• Title/Summary/Keyword: Chemical properties

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Influence of Functionalization on Physicochemical Properties of Multi-walled Carbon Nanotubes/Epoxy Matrix Nanocomposites

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.124-128
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    • 2009
  • In this study, the effect of multi-step purification or functionalization on physicochemical properties of multi-walled carbon nanotubes (MWNTs)/epoxy (EP) nanocomposites was investigated. The nanocomposites containing multi-step purified MWNTs showed a stronger influence on $T_g$ and increased in mechanical properties in comparison to nanocomposites containing the same amount of only purified MWNTs. Consequently, the multi-step purification of MWNTs led to an improvement of thermomechanical properties of nanocomposites, resulting from improving the intermolecular interaction of MWNTs in epoxy matrix resins.

MS-HEMs: An On-line Management System for High-Energy Molecules at ADD and BMDRC in Korea

  • Lee, Sung-Kwang;Cho, Soo-Gyeong;Park, Jae-Sung;Kim, Kwang-Yeon;No, Kyoung-Tae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.855-861
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    • 2012
  • A pioneering version of an on-line management system for high-energy molecules (MS-HEMs) was developed by the ADD and BMDRC in Korea. The current system can manage the physicochemical and explosive properties of virtual and existing HEMs. The on-line MS-HEMs consist of three main routines: management, calculation, and search. The management routine contains a user-friendly interface to store and manage molecular structures and other properties of the new HEMs. The calculation routine automatically calculates a number of compositional and topological molecular descriptors when a new HEM is stored in the MS-HEMs. Physical properties, such as the heat of formation and density, can also be calculated using group additivity methods. In addition, the calculation routine for the impact sensitivity can be used to obtain the safety nature of new HEMs. The impact sensitivity was estimated in a knowledge-based manner using in-house neural network code. The search routine enables general users to find an exact HEM and its properties by sketching a 2D chemical structure, or to retrieve HEMs and their properties by giving a range of properties. These on-line MS-HEMs are expected be powerful tool for deriving novel promising HEMs.

Temperature-dependent studies on catalytic hydrosilation of polyalkylsiloxane using NMR

  • Sul, Hyewon;Lee, Tae Hee;Lim, Eunsoo;Rho, Yecheol;Kim, Chong-Hyeak;Kim, Jeongkwon
    • Analytical Science and Technology
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    • v.30 no.4
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    • pp.213-219
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    • 2017
  • Polyalkylsiloxane has been spotlighted in pressure-sensitive adhesive (PSA) application due to excellent physical properties and good biocompatibility. Thermal behaviour of polyalkylsiloxane mixtures, such as thermal stability and heat flow, were studied using TG-DTA during catalytic hydrosilation. To understand reaction kinetics of cross-linking, catalytic hydrosilation of polyalkylsiloxane was monitored using variable temperature nuclear magnetic resonance (VT-NMR) as increased temperature. The formation of cross-linking bond $Si-CH_2-CH_2-Si$ was directly observed using distortionless enhanced by polarization transfer (DEPT) technique. Successfully polyalkylsiloxane PSA samples exhibited excellent adhesion properties by cross-linking reaction.

Comparison of Korean and Japanese Rice Cultivars in Terms of Physicochemical Properties (I) The Comparison of Korean and Japanese Rice by NIR and Chemical Analysis (한국 쌀과 일본 쌀의 물리화학적 특성 연구 (I) NIR을 사용한 한국 쌀과 일본 쌀의 품질 비교)

  • 김혁일
    • Journal of the East Asian Society of Dietary Life
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    • v.14 no.2
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    • pp.135-144
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    • 2004
  • A total of 40 Korean and Japanese rice varieties were evaluated for their main chemical components, physical properties, cooking quality, pasting properties, and instrumental measurements. Based on their quality evaluations, it was concluded that Korean and Japanese rice varieties were not significantly different in the basic components of NIR (Near Infra Red) data and the chemical analysis from the uncooked brown and milled rices. Korean rice had a little bit higher protein and amylose contents but much lower fat acidity than those of Japanese rice from the chemical analysis. From all the data of three different kinds of NIR methods, Korean and Japanese milled rice were very similar except the taste score. Japanese rice showed a slightly higher taste score, a little bit higher lightness and whiteness, but lower yellowness and redness than Korean one. From all those data of NIR and the chemical analysis, Korean and Japanese rices had very similar components except the fat content.

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Effect of Stem Drying Method during Curing Process on Physico-chemical Properties in Bulk Cured Leaves (Bulk건조에서 주맥건조방법이 잎담배 이화학성에 미치는 영향)

  • 이철환;이병철;진정의
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.2
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    • pp.133-137
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    • 2000
  • The bulk curing experiment to improve the quality of flue-cured leaves were carried out to evaluate relationship between the modified(3 step-up) drying and conventional drying method in bulk curing process. Modified drying method was somewhat higher values in yellowing color index of cured leaves, and less brittle than those in conventional drying program. As to the chemical properties, there was no difference in chemical component levels in cured leaves between the modified and the conventional methods, while the major chemical compounds in relation to aromatic essential oil of cured leaves showed mostly higher level in the modified method than that in conventional drying method. Additionally 3 step-up drying method increased the tobacco quality by 2 % in price per kg compared with conventional drying method.

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Mechanical Properties and Morphology of Polyamide/Polypropylene Blends

  • Kim, Su Young;Ha, Jin Uk;Shin, Donghyeok;Jung, Wooseok;Lee, Pyoung-Chan
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.1-5
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    • 2020
  • This study examined the effects of the addition of maleic anhydride-grafted polypropylene (PP-g-MA) and polyolefin elastomer (POE) on polyamide 66 (PA66) and polypropylene (PP) blends. The blends of PA66/PP with PP-g-MA and POE were prepared using a twin screw extruder. Mechanical testing results revealed that the tensile, flexural, and izod impact strengths of the blends were maximized at a PP-g-MA content of 2 phr. The increased mechanical strength of the blends with PP-g-MA was attributed to the compatibilizing effect of the PA66 and PP blends. In addition, as the POE content increased, the impact strength of the blends increased. However, at a high POE content, the tensile and flexural strengths decreased, seemingly because of the lower mechanical properties of POE.