coatings are explored to understand their water repellant properties. The chemical action at the bamboo concrete interface is studied through different chemical coatings, sand blasting, and steel wire wrapping treatment. Whereas mechanical action at the bamboo concrete interface is studied by developing mechanical interlock. The result of pullout tests revealed a unique combination of surface treatment and grooved bamboo profile. This combination of surface treatment and a grooved bamboo profile together enhances the strength of bond. Performance of a newly developed grooved bamboo strip is verified against equivalent plain rectangular bamboo strip. The test results show that the proposed grooved bamboo reinforcement, when treated, shows highest bond strength compared to treated plain, untreated plain and untreated grooved bamboo reinforcement. Also, it is observed that bond strength is majorly influenced by the type of surface treatment, size and spacing of groove. The changes in bamboo-concrete bond behavior are observed during the experimentation.

The Study on the Surface State of Mg2Ni Exposed to Air by a Chemical Treatment (화학처리방법을 이용한 공기중에 노출된 Mg2Ni의 표면상태에 관한 연구)

  • Han, Jeong-Seop
    • Transactions of the Korean hydrogen and new energy society
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    • v.6 no.2
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    • pp.91-100
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    • 1995
  • To investigate the surface state of $Mg_2Ni$ which was exposed to the air, a chemical treatment was undertaken with $H_2SO_4$ solution. During chemical treatment, the change of pH was measured continuously and the chemically treated specimen was hydrided to study the effect of chemical treatment on the hydrogenation. The pH changing behavior with the various $H_2SO_4$ concentration appeared very diffemrently. Especially in the solution including 3CC $H_2SO_4$, the behavior of pH change can be divided 3 steps. It is also shown that the $Mg_2Ni$ chemically treated with $H_2SO_4$ can be hydrided even under room temperature. By the SEM observation the was reasion that after chemical treatment the surface of a particle was covered with Ni layer.

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Development of An Eco-friendly Surface Treatment Process for the Design of the Al Lead Tab in Lithium-ion Batteries

  • Cheon, Jeongsuk;Kim, Jongwon
    • Journal of the Korean Chemical Society
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    • v.64 no.3
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    • pp.153-158
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    • 2020
  • With the recent popularity of mobile devices, the demand for lithium-ion batteries is increasing. In this study, the surface treatment process for the development of the Al (aluminum) lead tab for positive electrode, a key component of the pouch-type lithium-ion battery, was investigated. Anodizing and sealing processes were tested as surface treatment techniques. It was found that only a sealing process is needed to obtain sufficient adhesive strength. In the present study, an adhesive strength of 17 N/12 mm was achieved by degreasing and etching pretreatment, followed by a sealing process of 10 min duration. This adhesive strength was greater than that achievable using Cr (chromium) surface treatment. Using various surface analysis techniques, the shape and composition of the surface before and after being subjected to the surface treatment were compared and analyzed. The results of this study are expected to contribute to the development of an eco-friendly lead tab.

Study on the Effect of Surface Finishing Methods on Pitting Corrosion Behavior of 304 Stainless Steel Alloy

  • Yun, JunTae;kim, Se-Woong;Hwang, HyangAn;Toor, Ihsan-Ul-Haq;Shon, MinYoung
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.209-216
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    • 2009
  • In this study the effect of different surface finishing techniques on the pitting corrosion behaviour of a commercial 304 stainless steel alloy was investigated. Surface finishing methods were divided into two categories, i.e. mechanical and chemical. Mechanical treatment methods include power tooling such as grinding, emery paper brushing, stainless steel wire brushing and stainless steel shot blasting. Chemical treatment methods include chemical passivation (phosphoric acid, citric acid, nitric acid) and electro-cleaning (phosphoric acid and citric acid). Potentiodynamic polarization experiments were carried out in 3.5 wt. % NaCl solution at room temp. (20 $^{\circ}C$). The results showed that chemical treatment methods improved the corrosion resistance of stainless steel 304, measured in terms of pitting potential ($E_{pit}$). Corrosion resistance of the specimens was increased in the order of; electro-cleaning > manual passivation > mechanical cleaning. Surface of electro-cleaned specimens was smoother than rest of the surface treatment methods. Chrome content in chemically treated specimens was higher than in mechanically treated specimens as shown by EDX analysis.

A Study on the Surface Analysis of Plasma-Treated PET Film (플라즈마 처리된 PET 필름의 표면분석에 관한 연구)

  • Lim Kyung-Bum;Choi Hoon-Young;Lee Seok-Hyun;Lee Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.12
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    • pp.596-600
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    • 2004
  • In this study, the surface properties of PET film were analyzed after plasma surface treatment. After plasma treatment of surface roughness and XPS were evaluated to analyze the chemical property, while the surface potential decay and surface resistance rate was measured to analyze the electric관 characteristic. When plasma discharge treatment was conducted for less than 10 minutes, the electrical insulating property was improved by evaporation of low molecular weight materials and cleaning of surface. However, when the treatment was conducted for more than 10 minutes, the insulating property was decreased due to excessive discharge energy. Analyses of chemical characteristics showed that 10-minute treatment resulted in increase of C-O and O=C-O bonds. However, when treated for more than 10 minutes. they were relatively decreased.

Enhancement of Microbial Immobilization on the Surface of a Reticulated PU-g-PAAc Foam prepared through Graft Copolymerization induced by Atmosoheric Pressure Plasma Treatment (대기압 플라즈마 유도 그라프트 공중합으로 합성된 망상형 PU-g-PAAc 폼의 미생물 고정화능 향상)

  • Myung Sung Woon;Jang Yung Mi;Nam Ki Chun;Choi Ho Suk;Cho Dae Chul
    • KSBB Journal
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    • v.19 no.5
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    • pp.399-405
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    • 2004
  • A reticulated PU-g-PAAc foam was modified through the surface treatment of PU foam by one atmospheric pressure plasma. The synthesized PU-g-PAAc foam was prepared for the purpose of immobilizing microbial organisms. We also attempted different plasma treatment methods including simple plasma treatment, plasma induced grafting and plasma induced grafting followed by plasma re-treatment. The effect of grafting on equilibrium water content (EWC) of PU forms was examined by swelling measurements. Adhesion test was performed to investigate the effect of different plasma treatment methods on the improvement of microbial immobilization. Two foams modified by plasma induced grafting and plasma re-treatment after grafting showed 2.7 and 3.0 fold higher microbial immobilization than unmodified one, respectively. Meanwhile, simple plasma treatment showed a little enhancement. FT-IR analysis of each sample verified the contribution of surface functional groups on the enhancement of microbial immobilization. SEM observation confirmed microbial adherence.

Modified membrane with antibacterial properties

  • Aryanti, P.T.P.;Sianipar, M.;Zunita, M.;Wenten, I.G.
    • Membrane and Water Treatment
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    • v.8 no.5
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    • pp.463-481
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    • 2017
  • Bacteria have been considered as a major foulant that initiates the formation of biofilm on the polymeric membrane surface. Some polymeric membranes are naturally antibacterial and have low fouling properties, however, numerous efforts have been devoted to improve their antibacterial performance. These modifications are mostly carried out through blending the membrane with an antibacterial agent or introducing the antibacterial agent on the membrane surface by chemical grafting. Currently, a significant number of researches have reported nanocomposite membrane as a new approach to fabricate an excellent antibacterial membrane. The antibacterial nanoparticles are dispersed homogenously in membrane structure by blending method or coating onto the membrane surface. Aim of the modifications is to prevent the initial attachment of bacteria to membrane surface and kill bacteria when attached on the membrane surface. In this paper, several studies on antibacterial modified membranes, particularly for water treatment, will be reviewed comprehensively. Special attention will be given on polymeric membrane modifications by introducing antibacterial agents through different methods, such as blending, grafting, and coating.

Surface Treatment of Automotive Cast Parts of Magnesium Alloy

  • Sim, Yangjin;Kim, Jongmyung
    • Corrosion Science and Technology
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    • v.2 no.2
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    • pp.102-108
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    • 2003
  • The surface treatments. Chrome/Manganese and Modified Chrome Pickle, that are treated to improve the anti-corrosion property which is needed to increased the probability of prototype product enabled the sand cast Magnesium test specimens to have better corrosion resistance than non-treated one. Sand cast Magnesium specimens which was treated only with chemical conversion coating had same corrosion resistance with the Steel specimens plated by Zinc, and the another one that had the finishing treatment(painting) worked on the chemical surface treatment had the corrosion resistance property to meet to FPO-3 requirement. We also investigated the multiple finishing system(chemical surface treatment + 3 coating) to test the severe condition that magnesium should to endure.

Characterization of Plasma with Heating Treatment of ITO on the Efficiency of Polymer Solar Cells

  • Kim, Jung-Woo;Kim, Nam-Hun;Kim, Hyoung-Sub;Jung, Dong-Geun;Chae, Hee-Yeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.301-301
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    • 2010
  • In order to enhance the efficiency of the organic solar cells, the effects of plasma surface treatment with using $CF_4$ and $O_2$ gas on the anode ITO were studied. The polymer solar cell devices were fabricated on ITO glasses an active layer of P3HT (poly-3-hexylthiophene) and PCBM ([6,6]-phenyl C61-butyric acid methyl ester) mixture, without anode buffer layer, such as PEDOT:PSS layer. The metallic electrode was formed by thermally evaporated Al. Before the coating of organic layers, ITO surface was exposed to plasma made of $CF_4$ and $O_2$ gas, with/without heat treatment. In order to identify the effect the surface treatment, the current density and voltage characteristics were measured by solar simulator and the chemical composition of plasma treated ITO surface was analyzed by using X-ray photoelectron spectroscopy(XPS). In addition, the work function of the plasma treated ITO surface was measured by using ultraviolet photoelectron spectroscopy(UPS). The effects of plasma surface treatment can be attributed to the removal organic contaminants of the ITO surface, to the improvement of contact between ITO and buffer layer, and to the increase of work function of the ITO.

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Surface modification of polymeric membranes for low protein binding

  • Higuchi, Akon;Tamai, Miho;Tagawa, Yoh-Ichi;Chang, Yung;Ling, Qing-Dong
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.103-120
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    • 2010
  • Surface modification of microfiltration and ultrafiltration membranes has been widely used to improve the protein adsorption resistance and permeation properties of hydrophobic membranes. Several surface modification methods for converting conventional membranes into low-protein-binding membranes are reviewed. They are categorized as either physical modification or chemical modification of the membrane surface. Physical modification of the membrane surface can be achieved by coating it with hydrophilic polymers, hydrophilic-hydrophobic copolymers, surfactants or proteins. Another method of physical modification is plasma treatment with gases. A hydrophilic membrane surface can be also generated during phase-inverted micro-separation during membrane formation, by blending hydrophilic or hydrophilic-hydrophobic polymers with a hydrophobic base membrane polymer. The most widely used method of chemical modification is surface grafting of a hydrophilic polymer by UV polymerization because it is the easiest method; the membranes are dipped into monomers with and without photo-initiators, then irradiated with UV. Plasma-induced polymerization of hydrophilic monomers on the surface is another popular method, and surface chemical reactions have also been developed by several researchers. Several important examples of physical and chemical modifications of membrane surfaces for low-protein-binding are summarized in this article.