• Title/Summary/Keyword: Chemical substances

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Experiment on the Feasibility of Cleaning Building Pipelines using Ultrasonic Cavitation

  • Jo, Jae-Hyun;Lee, Ung-Kyun;Kim, Jae-Yeob;Lee, Sungchul;Kim, Kukhyun
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.295-303
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    • 2022
  • Residential heating systems in South Korea are largely based on the use of ondol pipelines. Heat is transferred to the floor by passing hot water through a metal or plastic pipe buried within the concrete of the floor. Consequently, it is difficult to clean the inside of these pipes after installation. Over time, foreign substances such as scale accumulate in the pipe when the ondol heating method is used for an extended period. Therefore, in the past, pipes were cleaned by removing foreign substances attached to the inside surfaces of the pipes using high-pressure water or by disassembling the pipes and removing foreign substances with chemical agents. Recently, a method for removing foreign substances through the cavitation effect of ultrasound has been proposed. This idea might lead to the development of new technologies for cleaning pipe interiors. Consequently, this study investigated the use of ultrasound to clean pipes embedded in concrete. In this study, devices that generated ultrasonic waves with various frequencies and directions were prepared. After preparing arbitrarily contaminated pipes, the appropriate frequency, output strength, and output direction for each foreign substance were determined through repeated experiments. The results of this experiment could provide important information for future methods of cleaning the interior of ondol piping systems.

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A Case Study on Health Impact Assessment from Petroleum Refinery Plant Operation - Human Risk Assessment due to Chemicals Inhalation - (석유정제시설 운영에 대한 건강영향평가 사례 연구 - 화학물질 흡입에 따른 인체 위해도 평가 -)

  • Myung, Nho-Il;Lee, Young-Soo;Shin, Dae-Yewn
    • Journal of Environmental Impact Assessment
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    • v.19 no.3
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    • pp.259-270
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    • 2010
  • We conducted human risk assessment for exposure to inhalation of chemical substances emitted from the storage tanks of petroleum refineries. To assess human risk, this study calculated chemical emissions from the external floating roofs on storage tank at petroleum refineries, as well as concentrations thereof in the ambient air using the K-SCREEN model, and then determined risk in accordance with the Reference Concentration (RfC) values and Inhalation Unit Risk criteria developed by the US Environmental Protection Agency. The results indicated that non-carcinogenic chemicals have a hazard quotient of less than 1, meaning they have an insignificant effect on human health for residential areas near the storage tanks. Among the known carcinogens, the hazard risk for benzene slightly exceeded $10^{-6}$, indicating the need for corrective reduction measures. The methodology for health impact assessment devised herein provides findings useful in decision making for policy makers and the general public with respect to construction of industrial complexes. However, the methodology proposed herein does have limitations, including discrepancy in results induced by use of U.S. data (due to the lack of usable domestic data). More systematic studies from related researchers will be needed to address these issues and produce more reliable outcomes.

The Search for Naturally Occurring Herbicidal Compounds - II. Isolation of Pinoresinol from Rhathiolepis ovata Briat and Its Biological Activity (천연에서부터 제초활성물질의 탐색 - 제2보 둥근잎가정큰나무(Rhathiolepis ovata Briat)로 부터 Pinoresinal의 단리 및 생물활성)

  • Ahn, J.W.;Choi, J.S.;Cho, K.Y.
    • Korean Journal of Weed Science
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    • v.9 no.1
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    • pp.76-79
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    • 1989
  • As a result of screening search for biologically active substances to weed seeds among higher plants, MeOH extract from Rhathiolepis ovata Briat was found to inhibit germination of test weeds considerably. In the course of purifying the active substances, pinoresinol which showed very similar behavior with the active fraction on various chromatographies, was isolated from the same source, spectrally identified and bioassayed. Pinoresinol exhibited germination inhibitory activity against the common purslane (Portulaca oleracea L.) only ; the inhibitory effect was about 55% at concentration of 5 mg/ml.

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Effect of solids retention time on membrane fouling in membrane bioreactors at a constant mixed liquor suspended solids concentration

  • Hao, L.;Liss, S.N.;Liao, B.Q.
    • Membrane and Water Treatment
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    • v.8 no.4
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    • pp.337-353
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    • 2017
  • Membrane fouling at different solids retention times (SRT) (7, 12 and 20 days) was studied under well-controlled conditions in a laboratory-scale aerobic submerged membrane bioreactor under constant biomass concentration using a synthetic high strength wastewater. An increase in SRT was found to improve membrane performance and this correlated to changes in the total production of bound extracellular polymeric substances (EPS), and the composition and properties of bound EPS using X-ray photoelectron spectroscopy (XPS) and Fourier transform-infrared spectroscopy (FTIR) and floc sizes. A larger amount of total bound EPS was found at the lowest SRT (7 days) tested but the ratio of proteins (PN) to carbohydrates (CH) in bound EPS increased with an increase in SRT. Similarly, the quantity of soluble microbial products (SMP) decreased with an increase in SRT and the SMP PN/CH ratio increased with an increase in SRT. SMP concentrations positively correlated to the percentage of membrane pore blocking resistance. The quantity of total bound EPS and total SMP positively corresponded to the membrane fouling rate, while the PN/CH ratio in the bound EPS and SMP negatively correlated to the membrane fouling rate. The results show that both the quantity and composition of bound EPS and SMP and floc sizes are important in controlling membrane fouling.

What must be done to prevent another humidifier disinfectant disaster?

  • Lee, Jong-Hyeon
    • Environmental Analysis Health and Toxicology
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    • v.31
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    • pp.24.1-24.7
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    • 2016
  • The humidifier disinfectant disaster (HDD) was not a simple poisoning accident by biocides, but a singular disaster in history created by chemicals in household products. This disaster was a result of the failure of a system for the management of chemical and product safety. Since the management authority for chemical usage safety is different from those for chemical safety in products, many blind areas for chemical safety management in products still remain. The 'Act on the Registration and Evaluation, etc. of Chemical Substances (ARECS)' or the new 'Biocidal Product Act' must not only address the blind areas in the management system for chemical and product safety, but also prevent a second HDD. To prevent another HDD, an integrated registration, evaluation, and management system for chemicals and consumer products must be incorporated into the 'ARECS' as an essential part for chemical safety in consumer products.

Anti-norovirus activity of natural compounds and its potential in food application (항노로바이러스 천연물을 이용한 식품개발)

  • Kim, Yeon-Ji;Lee, Jeong Su;Joo, In Sun;Lee, Sung-Joon
    • Food Science and Industry
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    • v.50 no.1
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    • pp.67-73
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    • 2017
  • Control of food pathogens is critical in food safety field. Norovirus is one of the major causes of gastroenteritis and food poisoning worldwide, however, currently, there is not a vaccine or a specific drug available for its treatment. There are several methods to inactivate norovirus during food processing by chemical and physical treatments, however, the use of natural substance has been suggested as an optional strategy due to their safety and consumer preference. In this study supported by Ministry of Food and Drug Safety in Korea, we identified novel plant-derived substances with significant anti-norovirus activities. The aim of this project was to determine the antiviral activity of a wide range of natural substances, including plant-derived extracts and essential oils, using a norovirus surrogate system, human norovirus replicon-bearing cells, and mouse in vivo experiments. During the activity screening test, we identified novel anti-norovirus substances or oils using plaque assay with MNV-1. Six selected substances were formulated into an optimum mixture and used as an ingredient for salad sauce of which anti-novovirus activity was confirmed(pending for patent and paper submission). The potential application of selected natural substances as a metal surface sanitizer was also tested. Interestingly, the mixture of selected natural compounds showed a significant inhibitory effect against norovirus. These results suggest that these substances may be used as food ingredient with anti-norovirus antivity or components for surface sanitizers to prevent norovirus contamination.

A Statistical Assessment of Increasing Tidal Mixing Effects on Water Quality in the Shiwha Coastal Reservoir (시화호 해수유통량 증대에 따른 통계학적 수질 영향 분석)

  • Lee, Bum-Yeon;Lee, Chang-Hee
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.425-432
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    • 2021
  • A tidal power plant (TPP) has been in operation since the end of 2011 to improve the water quality of Shihwa Coastal Reservoir (SCR). Tidal mixing rate increased 5.6 times after the TPP operation so that in this study, its effects on water quality was assessed through statistical analysis of long-term water quality monitoring data. It was found that the increased tidal mixing contributed to solving the hypoxia problem in the bottom water by preventing the summer stratification. The analysis also showed that the increased tidal mixing had different effects depending on the relative concentration difference for each water quality substances between the SCR and the outside of SCR. The average concentrations of some substances (chemical oxygen demand, total phosphorus, chlorophyll-a) with higher concentrations than the outside of SCR decreased due to the dilution effect, but the other substances (total nitrogen, dissolved inorganic nitrogen, dissolved inorganic phosphorus) with lower concentrations compared to the outside ones increased on the contrary. Factor analysis also showed a consistent result that the first factor accounting for the water quality was changed from the organic-related substances to the nutrient-related substances after the increased tidal mixing. These results imply that the focus of future water quality management needs shifting from the organic substances to the nutrients, particularly dissolved inorganic nutrients. Considering the effect of inflow seawater on the nutrients, the management area should be extended to cover not only SCR but also a certain area outside of SCR.

A Study on Prevention Measure Establishment through Cause Analysis of Chemical-Accidents (화학사고 원인분석을 통한 예방대책 수립에 관한 연구)

  • Lee, Hyung-Sub;Yim, Ji-Pyo
    • Journal of the Korean Society of Safety
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    • v.32 no.3
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    • pp.21-27
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    • 2017
  • Even if several chemical accident prevention systems such as PSM(Process Safety Management), RMP(Risk Management Plan), etc. have been carried out, many chemical accidents have still occurred at industrial plants in Korea. We describe the status of chemical industry and the trend of occurrence of chemical accidents in Korea. And this paper analyzes the recent chemical accidents in eight ways. These ways include chemical accident forms, ignition sources, sources of chemical equipment, human vs equipment/material causes, worker's working situation, employee scale, hazardous substances, week & time, fatalities of manufacture & contractor's workers. Finally we proposes the four representative prevention measures brought to result of cause analysis by accident statistics.

Alteration of Physical and chemical Characteristics of Waterlogged Archaeological Woods After Cleaning (세척 후 수침고목재의 물리.화학적 특성 변화)

  • Cha, Mi-Young;Lee, Kwang-Ho;Kim, Yoon-Soo
    • Journal of Conservation Science
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    • v.19
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    • pp.19-30
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    • 2006
  • Alteration of physical and chemical characteristics and the effect of removal of mineral substances in waterlogged archaeological woods by different cleaning processes were examined using oak wood(Quercus spp.) that was excavated from wetland near Gwangju, Korea. Cleaning methods employed in the present work were (1) tools, (2) deaeration, (3) EDTA and (4) ultrasonic cleaning, which are being currently applied in the field of preservation treatment. Cleaning process were performed independently or continuously. Composition of mineral substances in the waterlogged archaeological wood was almost same as the that of soil in which waterlogged archaeological woods were buried. In case of independent cleaning, tools cleaning efficiently removed the mineral substances on surface. Surface color become brighter after cleaning with EDTA. In contrast, deaeration and ultrasonic cleaning did not show any significant removal of mineral substances. In continuous cleaning process, tool cleaning as the first step treatment showed the same effect as shown in independent cleaning. Although deaeration as the second step cleaning did not remove the mineral substances, it could be assumed to contribute the infiltration of dimensional agents by homogenization of wood. EDTA treatment (the third step cleaning) removed the iron(Fe) and increased the whiteness of wood color. The ultrasonic treatment (the fourth step cleaning) removed the sodium(Na) remained after EDTA treatment and the fine mineral substances.

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Emission Factors of Chemical Substances and the Abatement Policies in Korea Industries (화학물질 배출량 변동 요인과 배출저감 정책의 조합)

  • Rhee, Hae-Chun
    • Environmental and Resource Economics Review
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    • v.18 no.4
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    • pp.653-693
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    • 2009
  • Using the Korean environmental input output analysis, this paper provides the emission intensities of the chemicals, especially, the toxic and carcinogenic substances, by linking the structure of demand, and the policy mix to abate these substances emissions. Acording to the results, Industries with the highest total emission intensities(TEI) of toxic substances are ranked : Printing and reproduction of recorded media(21), Other transportation equipment(26), Pulp and paper(11), Leather and fur products(9), Fiber yarn and fabrics(7). And the highest TEI of carcinogenic substances are Wood and wooden products(10), Motor vehicles and parts(25), Plastic and rubber products(15), Audio, video and communications equipment(23), etc.. The economic factors of changing these emissions are emission intensities and final demands. The effective combinations of policy instruments to abate these emissions are varied by the industries and substances. For example, Government need to execute the effective TEI management in the Fiber yarn and fabrics(7) sector, and, in furniture(27) sector, the reduction of final demand is more effective.

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