• 제목/요약/키워드: Chemical shrinkage

검색결과 266건 처리시간 0.024초

폴리프로필렌 합성섬유보강 콘크리트의 강도 특성 및 건조수축균열제어 특성에 관한 연구 (A Study on the Strength and Drying Shrinkage Crack Control Properties of Polypropyl)

  • 오병환;백상현
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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    • pp.146-152
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    • 1996
  • Polypropylene fiber reinforced mortar and concrete as civil material or architectural material have been used in America and British etc, and have been researched. Polypropylene fibers have many advantages in many points ; in economical costs, chemical stability and durability. It has been reported that polypropylene fiber can control restrained tensile stresses and cracks and increase toughness, resistance to impact, corrosion, fatigue and durability. This study has been performed to obtain the properties of polypropylene fiber reinforced concrete such as compressive strength, flexural strength, toughness, slump, drying shrinkage crack and drying shrinkage characteristics. The test variables are fiber contents, fiber length, fiber types, and so on. From the results of this study, we can expect the effects of the admixtures of polypropylene fiber about strength and drying shrinkage properties in concrete and mortar.

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저점도 Bis-GMA 유도체로부터 제조된 고분자계 치과 수복용 복합재의 특성 (Characteristics of Polymeric Dental Restorative Composites Fabricated from Bis-GMA Derivatives Having Low Viscosity)

  • 전미영;송정오;김창근
    • 폴리머
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    • 제31권6호
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    • pp.491-496
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    • 2007
  • 고분자계 치아 수복용 복합재에서 2,2-bis[4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane(Bis-GMA) 70 wt%와 희석제인 triethylene glycol dimethacrylate(TEGDMA)가 30 wt% 포함된 혼합물이 레진 기질로 사용되고 있다. Bis-GMA의 높은 점도로 인해 첨가되는 TEGDMA는 수복재의 높은 경화 수축과 물성 저하의 원인이 된다. 본 연구에서는 TEGDMA 첨가량을 감소시켜 우수한 특성을 나타내는 수복재를 제조하기 위해 저점도 Bis-GMA 유도체들을 이용하여 새로운 치과용 수복재를 제조하였다. 히드록실기를 포함하지 않는 Bis-GMA 유도체들의 경화 특성은 Bis-GMA와 비슷하였지만 이들의 흡습성과 점도는 Bis-GMA에 비해 크게 낮았다. Bis-GMA 유도체를 포함한 수복재를 제조하여 경화 수축률, 흡습성, 기계적 물성을 실험한 결과 기존 상업적으로 사용되는 수복재보다 낮은 흡습성과 탁월한 물성을 나타내었고, 경화 수축률도 약 25% 감소하였다.

3D 프린팅용 모르타르의 초기재령 수축거동 평가를 위한 실험적 연구 (Experimental Study for Evaluating Early Age Shrinkage of Mortar for 3D Printing)

  • 서은아;양근혁;이호재
    • 한국구조물진단유지관리공학회 논문집
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    • 제26권2호
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    • pp.76-83
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    • 2022
  • 이 연구는 적층 시공 시 타설 초기부터 외기에 직접 노출되는 조건을 모사하여 밀봉조건과 노출조건에 따른 수축거동을 100일 이상 실험적으로 분석하였다. 결합재 치환에 따른 수축거동 분석을 위해 1종 시멘트, 플라이애시, 실리카흄을 사용하여 동일한 조건에서 길이변화율을 측정하였다. 혼화제 사용이 수축거동에 미치는 영향을 분석하기 위해 적층 시공 시 사용되는 셀룰로오스계 점도조절제와 유지계 수축저감제를 사용하였다. 표면노출양생 시 초기 수축 발생시점이 단축됐으며, 플라이애시와 실리카흄을 사용 시 수축량은 양생조건에 따라 OPC100 배합 대비 60 - 110% 증가했다. 점도조절제와 수축저감제 적용은 양생조건에 따라 최소 18%에서 최대 70% 수축량을 저감시켰다. 시험체의 온도는 양생초기 15 ℃까지 일시적으로 저하됐으며, 수축거동과 상관성을 이 연구를 통해 확인했다.

저융점 폴리에스테르 복합사의 저온 염색성 (Dyeability of Low-melting Hybrid Polyester at Low Temperature)

  • 황지현;김창남;마진숙;오해선;윤남식
    • 한국염색가공학회지
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    • 제24권2호
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    • pp.113-120
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    • 2012
  • Jacquard floor covering could be prepared from low-melting/regular sheath-core hybrid polyester, where the fiber is dyed in yarn state. With regard that the expected high shrinkage of the hybrid polyester in water makes problems in yarn dyeing, low-temperature dyeing properties of the hybrid polyester were studied. The rate of shrinkage of low-melting hybrid polyester exceeds 9% in hot water above $90^{\circ}C$, at such condition, cheese yarn dyeing is very difficult. Although disperse dyes exhaust in a relatively high speed on low-melting hybrid polyester, diffusion of these dyes to the core regular polyester was extremely slow under $90^{\circ}C$. Foron Blue E-BL 150, an anthraquinone E-type disperse dye, showed appreciable diffusion after 48hrs dyeing at $90^{\circ}C$. The fastness to rubbing and drycleaning were improved by one grade after reduction cleaning.

양생조건 변화에 따른 비소성 시멘트 콘크리트의 건조수축 (Drying shrinkage of Non-Sintered Cement Concrete with various curing condition)

  • 문경주;박원춘;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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    • pp.357-360
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    • 2005
  • This research investigates the drying shrinkage of non-sintering cement(NSC) matrix added phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators with various curing condition. The experimental results are follow: When the moisture is fully supplied at the early curing age, there is effect which carries out abundant generation of the ettringite which is an expansion nature mineral, and compensates for contraction with a chemical prestress concept.

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고출력 LED 인캡슐런트용 실리콘 레진의 경화공정중 잔류응력 발달에 대한 유한요소해석 (Finite Element Analysis of Residual Stress Evolution during Cure Process of Silicone Resin for High-power LED Encapsulant)

  • 송민재;김흥규;강정진;김권희
    • 한국정밀공학회지
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    • 제28권2호
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    • pp.219-225
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    • 2011
  • Silicone resin is recently used as encapsulant for high-power LED module due to its excellent thermal and optical properties. In the present investigation, finite element analysis of cure process was attempted to examine residual stress evolution behavior during silicone resin cure process which is composed of chemical curing and post-cooling. To model chemical curing of silicone, a cure kinetics equation was evaluated based on the measurement by differential scanning calorimeter. The evolutions of elastic modulus and chemical shrinkage during cure process were assumed as a function of the degree of cure to examine their effect on residual stress evolution. Finite element predictions showed how residual stress in cured silicone resin can be affected by elastic modulus and chemical shrinkage behavior. Finite element analysis is supposed to be utilized to select appropriate silicone resin or to design optimum cure process which brings about a minimum residual stress in encapsulant silicone resin.

Studies on the Stabilization of Rayon Fabrics for Preparing Carbon Fabrics: 2. Fast Isothermal Stabilization Processes at High Temperature

  • Yoon, Sung-Bong;Cho, Chae-Wook;Cho, Dong-Hwan;Park, Jong-Kyoo;Lee, Jae-Yeol
    • Carbon letters
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    • 제9권4호
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    • pp.308-315
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    • 2008
  • In the present study, fast isothermal stabilization processes for rayon precursor fabrics were performed at $350^{\circ}C$ and $400^{\circ}C$ within 3 minutes and the chemical and physical characteristics of the stabilized fabrics were investigated. In addition, rayon precursor fabrics were pre-treated with three different phosphorous-based flame retardants and then stabilized. The effect of flame retardants on the chemical composition, thermal shrinkage, weight change, thermal stability and XRD results was examined, comparing with those of the precursor fabrics. The result showed that the stabilization of rayon fabrics was most effective as the stabilization temperature was $350^{\circ}C$, the stabilization time was 3 min, and the pre-treatment with phosphoric acid of 1 vol%. The carbon contents of stabilized rayon fabrics were increased with increasing stabilization temperature and time, whereas the oxygen contents were decreased. Also, it is likely that the pre-treatment with phosphoric acid plays a role in retarding the change of chemical structure of rayon fabric. The XRD result was quite consistent with the result showing the effect of phosphoric acid on the chemical composition, thermal shrinkage and weight reduction of rayon fabric.

C급 플라이애쉬 콘크리트의 장기특성에 관한 연구 (The Study on Long-Terms Properties of Concrete Using C Class Fly Ash)

  • 이상수;원철;권영호;안재현;박칠림
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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    • pp.141-145
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    • 1996
  • The primary purpose of this study is to investigate reusal techniques of by-product produced the combined heat power plant in the construction field, which may contribute to the savings of construction materials and the conservation of enviornment. This study is compared and evaluated by testing the chemical resistance, adiabatic temperature rising test, creep and drying shrinkage. As the result of the study, the following conclusions are derived : (1) hydration heat of the fly ash concrete is less than the plain concrete in adiabatic temperature rising test, (2) the fly axh concrete (FA 30%) is similar to the plain concrete in the chemical resistamce, (3) the fly ash concrete (FA 10, 30%) is similar to the plain concrete in drying shrinkage, but the fly ash concrete (FA 50%) is highly increased, (4) the fly ash concrete (FA 30%) is less than the plain concrete in creep test.

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복합재 성형후 열잔류응력에 의한 변형 연구 (Prediction of Spring-in Deformation of Carbon Fiber Reinforced Composite by Thermal Residual Stress)

  • 김용승;김위대
    • Composites Research
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    • 제30권6호
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    • pp.410-415
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    • 2017
  • 본 연구에서는 탄소섬유강화 복합재의 제작 시 열 잔류응력으로 인한 변형을 유한요소 프로그램 ABAQUS에서 User Subroutine을 이용한 유한요소 해석을 통해 예측한다. 탄소섬유강화 복합재의 변형에 영향을 주는 다양한 요인 중 온도구배, 제품 형상, 적층각 및 적층순서, 수지의 화학수축, 열 잔류응력을 고려한 복합재 성형을 해석하였다. 같은 형상의 실제 모델과 해석 모델의 결과를 비교한다. 또한 해석 결과를 분석하여 실제 제작의 오차에 적용하여 실제 제작에서의 성형 완성도를 높이는데 목적이 있다.

쓰레기 매립지에서 표층고화처리층의 건조수축특성 (Characteristics of Desiccation on the Stabilized Layer in Waste Landfill)

  • 천병식;임종윤;최창현;차용혁
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 1999년도 가을 학술발표회 논문집
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    • pp.301-308
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    • 1999
  • With the shortage of the land and NIMBY syndrome, it is issued recently that the capacity of waste-landfill site is needed though the decreasing tendency of waste landfill. From this point, the stability is the most essential problem in the landfill that will be constructed. Advanced design and construction are most important for that. In this paper, for the study of desiccation, dry-shrinkage crack from drying and chemical reaction in cement hydration, which is occurred when the surface layer stabilization method is applied in wast landfill, laboratory test of the ground and specimen according to the mixture ratio of stabilizer is performed. From the result, it is notified that the uni-axial strength increases with the stabilizer, but dry-shrinkage increases too, therefore, it is important and the goal of this study to find the optimal mixture ratio of each stabilizer. Analysis of variance for regression with acting variables is performed to find optimal mixture ratio of each stabilizer.

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