• Title/Summary/Keyword: Chemical structure

Search Result 7,781, Processing Time 0.039 seconds

Root Morphology of Norway Spruce (Picea abies [L.] Karst.) in the Differently Acidified Forest Soils (토양(土壤) 산성화(酸性化) 정도(程度)에 따른 독일가문비나무(Picea abies [L.] Karst.))

  • Lee, Do-Hyung
    • Journal of Korean Society of Forest Science
    • /
    • v.89 no.5
    • /
    • pp.677-684
    • /
    • 2000
  • This study was conducted to investigate the relationship of development of root and soil condition and also to elucidate the difference between stands for mechanical and physical stability according to distribution of roots in the Norway Spruce (Picea abies [L.] Karst.) stands of 30 to 40 year of ages with different soil condition. In the root structure, remarkably different root pattern was shown among the three stands; Eberg$\ddot{o}$tzen stand showed large number f roots with much fine roots which deeply in vertical direction while Barbis stands had thicker root and small number of root than Eberg$\ddot{o}$tzen stand. The Weidenbrunnen stand showed differently half-vertical and plate root structure and the root developed not to be deeply compared to the other two stands. In the total number of root, Eberg$\ddot{o}$tzen stand had the most number of 74 and Barbis stand 33, Weidenbrunnen stand 57 respectively. Eberg$\ddot{o}$tzen stand had much more number of vertical root with 57 than the other two stand; Barbis 21 and Weidenbrunnen 36. In the total length of root, Weidenbrunnen stand showed to be longer than the other two stands and the length of horizontal root also showed longer. Regarding to the rates of horizontal root against vertical root, Eberg$\ddot{o}$tzen stand showed comparatively higher value as 1,2 than other two stands(0.5). In the total weight of root, Weidenbrunnen stand showed very high value compared with the other stands and ratio of vertical root against horizontal root was 0,16 which is very lower than the other two stands(0,4). The remarkable differences of root pattern of Norway spruce stands appeared in this study are through to be caused more by chemical property of soil such as acidity den the mechanical or physical factor of soil conditions.

  • PDF

Characteristics of Fish Community in Gap Stream by Habitat Type (서식처 유형에 따른 갑천의 어류군집 특성)

  • Lee, Dong-Jun;Byeon, Hwa-Kun;Choi, Jun-Kill
    • Korean Journal of Ecology and Environment
    • /
    • v.42 no.3
    • /
    • pp.340-349
    • /
    • 2009
  • The natural type section of Gap Stream was divided into 7 sites, such as, closed pool, runs, riffle, opened pool, pool, reek-scattered riffle, and Dam-type pool. The ecological characteristics of fish community at each site was examined from April, 2007 to October, 2008. During the survey period, 29 species belonging to 8 families were collected, and Carassius auratus (St. 1), Coreoleuciscus splendidus (St. 3), Acheilognathus lanceolatus (St. 4) and Zacco platypus (St. 2, 5, 6, 7) were characteristic species that represent each habitat. The species of C. auratus preferred physical habitat with sand-bottom pool, moderate depth of 65$\sim$90 cm, and stagnant water. The species of C. splendidus mainly preferred physical habitat with cobbles and pebbles are scattered riffles (St. 3), moderate depth of 65$\sim$90 cm, and flow velocity is 0.14$\sim$0.85 m $sec^{-1}$. It also preferred where concentration of BOD, COD, TN, TP and SS is low and DO's value is high, because the flow velocity is fast. A. lanceolatus preferred where the depth of water is low (3$\sim$44 cm) like an opened pool (St. 4) and the flow velocity is slow (0.01$\sim$0.02 m $sec^{-1}$). Z. platypus dominated in a variety of habitats such as runs (St. 2), pool (St. 5), rock-scattered riffles (St. 6) and D-type pool (St. 7), and it preferred places where flow is abundant and riverbed structure is diverse. On the other hand, 4 individuals of Iksookimia choii appeared at reek-scattered riffles (St. 6). I. choii appeared in this research lived in where the width of river is 24 m, the depth of water is 3$\sim$35 cm and the flow velocity is 0.01$\sim$0.49 m $sec^{-1}$, and riverbed structure was diversely formed with boulder to sand. Also, water temperature, EC, BOD, COD, TN and TP was low, but concentrations of DO and SS were high comparatively. Therefore, it seems that I. choii can live only in physical and chemical environment with similar conditions.

An Experimental Study on Evaluation of Axially Compressive Buckling Strength of Corroded Temporary Steel (부식 손상된 가시설 강재의 축압축 좌굴강도 추정에 관한 실험적 연구)

  • Kim, In Tae;Lee, Myoung Jin;Shin, Chang Hee
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.15 no.6
    • /
    • pp.135-146
    • /
    • 2011
  • Steel structures have been generally painted to prevent corrosion damage. However, the painted film is deteriorated with increase in service life, and then corrosion damage resulting in cross sectional area occurs on steel surface. As a result, the buckling strength of steel structures can be decreased due to the corrosion damages. The evaluation method of the axial buckling strength of columns about a variety of section shapes and supporting conditions have been presented, but evaluation method of buckling strength about irregular nonprismatic columns is not established. In this study, the axial buckling strength of corroded steels was evaluated based on the buckling test results of corroded steel specimens that were cut off at a temporary steel structure. The corroded specimens were picked up total 10 specimens according to various slenderness ratio from the web of a temporary structure's main beam. The length of specimens is 200, 300, 400, 500 and 600mm respectively. The rust productions were removed by the chemical treatment. Then, the surface geometry was measured at intervals of $1{\times}1mm$ by using the optical 3D digitizing system, and the residual thickness of the specimens was calculated. The axial buckling test was performed on 10 corroded specimens and 12 non-corroded specimens under the fixed-fixed support condition. From the test results, the effect of corrosion damages on axial buckling load was investigated. Regardless of corrosion damage degree, the axial buckling strength of corroded specimens and non-corroded specimens was evaluated identically by using minimum average residual thickness or average residual thickness to minus its standard deviation. Reasonable measuring intervals of residual thickness was proposed by using the results to apply for practical works.

Interpreting Bounded Rationality in Business and Industrial Marketing Contexts: Executive Training Case Studies (집행관배훈안례연구(阐述工商业背景下的有限合理性):집행관배훈안례연구(执行官培训案例研究))

  • Woodside, Arch G.;Lai, Wen-Hsiang;Kim, Kyung-Hoon;Jung, Deuk-Keyo
    • Journal of Global Scholars of Marketing Science
    • /
    • v.19 no.3
    • /
    • pp.49-61
    • /
    • 2009
  • This article provides training exercises for executives into interpreting subroutine maps of executives' thinking in processing business and industrial marketing problems and opportunities. This study builds on premises that Schank proposes about learning and teaching including (1) learning occurs by experiencing and the best instruction offers learners opportunities to distill their knowledge and skills from interactive stories in the form of goal.based scenarios, team projects, and understanding stories from experts. Also, (2) telling does not lead to learning because learning requires action-training environments should emphasize active engagement with stories, cases, and projects. Each training case study includes executive exposure to decision system analysis (DSA). The training case requires the executive to write a "Briefing Report" of a DSA map. Instructions to the executive trainee in writing the briefing report include coverage in the briefing report of (1) details of the essence of the DSA map and (2) a statement of warnings and opportunities that the executive map reader interprets within the DSA map. The length maximum for a briefing report is 500 words-an arbitrary rule that works well in executive training programs. Following this introduction, section two of the article briefly summarizes relevant literature on how humans think within contexts in response to problems and opportunities. Section three illustrates the creation and interpreting of DSA maps using a training exercise in pricing a chemical product to different OEM (original equipment manufacturer) customers. Section four presents a training exercise in pricing decisions by a petroleum manufacturing firm. Section five presents a training exercise in marketing strategies by an office furniture distributer along with buying strategies by business customers. Each of the three training exercises is based on research into information processing and decision making of executives operating in marketing contexts. Section six concludes the article with suggestions for use of this training case and for developing additional training cases for honing executives' decision-making skills. Todd and Gigerenzer propose that humans use simple heuristics because they enable adaptive behavior by exploiting the structure of information in natural decision environments. "Simplicity is a virtue, rather than a curse". Bounded rationality theorists emphasize the centrality of Simon's proposition, "Human rational behavior is shaped by a scissors whose blades are the structure of the task environments and the computational capabilities of the actor". Gigerenzer's view is relevant to Simon's environmental blade and to the environmental structures in the three cases in this article, "The term environment, here, does not refer to a description of the total physical and biological environment, but only to that part important to an organism, given its needs and goals." The present article directs attention to research that combines reports on the structure of task environments with the use of adaptive toolbox heuristics of actors. The DSA mapping approach here concerns the match between strategy and an environment-the development and understanding of ecological rationality theory. Aspiration adaptation theory is central to this approach. Aspiration adaptation theory models decision making as a multi-goal problem without aggregation of the goals into a complete preference order over all decision alternatives. The three case studies in this article permit the learner to apply propositions in aspiration level rules in reaching a decision. Aspiration adaptation takes the form of a sequence of adjustment steps. An adjustment step shifts the current aspiration level to a neighboring point on an aspiration grid by a change in only one goal variable. An upward adjustment step is an increase and a downward adjustment step is a decrease of a goal variable. Creating and using aspiration adaptation levels is integral to bounded rationality theory. The present article increases understanding and expertise of both aspiration adaptation and bounded rationality theories by providing learner experiences and practice in using propositions in both theories. Practice in ranking CTSs and writing TOP gists from DSA maps serves to clarify and deepen Selten's view, "Clearly, aspiration adaptation must enter the picture as an integrated part of the search for a solution." The body of "direct research" by Mintzberg, Gladwin's ethnographic decision tree modeling, and Huff's work on mapping strategic thought are suggestions on where to look for research that considers both the structure of the environment and the computational capabilities of the actors making decisions in these environments. Such research on bounded rationality permits both further development of theory in how and why decisions are made in real life and the development of learning exercises in the use of heuristics occurring in natural environments. The exercises in the present article encourage learning skills and principles of using fast and frugal heuristics in contexts of their intended use. The exercises respond to Schank's wisdom, "In a deep sense, education isn't about knowledge or getting students to know what has happened. It is about getting them to feel what has happened. This is not easy to do. Education, as it is in schools today, is emotionless. This is a huge problem." The three cases and accompanying set of exercise questions adhere to Schank's view, "Processes are best taught by actually engaging in them, which can often mean, for mental processing, active discussion."

  • PDF

Two Anhydrous Zeolite X Crystal Structures, $Ca_{18}Tl_{56}Si_{100}Al_{92}O_{384}\;and\;Ca_{32}Tl_{28}Si_{100}Al_{92}O_{384}$ (제올라이트 X의 두 개의 무수물 $Ca_{18}Tl_{56}Si_{100}Al_{92}O_{384}$$Ca_{32}Tl_{28}Si_{100}Al_{92}O_{384}$의 결정구조)

  • Choi, Eun Young;Kim, Yang
    • Journal of the Korean Chemical Society
    • /
    • v.43 no.4
    • /
    • pp.384-385
    • /
    • 1999
  • Two anhydrous crystal structures of fully dehydrated, $Ca^{2+}$- and $Tl^+$-exchanged zeolite X, TEX>$Ca_{18}Tl_{56}Si_{100}Al_{92}O_{384}($Ca_{18}Tl_{56}$-X;\alpha=24.883(4)\AA)$ and TEX>$Ca_{32}Tl_{28}Si_{100}Al_{92}O_{384}($Ca_{32}Tl_{28}$-X;\alpha=24.973(4)\AA)$ per unit cell, have been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at $21(1)^{\circ}C.$ $Ca_{18}Tl_{56}-X$ was prepared by ion exchange in a flowing stream of 0.045 M aqueous $Ca(NO_3)_2$ and 0.005 M $TlNO_3$. $Ca_{32}Tl_{28}-X$ was prepared similarly using a mixed solution of 0.0495 M $Ca(NO_3)_2$ and 0.0005M $TlNO_3$. Each crystal was then dehydrated at 360 $^{\circ}C$ and $2{\times}10^{-6}$ Torr for 2 days. Their structures were refined to the final error indices, $R_1=0.039\;and\;R_2=0.036$ with 382 reflections for $Ca_{18}Tl_{56}-X$ , and $R_1=0.046\;and\;R_2=0.045$ with 472 reflections for $Ca_{32}Tl_{28}$-X for which $/>3\sigma(I).$ In the structures of dehydrated $Ca_{18}Tl_{56^-}X\;and\;Ca_{32}Tl_{28}$-X, $Ca^{2+}\;and\;Tl^+$ ions are located at six crystallographic sites. Sixteen $Ca^{2+}$ ions fill the octahedral sites I at the centers of double six rings ($Ca_{18}Tl_{56}$-X:Ca-O=2.42(1) and O-Ca-O=93.06(4)$^{\circ}$; $Ca_{32}Tl_{28}$-X Ca-O=2.40(1) $\AA$ and O-Ca-O=93.08(3)$^{\circ}$). In the structure of $Ca_{18}Tl_{56}$-X, another two $Ca^{2+}$ ions occupy site II (Ca-O=2.35(2) $\AA$ and O-Ca-O=111.69(2)$^{\circ}$) and twenty six $Tl^+$ ions occupy site II opposite single six-rings in the supercage; each is 1.493 $\AA$ from the plane of three oxygens $(Tl-O=2.70(8)\AA$ and O-Tl-O=92.33(4)$^{\circ}$). About four $Tl^+$ ions are found at site II',1.695 $\AA$ into sodalite cavity from their three oxygen plane (Tl-O=2.81 (1) and O-Tl-O=87.48(3)). The remaining twenty six $Tl^+$ ions are distributed over site III'(Tl-O=2.82 (1) $\AA$ and Tl-O=2.88(3)$^{\circ}$). In the structure of $Ca_{32}Tl_{28}$-X, sixteen $Ca^{2+}$ ions and fifteen $Tl^+$ ions occupy site III' (Ca-O=2.26(1) $\AA$ and O-Ca-O=119.14(4)$^{\circ}$; Tl-O=2.70(1) $\AA$ and O-Tl-O=92.38$^{\circ}$) and one $Tl^+$ ion occupies site II'. The remaining twelve $Tl^+$ ions are distributed over site III'. It appears that $Ca^{2+}$ ions prefer sites I and II in that order and $Tl^+$ ions occupy the remaining sites.

  • PDF

Enhancement of Magneto-Optical Kerr Effect in Annealed Granular Films of Co-Au and $Co-AlO_x$

  • Abe, Masanori;Takeda, Eishi;Kitamoto, Yoshitaka;Shirasaki, Fumio;Todoroki, Norikazu;Gorodetzky, Gad;Ohnuma, Shigehiro;Masumoto, Tasuku;Inoue, Mitsuteru
    • The Korean Journal of Ceramics
    • /
    • v.6 no.2
    • /
    • pp.100-102
    • /
    • 2000
  • Co fine particles were dispersed in Au metal and $AlO_x$ amorphous matrices by vacuum evaporation and rf-sputtering, respectively, thus forming granular composite films having chemical compositions of $Co_{0.59}-Au_{0.41}$ and $Co_{0.52}/(AlO_x$)_{0.48}$. The films were annealed at 200~$500^{\circ}C$ to increase the size of the Co particles, from 30$\AA$ to 180$\AA$ in the Au matrix and 40$\AA$ to 180$\AA$ in the $AlO_x$ matrix, as revealed by X-ray diffraction analysis. The Co metal in as-deposited films have saturation magnetization equivalent to that of bulk Co, which is unchanged by the annealing, showing that the Co metal is not oxidized by the annealing. Magneto-optical Kerr rotation measured at $\lambda$=400-900nm for the $Co_{0.59}-Au_{0.41}$ film as deposited is larger than that calculated for the composition. The rotation increases as the film is annealed at $200^{\circ}C$ and $300^{\circ}C$, approaching to that of bulk Co. The Kerr rotation for the $Co_{0.52}-(AlO_x)_{0.48}$ film as deposited is smaller than that calculated for the composition based on Bruggeman effective medium theory. However, the rotation increases much, exceeding the rotation of the bulk Co as annealed at $300^{\circ}C$ and $400^{\circ}C$. As a possible origin of the marked magneto-optical enhancement a weak localization of light in granular structure is suggested.

  • PDF

Isolation and Identification of Inhibitory Compounds from Morus alba cv. Kuksang on α-amylase and α-glucosidase (국상(Kuksang) 뽕잎(Morus alba L.)으로부터 α-amylase와 α-glucosidase 저해 물질 분리 및 동정)

  • Choi, Moo-Young;Cho, Young-Je
    • Journal of Life Science
    • /
    • v.25 no.8
    • /
    • pp.870-879
    • /
    • 2015
  • The objective of this research was to evaluate the inhibitory activities of phenolic compounds isolated from mulberry (Morus alba) leaves of 109 types against α-amylase and α-glucosidase. The inhibitory activity of the water extracts from Morus alba cv. Kuksang against α-amylase and α-glucosidase were determined as 93.8% and 48.7% respectively. The total phenolic content of extracts from Morus alba cv. Kuksang was 9.7±0.2 mg/g soluble in water and 14.3±0.2 mg/g soluble in ethanol. The inhibitory activity of the water extracts from Morus alba cv. Kuksang at 200 μg/ml phenolics concentration against α-amylase and α-glucosidase were determined as 100% and 82.6% respectively. The purification of inhibitory compounds was carried out by Sephadex LH-20 and MCI-gel CHP-20 column chromatography using a gradient elution procedure by nomal phase type (EtOH→distilled water) and reverse phase type (distilled water→MeOH). The quercetin was confirmed to be the chemical structure of the inhibitory compound against α-amylase and α-glucosidase by spectroscopic analysis of FAB-MS, NMR and IR spectrum.

Evaluation of Microcracks in Thermal Damaged Concrete Using Nonlinear Ultrasonic Modulation Technique (비선형 초음파 변조 기법을 이용한 열손상 콘크리트의 미세균열 평가)

  • Park, Sun-Jong;Yim, Hong Jae;Kwak, Hyo-Gyung
    • Journal of the Korea Concrete Institute
    • /
    • v.24 no.6
    • /
    • pp.651-658
    • /
    • 2012
  • This paper concentrates on the evaluation of microcracks in thermal damaged concrete on the basis of the nonlinear ultrasonic modulation technique. Since concrete structure exposed to high temperature accompanies the development of microcracks due to the physical and chemical changes from temperature and exposed time, the adoption of nonlinear approach is required. Instead of using the conventional ultrasonic nondestructive methods which have the limitation in evaluating excessive microcracks, accordingly, a nonlinear ultrasonic modulation method which shows better sensitivity in quantifying microcracks is introduced. Upon the analysis for the modulation of ultrasonic wave and low frequency impact to measure the nonlinearity parameter, which can be used as an indicator of thermal damage, the verification processes for the introduced technique are followed: SEM investigation and permeable pore space test are performed to characterize thermally induced microcracks in concrete, and ultrasonic pulse velocity tests are performed to confirm the outstanding sensitivity of nonlinear ultrasonic modulation technique. In advance, compressive strength of thermal damaged concrete is measured to represent the effect of microcracks on performance degradation. Correlation studies between experimental data and measured data show that nonlinear ultrasonic modulation technique can effectively be used to quantify thermally induced microcracks, and to estimate the compressive strength of thermally damaged concrete.

Strength Property Improvement of OCC-based Paper by Various Mechanical and Chemical Treatments of its Fiber (골판지 고지의 물리화학적 처리에 의한 강도향상)

  • Seo, Yung B.;Lee, Jong Hoon
    • Korean Journal of Agricultural Science
    • /
    • v.26 no.1
    • /
    • pp.21-30
    • /
    • 1999
  • To increase the strength properties of recycled fiber, especially OCC (Old Corrugated Container) in this study, we used the mechanical pretreatment on the fibers before refining. The mechanical action in the Hobart mixer induced high shear and compression on the fibers, which resulted in the breakdowns of fiber internal structure, and microcompressions on the surface of the fibers. We evaluated the degree of mechanical treatment by fiber curl index. Four different refining techniques were applied to the pretreated fibers (Valley beater, Kady mill, PFI mill, and Impact refining) to find the best combination of the pretreatment and the refining methods. Conclusions were summarized as followed. 1. In keeping the fiber length from shortening, Kady mill and PFI mill refining were effective. Kady mill and Valley beater application tended to straighten out the fiber shapes. 2. Valley beating increased the breaking length of the handsheets better than other methods, while lowering the tear strength most. The mechanical pretreatment increased breaking length about 10% in average irrespective of four different refining methods. 3. Tear strength was increased by the mechanical pretreatment and by the PFI mill refining. 4. Burst strength was increased by the mechanical pretreatment and by valley beating method. 5. In increasing the breaking length and burst strength while keeping tear strength, combination of mechanical pretreatment and Valley beating were most effective.

  • PDF

Preparation of Talc-Silica Composites by Controlling Surface Charge Behavior (표면전하 거동 조절을 이용한 탈크-실리카 복합체의 제조)

  • Yun, Ki-Hoon;Park, Min-Gyeong;Moon, Young-Jin;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
    • /
    • v.34 no.1
    • /
    • pp.116-124
    • /
    • 2017
  • A plate-type inorganic pigment complex was manufactured in a manner that treats the surface of the complex by adjusting zeta potential between talc, an inorganic pigment used as a material for color cosmetics, and hydrophobic silica. Talc, which is usually used in the prescription of color cosmetics, is a plate-type, white-colored inorganic substance with good application and spreadability to skin. Furthermore, it features excellent dispersibility and extensibility as well as outstanding heat tolerance, light stability, and chemical resistance. In general, silica contributes to durable makeup and stabilized formulation. This paper covers a process of manufacturing an inorganic pigment complex, where hydrophobic silica was applied to the surface of talc by using differences in zeta potential after the surface charges of talc and hydrophobic silica had been adjusted with cationic and anionic surfactants, respectively. The resulting inorganic pigment complex was composed of talc whose surface is coated hydrophobic silica to the thickness of $1{\mu}m$ or less, which developed an effective hydrophobic property. Zeta potential was measured to analyze the surface charge of an inorganic pigment, and FT-IR, used to check the functional group of a surfactant, was applied to treat the surface of the pigment. The surface of the inorganic pigment complex was observed employing SEM, EDS, and FIB, while its structure was confirmed with XRD and FT-IR.